Production Method 1

501-65-5

185990-03-8

141556-40-3

1699767-58-2

1877310-63-8

1699767-59-3

73183-34-3

Reaction Conditions

1.1R:Me2CHOH, R:t-BuOK, S:PhMe, 4.5 h, rt
1.218 h, rt
2.1S:PhMe, 0.5 h, rt
3.1S:C6D6

Reference

(N-Heterocyclic Carbene)2-Pd(0)-Catalyzed Silaboration of Internal and Terminal Alkynes: Scope and Mechanistic Studies

By Ansell, Melvyn B. et al, ACS Catalysis, 2016, 6(4), 2192-2196

Raw materials

• Diphenylacetylene
• dimethyl(phenyl)(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane
• 2H-Imidazol-2-ylidene, 1,3-dihydro-1,3,4,5-tetramethyl-
• Palladium, chloro(1,3-dihydro-1,3,4,5-tetramethyl-2H-imidazol-2-ylidene)[(1,2,3-η)-2-methyl-2-propen-1-yl]-

Preparation Products

• Palladium, bis(1,3-dihydro-1,3,4,5-tetramethyl-2H-imidazol-2-ylidene)- (1699767-59-3)
• (1877310-63-8)
• Bis(pinacolato)diborane (73183-34-3)

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