Production Method 1

501-65-5

185990-03-8

141556-40-3

1699767-58-2

1699767-59-3

1877310-63-8

73183-34-3

Reaction Conditions

1.1R:Me2CHOH, R:t-BuOK, S:PhMe, 4.5 h, rt
1.218 h, rt
2.1S:PhMe, 0.5 h, rt
3.1S:C6D6

Reference

(N-Heterocyclic Carbene)2-Pd(0)-Catalyzed Silaboration of Internal and Terminal Alkynes: Scope and Mechanistic Studies

By Ansell, Melvyn B. et al, ACS Catalysis, 2016, 6(4), 2192-2196

Production Method 2

103-33-3

73183-34-3

141556-40-3

1699767-58-2

1699767-59-3

2043599-01-3

Reaction Conditions

1.1R:t-BuOK, S:Me2CHOH, S:PhMe, 4.5 h, rt
1.217 h, rt
2.1S:C6D6, rt

Reference

Comparison of the Reactivity of the Low Buried-Volume Carbene Complexes (ITMe)2Pd(PhC≡CPh) and (ITMe)2Pd(PhN=NPh)

By Ansell, Melvyn B. et al, Organometallics, 2018, 37(7), 1214-1218

Production Method 3

1699767-59-3

Reaction Conditions

1.1S:C6D6, rt → 85°C; 24 h, 85°C

Reference

Synthesis of an [(NHC)2Pd(SiMe3)2] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes

By Ansell, Melvyn B. et al, Angewandte Chemie, 2015, 54(19), 5578-5582

Palladium, bis(1,3-dihydro-1,3,4,5-tetramethyl-2H-imidazol-2-ylidene)- Raw materials

• Azobenzene
• Diphenylacetylene
• Bis(pinacolato)diborane
• dimethyl(phenyl)(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane
• 2H-Imidazol-2-ylidene, 1,3-dihydro-1,3,4,5-tetramethyl-
• Palladium, chloro(1,3-dihydro-1,3,4,5-tetramethyl-2H-imidazol-2-ylidene)[(1,2,3-η)-2-methyl-2-propen-1-yl]-

Palladium, bis(1,3-dihydro-1,3,4,5-tetramethyl-2H-imidazol-2-ylidene)- Preparation Products

• Palladium, bis(1,3-dihydro-1,3,4,5-tetramethyl-2H-imidazol-2-ylidene)- (1699767-59-3)
• Hydrazine, 1,2-diphenyl-1,2-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- (2043599-01-3)
• (1877310-63-8)
• Bis(pinacolato)diborane (73183-34-3)

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