Synthesis of 1,3-bis(1,2,4-triazol-3-amino)-2,4,6-trinitrobenzene and its thermal and explosive behaviour
New Journal of Chemistry Pub Date: 2000-07-05 DOI: 10.1039/B003139I
Abstract
1,3-Bis(1,2,4-triazol-3-amino)-2,4,6-trinitrobenzene (BTATNB) has been synthesized by condensing 1,3-dichloro-2,4,6-trinitrobenzene and 3-amino-1,2,4-triazole in dimethyl formamide (DMF) at 125±2°C. The product has been characterized by elemental analysis, Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR) and mass spectrometry. The data on thermal and explosive properties indicate that BTATNB is slightly more thermally stable than 3-picrylamino-1,2,4-triazole (PATO). At the same time, it is safer towards impact and friction.
Recommended Literature
- [1] Enabling chloride salts for thermal energy storage: implications of salt purity? J. Matthew Kurley,Phillip W. Halstenberg,Abbey McAlister,Stephen Raiman,Richard T. MayesRSC Adv., 2019,9, 25602-25608 10.1039/C9RA03133B
- [2] Ester-directed orthogonal dual C–H activation and ortho aryl C–H alkenylation via distal weak coordination? Manickam Bakthadoss,Tadiparthi Thirupathi Reddy,Vishal Agarwal,Duddu S. SharadaChem. Commun., 2022,58, 1406-1409 10.1039/D1CC06097J
- [3] Excimer formation effects and trap-assisted charge recombination loss channels in organic solar cells of perylene diimide dimer acceptors? Min Kim,Jae-Joon Lee,Tengling Ye,Panagiotis E. Keivanidis,Kilwon ChoJ. Mater. Chem. C, 2020,8, 1686-1696 10.1039/C9TC04955J
- [4] Excited-state proton-coupled electron transfer within ion pairs? Gerald J. Meyer,Leif Hammarstr?mChem. Sci., 2020,11, 3460-3473 10.1039/C9SC04941J
- [5] Fate of nitrogen-15 in the subsequent growing season of greenhouse tomato plants (Lycopersicon esculentum Mill) as influenced by alternate partial root-zone irrigation Maomao Hou,Fenglin Zhong,Qiu Jin,Enjiang Liu,Jie Feng,Tengyun Wang,Yue GaoRSC Adv., 2017,7, 34392-34400 10.1039/C7RA05271E
- [6] Enabling non-flammable Li-metal batteries via electrolyte functionalization and interface engineering? Jing Yu,Yu-Qi Lyu,Jiapeng Liu,Mohammed B. Effat,Junxiong WuJ. Mater. Chem. A, 2019,7, 17995-18002 10.1039/C9TA03784E
- [7] Examination of deposit in commercial diluted phosphoric acid Analyst, 1880,5, 146-147 10.1039/AN8800500146
- [8] Ester-mediated peptide formation promoted by deep eutectic solvents: a facile pathway to proto-peptides? Chen-Yu Chien,Sheng-Sheng YuChem. Commun., 2020,56, 11949-11952 10.1039/D0CC03319G
- [9] Dissolved oxygen sensor based on fluorescence quenching of oxygen-sensitive ruthenium complexes immobilized in sol–gel-derived porous silica coatings Analyst, 1996,121, 785-788 10.1039/AN9962100785
- [10] Evolution of shape, size, and areal density of a single plane of Si nanocrystals embedded in SiO2 matrix studied by atom probe tomography Bin Han,Yasuo Shimizu,Gabriele Seguini,Celia Castro,Gérard Ben Assayag,Koji Inoue,Yasuyoshi Nagai,Sylvie Schamm-Chardon,Michele PeregoRSC Adv., 2016,6, 3617-3622 10.1039/C5RA26710B
Journal Name:New Journal of Chemistry
research_products
-
CAS no.: 89640-58-4