A dual approach to tuning the porosity of porous organic polymers: controlling the porogen size and supercritical CO2 processing?
Chemical Science Pub Date: 2013-10-09 DOI: 10.1039/C3SC52010B
Abstract
Porous organic polymers (POPs) with tunable pore volumes and surface areas can be made from a series of SnIV(porphyrins) functionalized with labile, bulky trans-diaxial ligands. Varying the ligand size allows for the tuning of the micropore volume while supercritical CO2 processing resulted in excellent enhancements of the total pore volumes.
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Journal Name：Chemical Science
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CAS no.: 89640-58-4
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