Aluminium complexes with thio-phosphorus ligands: syntheses and characterisations of [Al2(CyPS3)2(CyPHS2)2] and [Al(S2PPh2)3]?

Dalton Transactions Pub Date: 2008-09-18 DOI: 10.1039/B813427H

Abstract

The novel aluminium complexes [Al2(CyPS3)2(CyPHS2)2] and [Al(S2PPh2)3] have been prepared as potential models for alumino-thiophosphonate based materials; [Al2(CyPS3)2(CyPHS2)2] is the first example of a primary dithiophosphinate to be characterised in the solid state.

Graphical abstract: Aluminium complexes with thio-phosphorus ligands: syntheses and characterisations of [Al2(CyPS3)2(CyPHS2)2] and [Al(S2PPh2)3]
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