- Process and catalysts for the preparation of alkenyl ethers by the addition reaction of alkynes with alcohols, Germany, , ,
Cas no 926-02-3 (tert-Butyl vinyl ether -)
tert-Butyl vinyl ether - structure
Product Name:tert-Butyl vinyl ether -
CAS No:926-02-3
MF:C6H12O
MW:100.158882141113
MDL:MFCD00048246
CID:94942
PubChem ID:70220
Update Time:2024-10-26
tert-Butyl vinyl ether - Chemical and Physical Properties
Names and Identifiers
-
- Tert-Butyl Vinyl Ether
- 2-ethenoxy-2-methylpropane
- TERT-BUTYL VINYL ETHERL
- 2-(Ethenyloxy)-2-methylpropane (ACI)
- Ether, tert-butyl vinyl (6CI, 7CI, 8CI)
- 2-Methyl-2-(vinyloxy)propane
- t-Butyl vinyl ether
- tert-Butoxyethene
- tert-Butoxyethylene
- TERT-BUTYLVINYLETHER
- Q29448631
- NS00039473
- tertiary butyl vinyl ether
- 926-02-3
- 2-Methyl-2-vinyloxy-propane
- C6H12O
- DB-008718
- EN300-117591
- vinyl tertiary-butyl ether
- AS-31067
- MFCD00048246
- tert-Butyl vinyl ether, 98%
- DTXSID0061290
- AKOS009156422
- tertiarybutyl vinyl ether
- SCHEMBL49310
- Vinyltertiary-butylether
- tert-butylvinyl ether
- 2-(Ethenyloxy)-2-methylpropane
- Propane, 2-(ethenyloxy)-2-methyl-
- tert-Butyl vinyl ether -
-
- MDL: MFCD00048246
- Inchi: 1S/C6H12O/c1-5-7-6(2,3)4/h5H,1H2,2-4H3
- InChI Key: PGYJSURPYAAOMM-UHFFFAOYSA-N
- SMILES: O(C(C)(C)C)C=C
Computed Properties
- Exact Mass: 100.08900
- Monoisotopic Mass: 100.089
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 1
- Heavy Atom Count: 7
- Rotatable Bond Count: 2
- Complexity: 59.1
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: 1.8
- Topological Polar Surface Area: 9.2A^2
Experimental Properties
- Color/Form: Light yellow or colorless transparent liquid
- Density: 0.762
- Melting Point: -112°C
- Boiling Point: 75-76 oC
- Flash Point: -17 oC
- Refractive Index: 1.398
- Water Partition Coefficient: Miscible with alcohol, carbon disulfide, chloroform and diethyl ether. Slightly miscible with water.
- Stability/Shelf Life: Stable. Highly flammable. Incompatible with strong oxidizing agents. May be prone to the formation of peroxides when stored in contact with air.
- PSA: 9.23000
- LogP: 1.94500
- Solubility: Slightly soluble in water
tert-Butyl vinyl ether - Security Information
- Hazardous Material transportation number:UN 3271 3/PG 2
- WGK Germany:3
- Hazard Category Code: R11;R38
- Safety Instruction: S16-S26-S36
-
Hazardous Material Identification:
- HazardClass:3.1
- PackingGroup:II
- TSCA:Yes
- Safety Term:3.1
- Packing Group:II
- Risk Phrases:R11
- Storage Condition:Cold storage (+4 ° C) + flammable area
tert-Butyl vinyl ether - Customs Data
- HS CODE:2909199090
- Customs Data:
China Customs Code:
2909199090Overview:
2909199090. Other acyclic ethers and their halogenated derivatives(Including sulfonation,Nitrosative or nitrosative derivatives). VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:5.5%. general tariff:30.0%
Declaration elements:
Product Name, component content, use to
Summary:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
tert-Butyl vinyl ether - Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | T139444-5ml |
tert-Butyl vinyl ether - |
926-02-3 | ≥98%, 0.1% N,N- | 5ml |
¥370.90 | 2023-08-31 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R096204-5g |
tert-Butyl vinyl ether - |
926-02-3 | 0.1% | 5g |
¥605 | 2024-05-20 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R096204-25g |
tert-Butyl vinyl ether - |
926-02-3 | 0.1% | 25g |
¥2089 | 2024-05-20 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T62740-25g |
TERT-BUTYL VINYL ETHER |
926-02-3 | 98%(0.1% N,N-) | 25g |
¥1388.0 | 2023-09-06 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T62740-5g |
TERT-BUTYL VINYL ETHER |
926-02-3 | 98%(0.1% N,N-) | 5g |
¥408.0 | 2023-09-06 | |
| XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd. | 410012-10ML |
tert-Butyl vinyl ether - |
926-02-3 | 98% | 10ML |
¥1094.13 | 2022-02-24 | |
| XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd. | 410012-50ML |
tert-Butyl vinyl ether - |
926-02-3 | 98% | 50ML |
¥3562.69 | 2022-02-24 | |
| abcr | AB255830-5 g |
tert-Butyl vinyl ether, 98%, stabilized with ca 0.1% N,N-diethylaniline; . |
926-02-3 | 98% | 5g |
€39.90 | 2023-04-27 | |
| abcr | AB255830-25 g |
tert-Butyl vinyl ether, 98%, stabilized with ca 0.1% N,N-diethylaniline; . |
926-02-3 | 98% | 25g |
€59.70 | 2023-04-27 | |
| abcr | AB255830-100 g |
tert-Butyl vinyl ether, 98%, stabilized with ca 0.1% N,N-diethylaniline; . |
926-02-3 | 98% | 100g |
€109.50 | 2023-04-27 |
tert-Butyl vinyl ether - Production Method
Production Method 1
Reaction Conditions
1.1 Catalysts: Potassium tert-butoxide , 1,4-Diethoxybutane
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Potassium
Reference
- Chemistry of acetylenic ethers. LII. Acetylenic tert-butyl ethers and other acetylenic ethers with branched alkyl groups. The preparation and pyrolysis of acetylenic ethersvan Daalen, J. J.; Kraak, A.; Arens, J. F., Recueil des Travaux Chimiques des Pays-Bas, 1961, 80, 810-18
Production Method 3
Reaction Conditions
1.1 Catalysts: Triethylamine , 4,7-Diphenyl-1,10-phenanthroline , Palladium trifluoroacetate ; 13 h, 75 °C
Reference
- Synthesis of Allyl and Alkyl Vinyl Ethers Using an in Situ Prepared Air-Stable Palladium Catalyst. Efficient Transfer Vinylation of Primary, Secondary, and Tertiary AlcoholsBosch, Martin; Schlaf, Marcel, Journal of Organic Chemistry, 2003, 68(13), 5225-5227
Production Method 4
Reaction Conditions
1.1 Reagents: 3,3-Dimethyl-1-butene , Sodium tert-butoxide Catalysts: [1,8-Bis[bis(1-methylethyl)phosphino-κP]-9,10[1′,2′]-benzenoanthracen-9(10H)-yl-… Solvents: Diethyl ether ; 15 h, 120 °C
Reference
- Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen AcceptorLyons, Thomas W.; Bezier, David; Brookhart, Maurice, Organometallics, 2015, 34(16), 4058-4062
Production Method 5
Reaction Conditions
Reference
- Product subclass 3: enol ethersMilata, V.; Radl, S.; Voltrova, S., Science of Synthesis, 2008, 32, 589-756
Production Method 6
Reaction Conditions
Reference
- Total Synthesis of (+)-Haperforin GZhang, Wei; Zhang, Zhenyu; Tang, Jun-Chen; Che, Jin-Teng; Zhang, Hao-Yu; et al, Journal of the American Chemical Society, 2020, 142(46), 19487-19492
Production Method 7
Reaction Conditions
Reference
- Application of 1-tert-butoxy-3-[(trimethylsilyl)oxy]buta-1,3-diene in the preparation of functionalized β-hydroxycyclohexanone derivatives, including valuable precursors of daunomycinone analogsPotman, R. P.; Janssen, N. J. M. L.; Scheeren, J. W.; Nivard, R. J. F., Journal of Organic Chemistry, 1984, 49(19), 3628-34
Production Method 8
Reaction Conditions
1.1 Reagents: Potassium tert-butoxide
1.2 -
1.3 Solvents: Water
1.2 -
1.3 Solvents: Water
Reference
- Procedure for the production of tertiary-alkyl alkenyl ethers by the etherification of tertiary alkanols with alkynes in the presence of alkali metal bases, Germany, , ,
Production Method 9
Reaction Conditions
1.1 Reagents: Potassium hydroxide Catalysts: Lithium diisopropylamide Solvents: 1,3-Dimethyl-2-imidazolidinone , Tetrahydrofuran , Cyclohexane ; 2 h, rt → 50 °C; 50 °C → reflux; 2 h, reflux; 10 min, 70 °C
1.2 60 - 65 °C
1.2 60 - 65 °C
Reference
- Process for preparation of tert-butyl vinyl ether, China, , ,
Production Method 10
Reaction Conditions
1.1 Catalysts: Silica , Cesium oxide ; 1 atm, 380 °C
Reference
- New method of production of vinyl ether by vapor phase intramolecular dehydration of glycol ether over solid catalystsShimasaki, Yuuji; Ariyoshi, Kimio; Kambe, Hideyuki; Yano, Hitoshi; Ugamura, Shukichi, Journal of Molecular Catalysis A: Chemical, 2006, 256(1-2), 37-42
Production Method 11
Production Method 12
Production Method 13
Reaction Conditions
1.1 Catalysts: Silica , Diammonium hydrogen phosphate , Cesium nitrate Solvents: Water ; heated
1.2 380 mm Hg, 450 °C
1.2 380 mm Hg, 450 °C
Reference
- Gas-phase intramolecular dehydration process for the manufacture of alkyl vinyl ethers from glycol ethers and distillation processes for product and unreacted starting material recovery, European Patent Organization, , ,
Production Method 14
Reaction Conditions
Reference
- An organic thiyl radical catalyst for enantioselective cyclizationHashimoto, Takuya; Kawamata, Yu; Maruoka, Keiji, Nature Chemistry, 2014, 6(8), 702-705
Production Method 15
Reaction Conditions
Reference
- 17O NMR spectra of vinyl ethersTaskinen, Esko; Hellman, Jaakko, Magnetic Resonance in Chemistry, 1994, 32(6), 353-7
Production Method 16
Reaction Conditions
Reference
- Preparation of vinyl ethers by transetherification in the presence of molecular sievesYuki, Heimei; Hatada, Koichi; Nagata, Kazuhiko; Kajiyama, Kenichi, Bulletin of the Chemical Society of Japan, 1969, 42(12), 3546-50
tert-Butyl vinyl ether - Raw materials
- tert-Butyl vinyl ether -
- 4-Vinylphenol
- Dodecyl vinyl ether
- Ethylene glycol mono-tert-buthyl ether
- tert-Butyl Ethyl Ether
tert-Butyl vinyl ether - Preparation Products
tert-Butyl vinyl ether - Suppliers
Jiangsu Xinsu New Materials Co., Ltd
Gold Member
(CAS:926-02-3)
Order Number:SFD427;SDF423
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Wednesday, 11 December 2024 17:01
Price ($):
Email:[email protected]
Suzhou Senfeida Chemical Co., Ltd
Gold Member
(CAS:926-02-3)TERT-BUTYL VINYL ETHER
Order Number:sfd1561
Stock Status:in Stock
Quantity:200kg
Purity:99.9%
Pricing Information Last Updated:Friday, 19 July 2024 14:32
Price ($):discuss personally
Email:[email protected]
Amadis Chemical Company Limited
Gold Member
(CAS:926-02-3)tert-Butyl vinyl ether -
Order Number:A1207447
Stock Status:in Stock
Quantity:10g/25g/50g/100g
Purity:99%
Pricing Information Last Updated:Monday, 2 September 2024 15:57
Price ($):172.0/280.0/520.0/1036.0
Email:[email protected]
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
(CAS:926-02-3)叔丁基乙烯基醚
Order Number:LE27016715
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 13:01
Price ($):discuss personally
Email:[email protected]
tert-Butyl vinyl ether - Related Literature
-
Suji Lee,Min Su Han Chem. Commun., 2021,57, 9450-9453
-
Yang Xu,Min Wang,Donghui Wei,Rongqiang Tian,Zheng Duan,Fran?ois Mathey Dalton Trans., 2019,48, 5523-5526
-
R. M. Pemberton,J. P. Hart,T. T. Mottram Analyst, 2001,126, 1866-1871
-
Jieun Kim,Han-Saem Park,Tae-Hee Kim,Sung Yeol Kim,Hyun-Kon Song Phys. Chem. Chem. Phys., 2014,16, 5295-5300
-
Jing Chen,Yu Shao,Danzhen Li J. Mater. Chem. A, 2017,5, 937-941
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