An approach to 7-aza-1-phosphanorbornane complexes: strain promoted rearrangement of 1-iminylphosphirane complexes and cycloaddition with olefins?

Dalton Transactions Pub Date: 2019-04-04 DOI: 10.1039/C9DT00838A

Abstract

1-Iminylphosphirane W(CO)5 complexes react with alkenes under an atmosphere of CO at 130 °C to form the original 7-aza-1-phosphanorbornane complexes. The reaction works well with both electron-rich and electron-poor alkenes. On the basis of DFT calculations, we propose a mechanism including the rearrangement of phosphirane into a dipolar five-membered ring and the following cycloaddition of this dipolar intermediate with alkenes.

Graphical abstract: An approach to 7-aza-1-phosphanorbornane complexes: strain promoted rearrangement of 1-iminylphosphirane complexes and cycloaddition with olefins
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