Production Method 1

926-65-8

Reaction Conditions

1.1 Catalysts: Sodium hydroxide ,  Cesium fluoride

Reference

Alkenylation of organic functional groups

, Germany, , ,

Production Method 2

926-65-8

Reaction Conditions

1.1 Catalysts: Silica ,  Cesium oxide ;  1 atm, 380 °C

Reference

New method of production of vinyl ether by vapor phase intramolecular dehydration of glycol ether over solid catalysts

Shimasaki, Yuuji; Ariyoshi, Kimio; Kambe, Hideyuki; Yano, Hitoshi; Ugamura, Shukichi, Journal of Molecular Catalysis A: Chemical, 2006, 256(1-2), 37-42

Production Method 3

926-65-8

Reaction Conditions

Reference

Preparation of vinyl ethers by transetherification using palladium complexes having nitrogen-bidentate ligands

, Japan, , ,

Production Method 4

926-65-8

Reaction Conditions

Reference

Divinyl sulfoxide. V. Base-catalyzed addition of alcohols and thermolysis of the adducts

Gusarova, N. K.; Trofimov, B. A.; Efremova, G. G.; Amosova, S. V., Zhurnal Organicheskoi Khimii, 1981, 17(11), 2272-7

Production Method 5

926-65-8

Reaction Conditions

Reference

Vinyl ethers

, United States, , ,

Production Method 6

926-65-8

Reaction Conditions

1.1 Catalysts: Sodium hydroxide ,  Cesium fluoride Solvents: Dimethyl sulfoxide ;  5.5 h, 100 °C

Reference

Nucleophilic Addition to Acetylenes in Superbasic Catalytic Systems: Part XIII. Cesium Fluoride Containing Systems, Efficient Catalysts for Alkanols Vinylation

Oparina, L. A.; Shaikhudinova, S. I.; Parshina, L. N.; Vysotskaya, O. V.; Preiss, Th.; et al, Russian Journal of Organic Chemistry, 2005, 41(5), 656-660

Production Method 7

926-65-8

Reaction Conditions

1.1 Reagents: Disodium phosphate Catalysts: Palladium chloride Solvents: 2,2,4-Trimethylpentane ;  48 h, 2 atm, rt

Reference

The reaction of vinyl halide-palladium to chloride complexes with nucleophiles catalytic vinylation

Anonymous, IP.com Journal, 2012, 12,

Production Method 8

926-65-8

Reaction Conditions

1.1 6 h, 0.85 MPa, 220 °C

Reference

Reaction behavior of calcium carbide with alcohols

Liu, Qing; Liu, Qingya; Wang, Renxing; Xu, Tao; Liu, Zhenyu, Huagong Xuebao (Chinese Edition), 2013, 64(7), 2573-2579

Production Method 9

926-65-8

Reaction Conditions

Reference

Product subclass 3: enol ethers

Milata, V.; Radl, S.; Voltrova, S., Science of Synthesis, 2008, 32, 589-756

Production Method 10

67-68-5

926-65-8

Reaction Conditions

Reference

Nucleophilic addition to acetylene in superbasic catalytic systems. VII. Vinylation of lower alcohols

Trofimov, B. A.; Oparina, L. A.; Lavrov, V. I.; Parshina, L. N., Zhurnal Organicheskoi Khimii, 1995, 31(5), 647-50

Production Method 11

926-65-8

Reaction Conditions

Reference

Vinylation of alcohols by divinyl sulfoxide

Trofimov, B. A.; Gusarova, N. K.; Efremova, G. G.; Amosova, S. V., Zhurnal Organicheskoi Khimii, 1982, 18(2), 450-1

Production Method 12

926-65-8

Reaction Conditions

Reference

Preparation of vinyl ethers by transetherification in the presence of molecular sieves

Yuki, Heimei; Hatada, Koichi; Nagata, Kazuhiko; Kajiyama, Kenichi, Bulletin of the Chemical Society of Japan, 1969, 42(12), 3546-50

Isopropyl vinylether Raw materials

• Dimethyl sulfoxide

Isopropyl vinylether Preparation Products

• Isopropyl vinylether (926-65-8)

• 1. An artificial photosynthesis system comprising a covalent triazine framework as an electron relay facilitator for photochemical carbon dioxide reduction?
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Isopropyl Vinyl Ether: A Comprehensive Overview

Isopropyl vinyl ether, also known as cas no926-65-8, is a versatile organic compound with the chemical formula C5H10O. It belongs to the class of ethers and is widely used in various industrial and chemical applications. This compound is characterized by its simple structure, consisting of an isopropyl group attached to a vinyl group via an oxygen atom. Its molecular weight is approximately 82.14 g/mol, and it exists as a colorless liquid with a characteristic odor.

The synthesis of isopropyl vinyl ether typically involves the reaction of isopropyl alcohol with ethylene oxide in the presence of an acid catalyst, such as sulfuric acid or p-toluenesulfonic acid. This reaction is exothermic and can be carried out under reflux conditions to ensure complete conversion. The product is then purified by distillation to remove any unreacted starting materials or byproducts.

Isopropyl vinyl ether has gained significant attention in recent years due to its role in polymer chemistry and organic synthesis. One of its most notable applications is as a precursor for the production of polyvinyl ethers, which are used in the manufacture of adhesives, coatings, and elastomers. The compound's ability to undergo polymerization under controlled conditions makes it an ideal candidate for these applications.

In addition to its use in polymer production, isopropyl vinyl ether has found applications in organic synthesis as a protecting group for alcohols. This is particularly useful in the synthesis of complex molecules, where the protection and subsequent deprotection of functional groups are critical steps. Recent studies have explored the use of this compound in the synthesis of biologically active molecules, including pharmaceuticals and agrochemicals.

The stability and reactivity of isopropyl vinyl ether have been extensively studied, with researchers focusing on its thermal and photochemical properties. For instance, studies have shown that the compound undergoes thermal decomposition at elevated temperatures, leading to the formation of various byproducts. On the other hand, under photochemical conditions, it can undergo [2+2] cycloaddition reactions with alkenes, making it a valuable reagent in photoredox catalysis.

Recent advancements in catalytic chemistry have further expanded the utility of isopropyl vinyl ether. For example, researchers have developed novel catalysts that enable selective transformations of this compound into value-added products. These include its use as a substrate for cross-coupling reactions, such as Suzuki-Miyaura coupling, which has opened new avenues for its application in drug discovery and materials science.

In terms of environmental impact, isopropyl vinyl ether has been classified as a low-toxicity compound with limited persistence in aquatic environments. However, its handling requires adherence to standard safety precautions due to its flammability and potential irritation effects on human skin and eyes.

In conclusion, isopropyl vinyl ether, or cas no926-65-8, remains a critical compound in modern chemistry due to its diverse applications and reactivity. Its continued exploration in both academic and industrial settings ensures that new uses will emerge, further solidifying its importance in the chemical landscape.

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