Production Method 1

2797-28-6

89171-23-3

Reaction Conditions

1.1 Reagents: Potassium fluoride Solvents: Methanol ;  15 min, rt

Reference

Silanol-Based Pincer Pt(II) Complexes: Synthesis, Structure, and Unusual Reactivity

Korshin, Edward E.; Leitus, Gregory; Shimon, Linda J. W.; Konstantinovski, Leonid; Milstein, David, Inorganic Chemistry, 2008, 47(16), 7177-7189

Production Method 2

344-04-7

89171-23-3

Reaction Conditions

1.1 Reagents: 1-Bromopropane ,  Magnesium Solvents: Diethyl ether ;  1 h, reflux; 4 h, reflux
1.2 Reagents: Sodium tetrafluoroborate ;  12 h, reflux
1.3 Reagents: Potassium bromide Solvents: Water

Reference

Mechanochemical synthesis of triphenylmethylium and triphenylcyclopropenylium tetrakis(pentafluorophenyl)borates

Makhaev, V. D.; Galiullin, A. N.; Faingol'd, E. E.; Bravaya, N. M.; Petrova, L. A., Russian Chemical Bulletin, 2014, 63(3), 651-656

Production Method 3

79230-20-9

178233-71-1

89171-23-3

Reaction Conditions

1.1 Reagents: Sodium azide Solvents: Ethanol ;  12 h, rt → 80 °C
1.2 Reagents: Potassium chloride Solvents: Water

Reference

Shelf-Stable (E)- and (Z)-Vinyl-λ3-chlorane: A Stereospecific Hyper-vinylating Agent

Watanabe, Yuichiro; Takagi, Taisei; Miyamoto, Kazunori ; Kanazawa, Junichiro ; Uchiyama, Masanobu, Organic Letters, 2020, 22(9), 3469-3473

Production Method 4

344-04-7

89171-23-3

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Diethyl ether ,  Hexane ;  70 min, -78 °C
1.2 Reagents: Boron trichloride ;  50 min, -78 °C; 20 h, rt
1.3 Reagents: Potassium chloride Solvents: Water ;  1 h

Reference

Intramolecular Halogen Stabilization of Silylium Ions Directs Gearing Dynamics

Romanato, Paola; Duttwyler, Simon; Linden, Anthony; Baldridge, Kim K.; Siegel, Jay S., Journal of the American Chemical Society, 2010, 132(23), 7828-7829

Production Method 5

344-04-7

89171-23-3

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Diethyl ether ,  Hexane ;  30 min, -72 °C; 1.5 h, -72 °C
1.2 Reagents: Boron trichloride Solvents: Hexane ;  20 min; 1 h, -72 °C; 16 h, rt
1.3 Reagents: Potassium chloride Solvents: Water ;  2 h, rt

Reference

Converting Non-strained γ-Valerolactone and Derivatives into Sustainable Polythioesters via Isomerization-driven Cationic Ring-Opening Polymerization of Thionolactone Intermediate

Xia, Yongliang; Yuan, Pengjun; Zhang, Yanping; Sun, Yangyang; Hong, Miao, Angewandte Chemie, 2023, 62(14),

Production Method 6

2797-28-6

89171-23-3

Reaction Conditions

1.1 Reagents: Potassium chloride ;  rt

Reference

Synthesis, Characterization and Biological and Catalytic Activities of Propionitrile: Ligated Transition Metal Complexes with [B(C6F5)4] as Counter Anion

Ajlouni, Abdulaziz M.; Hijazi, Ahmed K.; Taha, Ziyad A.; Al-Momani, Waleed; Okour, Areen; et al, Catalysis Letters, 2019, 149(8), 2317-2324

Production Method 7

118611-98-6

89171-23-3

Reaction Conditions

1.1 Reagents: Potassium bis(trimethylsilyl)amide Solvents: Benzene-d6 ;  5 min, rt

Reference

Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E-H Bonds by a Bis(boryl)stannylene

Protchenko, Andrey V.; Bates, Joshua I.; Saleh, Liban M. A.; Blake, Matthew P.; Schwarz, Andrew D.; et al, Journal of the American Chemical Society, 2016, 138(13), 4555-4564

Production Method 8

47855-94-7

89171-23-3

7782-42-5

Reaction Conditions

1.1 Reagents: Graphite, compd. with potassium (8:1) ;  30 min, rt

Reference

From a (Silatrigerma)cyclobutenylium Ion to a (Silatrigerma)cyclobutenyl Radical and Back

Lee, Vladimir Ya. ; Ito, Yuki; Gapurenko, Olga A. ; Minyaev, Ruslan M.; Gornitzka, Heinz; et al, Journal of the American Chemical Society, 2020, 142(38), 16455-16460

Potassium tetrakis(pentafluorophenyl)borate Raw materials

• Borate(1-), tetrakis[3,5-bis(trifluoromethyl)phenyl]-
• Borate(1-),tetrakis(pentafluorophenyl)-, lithium (1:1)
• Bromopentafluorobenzene
• Hydrogen tetrakis(pentafluorophenyl)borate
• Iodonium, [4-(1-methylethyl)phenyl](4-methylphenyl)-

Potassium tetrakis(pentafluorophenyl)borate Preparation Products

• Carbon (7782-42-5)
• Potassium tetrakis(pentafluorophenyl)borate (89171-23-3)

• 1. Fast-pulsing NMR techniques for the detection of weak interactions: successful natural abundance probe of hydrogen bonds in peptides?
  Amandine Altmayer-Henzien,Valérie Declerck,David J. Aitken,Ewen Lescop,Denis Merlet,Jonathan Farjon Org. Biomol. Chem., 2013,11, 7611-7615
• 2. Evolution of shape, size, and areal density of a single plane of Si nanocrystals embedded in SiO2 matrix studied by atom probe tomography
  Bin Han,Yasuo Shimizu,Gabriele Seguini,Celia Castro,Gérard Ben Assayag,Koji Inoue,Yasuyoshi Nagai,Sylvie Schamm-Chardon,Michele Perego RSC Adv., 2016,6, 3617-3622
• 3. Emerging investigators
  Polym. Chem., 2015,6, 5501-5502
• 4. Enabling chloride salts for thermal energy storage: implications of salt purity?
  J. Matthew Kurley,Phillip W. Halstenberg,Abbey McAlister,Stephen Raiman,Richard T. Mayes RSC Adv., 2019,9, 25602-25608
• 5. Evolutionary de novo design of phenothiazine derivatives for dye-sensitized solar cells?
  Vishwesh Venkatraman,Marco Foscato,Vidar R. Jensen,Bj?rn K?re Alsberg J. Mater. Chem. A, 2015,3, 9851-9860

• Catalysts and Inorganic Chemicals Inorganic Compounds Salt

• 916442-23-4(Borane, bis(2,3,4,5,6-pentafluorophenyl)(tetrafluorophenyl)-)
• 2797-28-6(Borate(1-),tetrakis(pentafluorophenyl)-, lithium (1:1))
• 149213-65-0(Tetrakis(2,3,4,5,6-Pentafluorophenyl)-Borate Sodium (1:1))
• 154735-08-7(Borane, tris(2,4-difluorophenyl)-)
• 148892-98-2(Borane, bis(pentafluorophenyl)phenyl-)
• 170151-48-1(Borane, methylbis(pentafluorophenyl)-)
• 1109-15-5(Tris(perfluorophenyl)borane)
• 263879-45-4(Borate(1-), tetrakis(2,3,4,5-tetrafluorophenyl)-,sodiuM (9CI))
• 165612-94-2(Borane,bis(2,3,4,5,6-pentafluorophenyl)-)
• 154735-10-1(Borane, (pentafluorophenyl)diphenyl-)