Cas no 1109-15-5 (Tris(perfluorophenyl)borane)

Tris(perfluorophenyl)borane (B(C6F5)3) is a highly electron-deficient Lewis acid widely used in catalysis, polymerization, and organic synthesis. Its strong electrophilic character, derived from the electron-withdrawing perfluorophenyl groups, enables efficient activation of substrates such as olefins, silanes, and carbonyl compounds. The compound exhibits exceptional thermal and chemical stability, making it suitable for demanding reaction conditions. It serves as a key component in frustrated Lewis pair (FLP) chemistry, facilitating hydrogenation and small-molecule activation. Its non-coordinating anion properties are valuable in olefin polymerization catalysts. The steric bulk of the perfluorophenyl groups also enhances selectivity in asymmetric transformations. Handling requires precautions due to moisture sensitivity.
Tris(perfluorophenyl)borane structure
Tris(perfluorophenyl)borane structure
Product Name:Tris(perfluorophenyl)borane
CAS No:1109-15-5
MF:C18BF15
MW:511.979657173157
MDL:MFCD00269813
CID:40735
PubChem ID:24867921
Update Time:2025-10-23

Tris(perfluorophenyl)borane Chemical and Physical Properties

Names and Identifiers

    • Tris(perfluorophenyl)borane
    • Tris(pentafluorophenyl)borane
    • Perfluorotriphenylborane
    • TRIS(PENTAFLUOROPHENYL)BORON
    • Perfluorotriphenylboron
    • tris(2,3,4,5,6-pentafluorophenyl)borane
    • Borane,tris(pentafluorophenyl)- (7CI,8CI,9CI)
    • BF 15
    • Tri(pentafluorophenyl)boron
    • Tri(perfluorophenyl)borane
    • Tris(perfluorophenyl)boron
    • perfluorotriphenylborone
    • Tris(Pentafluorophenyl)Borate
    • Tris(pentafluorophenyl)borane,95%
    • Tris(pentafluorophenyl)borane 95%
    • Tris(pentafluorophenyl)borane ,94%
    • TRIS(PENTAFLUOROPHENYL)BORON, 97+%
    • Borane, tris(2,3,4,5,6-pentafluorophenyl)-
    • tris(pentafluorophenyl)-borane
    • Borane, tris(pentafluorophenyl)-
    • OBAJXDYVZBHCGT-UHFFFAOYSA-N
    • I3WU5E2578
    • Tris(pentafluorophenyl)borane, 95%
    • B(C6F5)3
    • zlchem 1272
    • tris(pentafluorophenyl) boron
    • tris(pentafluorophenyl
    • KSC491C8H
    • tris(pentafluorophenyl) borane
    • tris (pentafluo
    • Tri-(2,3,4,5,6-pentafluor-phenyl)-borane (perfluortriphenylborane)
    • C18BF15
    • 135072-62-7
    • BF-15
    • ORANE, TRIS(2,3,4,5,6-PENTAFLUOROPHENYL)-
    • Tris(pentafluorophenyl)borane, 97%
    • AKOS005063333
    • tris[2,3,4,5,6-pentakis(fluoranyl)phenyl]borane
    • UNII-I3WU5E2578
    • A802267
    • GS-3632
    • (C6F5)3B
    • CS-W008525
    • AC-30156
    • tris (pentafluorophenyl) borane
    • SCHEMBL56560
    • YSWG290
    • AMY7149
    • T2313
    • TRIS(2,3,4,5,6-PENTAFLUOROPHENYL)BORANE [MI]
    • J-002489
    • HY-W008525
    • 1109-15-5
    • MFCD00269813
    • TRIS (PENTAFLUORO) PHENYL BORANE
    • DTXSID6074594
    • Tris(2,3,4,5,6-pentafluorophenyl)borane #
    • Q3562143
    • SY011213
    • FT-0649882
    • Perfluorotriphenylboron; Perfluorotriphenylborane;
    • TPB TRIS(PENTAFLUOROPHENYL) BORANE
    • DB-001436
    • DTXCID4033182
    • 601-014-5
    • 414-000-7
    • tri(pentafluorophenyl)borane
    • FT73249
    • MDL: MFCD00269813
    • Inchi: 1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
    • InChI Key: OBAJXDYVZBHCGT-UHFFFAOYSA-N
    • SMILES: FC1C(=C(C(=C(C=1B(C1C(=C(C(=C(C=1F)F)F)F)F)C1C(=C(C(=C(C=1F)F)F)F)F)F)F)F)F
    • BRN: 2931347

Computed Properties

  • Exact Mass: 511.98500
  • Monoisotopic Mass: 511.985
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 15
  • Heavy Atom Count: 34
  • Rotatable Bond Count: 3
  • Complexity: 566
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Surface Charge: 0
  • Tautomer Count: nothing
  • XLogP3: nothing
  • Topological Polar Surface Area: 0

Experimental Properties

  • Color/Form: White powder
  • Density: 0.73?g/mL?at 20?°C
  • Melting Point: 128°C(lit.)
  • Boiling Point: 327.3°C at 760 mmHg
  • Flash Point: 7?°C
  • Refractive Index: n20/D 1.41
  • Solubility: Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.
  • PSA: 0.00000
  • LogP: 4.28930
  • λmax: 306(Toluene)(lit.)
  • Merck: 9755
  • Sensitiveness: Moisture Sensitive
  • Solubility: Not determined

Tris(perfluorophenyl)borane Security Information

  • Symbol: GHS07
  • Prompt:warning
  • Signal Word:Warning
  • Hazard Statement: H315,H319,H335
  • Warning Statement: P261,P305+P351+P338
  • Hazardous Material transportation number:UN 1268 3/PG 2
  • WGK Germany:3
  • Hazard Category Code: 36/37/38
  • Safety Instruction: S60-S61-S62-S45-S37/39-S26-S36
  • Hazardous Material Identification: Xi
  • HazardClass:6.1
  • PackingGroup:III
  • TSCA:No
  • Storage Condition:<0°C
  • Safety Term:6.1
  • Packing Group:III
  • Risk Phrases:R25; R36/37/38
  • Packing Group:III
  • Hazard Level:6.1

Tris(perfluorophenyl)borane Customs Data

  • HS CODE:2931900090
  • Customs Data:

    China Customs Code:

    2931900090

    Overview:

    2931900090. Other organic-Inorganic compound. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods). MFN tariff:6.5%. general tariff:30.0%

    Summary:

    2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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Tris(perfluorophenyl)borane Suppliers

Suzhou Senfeida Chemical Co., Ltd
Gold Member
Audited Supplier Audited Supplier
(CAS:1109-15-5)TRIS(PENTAFLUOROPHENYL)BORANE
Order Number:sfd22219
Stock Status:in Stock
Quantity:200kg
Purity:99.9%
Pricing Information Last Updated:Friday, 19 July 2024 14:39
Price ($):discuss personally
Amadis Chemical Company Limited
Gold Member
Audited Supplier Audited Supplier
(CAS:1109-15-5)Tris(perfluorophenyl)borane
Order Number:A1198803
Stock Status:in Stock
Quantity:25g/100g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 02:38
Price ($):197.0/692.0
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
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(CAS:1109-15-5)TRIS(PENTAFLUOROPHENYL)BORANE
Order Number:LE9225
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:01
Price ($):discuss personally

Tris(perfluorophenyl)borane Related Literature

Recommended suppliers
Suzhou Senfeida Chemical Co., Ltd
(CAS:1109-15-5)TRIS(PENTAFLUOROPHENYL)BORANE
sfd22219
Purity:99.9%
Quantity:200kg
Price ($):Inquiry
Email
Amadis Chemical Company Limited
(CAS:1109-15-5)Tris(perfluorophenyl)borane
A1198803
Purity:99%/99%
Quantity:25g/100g
Price ($):197.0/692.0
Email