Production Method 1

3437-95-4

88105-22-0

35475-03-7

Reaction Conditions

1.1 Catalysts: Molybdenum hexacarbonyl ;  6 h, 150 °C

Reference

Synthesis of 2-thiophenecarboxylic and 2,5-thiophenedicarboxylic acid esters via the reaction of thiophenes with the CCl4-ROH reagent in the presence of vanadium, iron, and molybdenum catalysis

Khusnutdinov, R. I.; Shchadneva, N. A.; Baiguzina, A. R.; Mukminov, R. R.; Mayakova, Yu. Yu.; et al, Neftekhimiya, 2008, 48(6), 467-473

Production Method 2

5380-42-7

88105-22-0

Reaction Conditions

1.1 Reagents: Zinc chloride ,  Benzyltrimethylammonium dichloroiodate Solvents: Acetic acid

Reference

Reevaluation of benzyltrimethylammonium dichloroiodide, previously reported to be a selective iodinating agent

D'Auria, Maurizio; Mauriello, Giacomo, Synthesis, 1995, (3), 248-50

Production Method 3

5380-42-7

88105-22-0

Reaction Conditions

1.1 Reagents: Bis(trifluoroacetoxy)iodobenzene ,  Iodine Solvents: Carbon tetrachloride

Reference

Bis(trifluoroacetoxy)iodobenzene-iodine system: an efficient and selective reagent for iodination of thiophene derivatives

D'Auria, Maurizio; Mauriello, Giacomo, Tetrahedron Letters, 1995, 36(27), 4883-4

Production Method 4

3437-95-4

88105-22-0

Reaction Conditions

1.1 Reagents: Potassium carbonate Catalysts: Tris(2,2′-bipyridyl)ruthenium(II) chloride Solvents: Methanol ;  24 h, rt
1.2 Reagents: Water ;  rt

Reference

Visible Light-Promoted Photocatalytic C-5 Carboxylation of 8-Aminoquinoline Amides and Sulfonamides via a Single Electron Transfer Pathway

Sen, Chiranjit; Sahoo, Tapan; Singh, Harshvardhan; Suresh, Eringathodi ; Ghosh, Subhash Chandra, Journal of Organic Chemistry, 2019, 84(16), 9869-9896

Methyl 5-iodothiophene-2-carboxylate Raw materials

• 2-Iodothiophene
• Methyl thiophene-2-carboxylate

Methyl 5-iodothiophene-2-carboxylate Preparation Products

• Methyl 5-iodothiophene-2-carboxylate (88105-22-0)
• Methyl 5-chlorothiophene-2-carboxylate (35475-03-7)

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• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Thiophenes Thiophene carboxylic acids and derivatives

• 50340-79-9(5-(Methoxycarbonyl)thiophene-2-carboxylic acid)
• 5271-35-2(2-Thiophenecarboxylic acid, 2-thienylmethyl ester)
• 156910-49-5(5-(ethoxycarbonyl)-2-thiophenecarboxylic Acid)
• 67808-64-4(Methyl 5-formylthiophene-2-carboxylate)
• 5380-42-7(Methyl thiophene-2-carboxylate)
• 2810-04-0(Ethyl 2-thiophenecarboxylate)
• 4282-34-2(Dimethyl thiophene-2,5-dicarboxylate)
• 25569-97-5(Thiophene-2-carboxylic acid anhydride)
• 105125-03-9([2,2'-Bithiophene]-5-carboxylicacid, 5'-iodo-, ethyl ester)
• 67808-65-5(Ethyl 5-formylthiophene-2-carboxylate)