Cas no 870777-33-6 ((3-Formyl-5-methylphenyl)boronic acid)

(3-Formyl-5-methylphenyl)boronic acid is a versatile boronic acid derivative widely used in Suzuki-Miyaura cross-coupling reactions, a key method for forming carbon-carbon bonds in organic synthesis. The presence of both a formyl (–CHO) and methyl (–CH?) group on the phenyl ring enhances its reactivity and selectivity in palladium-catalyzed transformations. This compound is particularly valuable in pharmaceutical and materials science research, where it serves as a building block for synthesizing complex aromatic structures. Its stability under standard conditions and compatibility with various reaction conditions make it a reliable reagent. The boronic acid moiety ensures efficient transmetalation, while the formyl group offers further functionalization opportunities.

(3-Formyl-5-methylphenyl)boronic acid structure

870777-33-6 structure

Product Name:(3-Formyl-5-methylphenyl)boronic acid

CAS No:870777-33-6

MF:C₈H₉BO₃

MW:163.966262578964

MDL:MFCD08276762

CID:719180

PubChem ID:24882679

Update Time:2025-05-28

(3-Formyl-5-methylphenyl)boronic acid Chemical and Physical Properties

Names and Identifiers

- (3-Formyl-5-methylphenyl)boronic acid
- 3-FORMYL-5-METHYLPHENYLBORONIC ACID
- 3-Fornyl-5-methylphenylboronic acid
- Boronic acid,B-(3-formyl-5-methylphenyl)-
- IDXLUNCVVBZUEN-UHFFFAOYSA-N
- FCH1122944
- TRA0100264
- AM85133
- AB44850
- (3-Formyl-5-methyl-phenyl)boronic acid
- OR350181
- BC001785
- ST2407982
- AX8217996
- X1405
- Boronic acid, B-(3-formyl
- B-(3-Formyl-5-methylphenyl)boronic acid (ACI)
- Boronic acid, (3-formyl-5-methylphenyl)- (9CI)
- CS-W016100
- MFCD08276762
- 3-Formyl-5-methylphenyl boronic acid
- (3-Formyl-5-methylphenyl)boronicacid
- EN300-7372727
- DS-14899
- BP-12104
- 870777-33-6
- DTXSID30584489
- AKOS015837463
- VJB77733
- SCHEMBL1072576
- MDL： MFCD08276762
- Inchi： 1S/C8H9BO3/c1-6-2-7(5-10)4-8(3-6)9(11)12/h2-5,11-12H,1H3
- InChI Key： IDXLUNCVVBZUEN-UHFFFAOYSA-N
- SMILES： O=CC1C=C(C)C=C(B(O)O)C=1

Computed Properties

Exact Mass: 164.06400
Monoisotopic Mass: 164.0644743g/mol
Isotope Atom Count: 0
Hydrogen Bond Donor Count: 2
Hydrogen Bond Acceptor Count: 3
Heavy Atom Count: 12
Rotatable Bond Count: 2
Complexity: 160
Covalently-Bonded Unit Count: 1
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count : 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Topological Polar Surface Area: 57.5

Experimental Properties

Color/Form: No data available
Density: 1.2
Melting Point: No data available
Boiling Point: 370.9±52.0 °C at 760 mmHg
Flash Point: 178.1±30.7 °C
Refractive Index: 1.54
PSA: 57.53000
LogP: -0.51270

(3-Formyl-5-methylphenyl)boronic acid Security Information

Signal Word：Warning
Hazard Statement： H315-H319-H335
Warning Statement： P261-P305+P351+P338
Hazardous Material transportation number：NONH for all modes of transport
WGK Germany：3
Safety Instruction： S22; S24/25
Storage Condition：Inert atmosphere,2-8°C

(3-Formyl-5-methylphenyl)boronic acid Customs Data

HS CODE：2931900090
Customs Data：

China Customs Code:
2931900090

Overview:

2931900090. Other organic-Inorganic compound. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods). MFN tariff:6.5%. general tariff:30.0%

Summary:

2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

(3-Formyl-5-methylphenyl)boronic acid Pricemore >>

Related Categories	No.	Product Name	Cas No.	Purity	Specification	Price	update time
SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd.	F139361-250mg	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	95%	250mg	￥105.90	2023-09-02
SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd.	F139361-5g	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	95%	5g	￥1381.90	2023-09-02
SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd.	F139361-1g	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	95%	1g	￥368.90	2023-09-02
Chemenu	CM137306-5g	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	95+%	5g	$133	2021-08-05
Alichem	A019115972-5g	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	97%	5g	$368.22	2023-08-31
SHANG HAI XIAN DING Biotechnology Co., Ltd.	B-GA106-50mg	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	97%	50mg	95.0CNY	2021-08-04
SHANG HAI XIAN DING Biotechnology Co., Ltd.	B-GA106-250mg	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	97%	250mg	351CNY	2021-05-08
Fluorochem	219672-250mg	3-Formyl-5-methylphenyl)boronic acid	870777-33-6	95%	250mg	￡28.00	2022-03-01
SHANG HAI XIAN DING Biotechnology Co., Ltd.	B-GA106-1g	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	97%	1g	680.0CNY	2021-08-04
SHANG HAI XIAN DING Biotechnology Co., Ltd.	B-GA106-200mg	(3-Formyl-5-methylphenyl)boronic acid	870777-33-6	97%	200mg	194.0CNY	2021-08-04

(3-Formyl-5-methylphenyl)boronic acid Production Method

Production Method 1

172975-69-8

870777-33-6

Reaction Conditions

1.1 Reagents: Tetrabutylammonium bromide , Potassium persulfate , Poly(methylhydrosiloxane) Catalysts: Ferrous chloride Solvents: Acetonitrile , Water ; 12 h, 80 °C

Reference

Bio-inspired iron-catalyzed oxidation of alkylarenes enables late-stage oxidation of complex methylarenes to arylaldehydes

Hu, Penghui; et al, Nature Communications, 2019, 10(1), 1-9

(3-Formyl-5-methylphenyl)boronic acid Raw materials

3,5-Dimethylphenylboronic acid

(3-Formyl-5-methylphenyl)boronic acid Preparation Products

(3-Formyl-5-methylphenyl)boronic acid (870777-33-6)

(3-Formyl-5-methylphenyl)boronic acid Suppliers

Amadis Chemical Company Limited

Gold Member

Audited Supplier

(CAS:870777-33-6)(3-Formyl-5-methylphenyl)boronic acid

Order Number:A854218

Stock Status:in Stock

Quantity:5g/25g

Purity:99%

Pricing Information Last Updated:Friday, 30 August 2024 07:49

Price ($):193.0/788.0

Email:[email protected]

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