Production Method 1

2438-04-2

73183-34-3

852110-33-9

Reaction Conditions

1.1 Reagents: Sodium fluoride ,  Proton sponge Catalysts: (SP-4-2)-Chlorotris(triphenylphosphine)rhodium ,  Methanaminium, N-[(dimethylamino)fluoromethylene]-N-methyl-, hexafluorophosphate… Solvents: Toluene ;  24 h, 140 °C

Reference

Rh-Catalyzed Direct Decarbonylative Borylation of Carboxylic Acids

Yin, Chang; Liao, Yanjing; He, Bangyue; Li, Hongyi; Su, Weiping, Chemistry - A European Journal, 2023, 29(29),

Production Method 2

76-09-5

89787-12-2

852110-33-9

Reaction Conditions

1.1 Solvents: Diethyl ether ;  18 h, rt

Reference

Hydrogenation of (Hetero)aryl Boronate Esters with a Cyclic (Alkyl)(amino)carbene-Rhodium Complex: Direct Access to cis-Substituted Borylated Cycloalkanes and Saturated Heterocycles

Ling, Liang; He, Yuan; Zhang, Xue; Luo, Meiming; Zeng, Xiaoming, Angewandte Chemie, 2019, 58(20), 6554-6558

Production Method 3

643-28-7

73183-34-3

852110-33-9

Reaction Conditions

1.1 Reagents: tert-Butyl nitrite Solvents: Acetonitrile

Reference

Direct synthesis of arylboronic pinacol esters from arylamines

Qiu, Di; Zhang, Yan; Wang, Jianbo, Organic Chemistry Frontiers, 2014, 1(4), 422-425

Production Method 4

643-28-7

73183-34-3

852110-33-9

Reaction Conditions

1.1 Reagents: tert-Butyl nitrite Solvents: Acetonitrile ;  2 h, 80 °C

Reference

Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation

Qiu, Di; Jin, Liang; Zheng, Zhitong; Meng, He; Mo, Fanyang; et al, Journal of Organic Chemistry, 2013, 78(5), 1923-1933

4,4,5,5-tetramethyl-2-2-(propan-2-yl)phenyl-1,3,2-dioxaborolane Raw materials

• 2,3-Dimethylbutane-2,3-diol
• 2-Isopropylbenzeneboronic acid
• 2-Isopropylbenzoic acid
• 2-Isopropylaniline
• Bis(pinacolato)diborane

4,4,5,5-tetramethyl-2-2-(propan-2-yl)phenyl-1,3,2-dioxaborolane Preparation Products

• 4,4,5,5-tetramethyl-2-2-(propan-2-yl)phenyl-1,3,2-dioxaborolane (852110-33-9)

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• 2. Enabling non-flammable Li-metal batteries via electrolyte functionalization and interface engineering?
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• 4. Fe(ii)-Assisted one-pot synthesis of ultra-small core–shell Au–Pt nanoparticles as superior catalysts towards the HER and ORR?
  Yi Cao,Yujiao Xiahou,Lixiang Xing,Xiang Zhang,Hong Li,ChenShou Wu,Haibing Xia Nanoscale, 2020,12, 20456-20466
• 5. Evolution of shape, size, and areal density of a single plane of Si nanocrystals embedded in SiO2 matrix studied by atom probe tomography
  Bin Han,Yasuo Shimizu,Gabriele Seguini,Celia Castro,Gérard Ben Assayag,Koji Inoue,Yasuyoshi Nagai,Sylvie Schamm-Chardon,Michele Perego RSC Adv., 2016,6, 3617-3622

• 1375301-93-1(2-(2-Isopropyl-6-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 914675-53-9(1,3,2-Dioxaborolane,4,4,5,5-tetramethyl-2-[2,4,6-tris(1-methylethyl)phenyl]-)
• 374934-77-7(1,4-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2,5-dihexylbenzene)
• 1362243-53-5(2-(2-Cyclopropylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 1362243-52-4(2-Methyl-4-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)butan-2-ol)
• 1817810-64-2(1,3,2-Dioxaborolane, 2-[2-(diphenylmethyl)phenyl]-4,4,5,5-tetramethyl-)
• 1613405-69-8(1,3,2-Dioxaborolane, 2-[2-[(1S)-1-ethyl-1-methyl-3-phenylpropyl]-4,6-dimethylphenyl]-4,4,5,5-tetramethyl-)
• 850567-53-2(2-(2-Bromoethyl)phenylboronic acid, pinacol ester)
• 857934-92-0(4,4,5,5-tetramethyl-2-2-(prop-2-en-1-yl)phenyl-1,3,2-dioxaborolane)
• 1683582-61-7(2-(2-Ethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)