Production Method 1

7073-94-1

89787-12-2

Reaction Conditions

1.1 Reagents: tert-Butyllithium Solvents: Pentane ,  Tetrahydrofuran ;  2 h, -78 °C
1.2 Reagents: Triisopropyl borate Solvents: Tetrahydrofuran ;  -78 °C; -78 °C → rt; overnight, rt
1.3 Reagents: Hydrochloric acid Solvents: Water ;  30 min, rt
1.4 Reagents: Sodium hydroxide Solvents: Ethanol ,  Water ;  30 min, rt
1.5 Reagents: Hydrochloric acid Solvents: Water ;  acidified, rt

Reference

9,10-diarylanthracenes as molecular switches: syntheses, properties, isomerizations and their reactions with singlet oxygen

Zehm, Daniel; Fudickar, Werner; Hans, Melanie; Schilde, Uwe; Kelling, Alexandra; et al, Chemistry - A European Journal, 2008, 14(36), 11429-11441

Production Method 2

7073-94-1

89787-12-2

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  15 min, -78 °C
1.2 Reagents: Triisopropyl borate Solvents: Tetrahydrofuran ;  -78 °C; 1 h, -78 °C; 1 h, -78 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: Water

Reference

Group 4 Dimethylsilylenebisamido Complexes Bearing the 6-[2-(Diethylboryl)phenyl]pyrid-2-yl Motif: Synthesis and Use in Tandem Ring-Opening Metathesis/Vinyl-Insertion Copolymerization of Cyclic Olefins with Ethylene

Zou, Yuanlin; Wang, Dongren; Wurst, Klaus; Kuehnel, Christa; Reinhardt, Ingrid; et al, Chemistry - A European Journal, 2011, 17(49), 13832-13846

Production Method 3

89787-12-2

Reaction Conditions

1.1 Solvents: Acetonitrile-d3 ,  Water-d2 ;  24 h, rt

Reference

Fast and Tight Boronate Formation for Click Bioorthogonal Conjugation

Akgun, Burcin; Hall, Dennis G., Angewandte Chemie, 2016, 55(12), 3909-3913

Production Method 4

7073-94-1

89787-12-2

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  15 min, -78 °C
1.2 Reagents: Triisopropyl borate Solvents: Tetrahydrofuran ;  -78 °C; 1 h, -78 °C; 1 h, -78 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: Water ;  rt

Reference

Group 4 metal complexes bearing the aminoborane motif: origin of tandem ring-opening metathesis/vinyl-insertion polymerization

Wang, M.; Xu, G.; Wang, D.; Zou, Y.; Frey, W.; et al, Polymer Chemistry, 2015, 6(17), 3290-3304

Production Method 5

7073-94-1

89787-12-2

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  2 h, -78 °C
1.2 Reagents: Triisopropyl borate Solvents: Tetrahydrofuran ;  1 h, -78 °C; 1 h, rt
1.3 Reagents: Hydrochloric acid Solvents: Water ;  rt

Reference

Structure, Conformation, and Dynamic Processes of the Stereolabile Atropisomers of Hindered Terphenyl Hydrocarbons

Lunazzi, Lodovico; Mazzanti, Andrea; Minzoni, Mirko; Anderson, J. Edgar, Organic Letters, 2005, 7(7), 1291-1294

Production Method 6

2842844-65-7

89787-12-2

98-80-6

Reaction Conditions

1.1 Reagents: Carbamide peroxide Solvents: DMSO-d6 ,  Water ,  Water-d2 ;  rt

Reference

Hydrogen Peroxide-Responsive Triggers Based on Borinic Acids: Molecular Insights into the Control of Oxidative Rearrangement

Gatin-Fraudet, Blaise; Pucher, Mathilde; Le Saux, Thomas; Doisneau, Gilles ; Bourdreux, Yann ; et al, Chemistry - A European Journal, 2022, 28(59),

2-Isopropylbenzeneboronic acid Raw materials

• Borinic acid, B-[2-(1-methylethyl)phenyl]-B-phenyl-
• 1-Bromo-2-isopropylbenzene

2-Isopropylbenzeneboronic acid Preparation Products

• Phenylboronic acid (98-80-6)
• 2-Isopropylbenzeneboronic acid (89787-12-2)

• 1. Alumina coating on 5 V lithium cobalt fluorophosphate cathode material for lithium secondary batteries – synthesis and electrochemical properties?
  S. Amaresh,K. Karthikeyan,K. J. Kim,Y. S. Lee RSC Adv., 2014,4, 23107-23115
• 2. An assay for the enzyme N-acetyl-β-d-glucosaminidase (NAGase) based on electrochemical detection using screen-printed carbon electrodes (SPCEs)
  R. M. Pemberton,J. P. Hart,T. T. Mottram Analyst, 2001,126, 1866-1871
• 3. An aqueous ammonia sensor based on an inkjet-printed polyaniline nanoparticle-modified electrode
  Karl Crowley,Eimer O'Malley,Aoife Morrin,Malcolm R. Smyth,Anthony J. Killard Analyst, 2008,133, 391-399
• 4. An intermolecular C–H oxidizing strategy to access highly fused carbazole skeletons from simple naphthylamines?
  Christian K. Rank,Alexander W. Jones,Tatjana Wall,Patrick Di Martino-Fumo,Sarah Schr?ck,Markus Gerhards,Frederic W. Patureau Chem. Commun., 2019,55, 13749-13752
• 5. An amorphous lanthanum–iridium solid solution with an open structure for efficient water splitting?
  Wei Sun,Chenglong Ma,Xinlong Tian,Jianjun Liao,Ji Yang,Chengjun Ge,Weiwei Huang J. Mater. Chem. A, 2020,8, 12518-12525

• Other Chemical Reagents Derivatization Reagents
• Solvents and Organic Chemicals Organic Compounds Acids/Esters

• 154549-38-9(2,4,6-Triisopropylbenzeneboronic Acid)
• 1402929-71-8(Boronic acid, B-[2-(1-methylethyl)-1-naphthalenyl]-)
• 40276-63-9((2-Benzylphenyl)boronic acid)
• 1809006-69-6(Boronic acid, B-[2,6-dimethyl-4-(triphenylmethyl)phenyl]-)
• 953075-90-6(2,6-diethyl-4-methylphenylboronic acid)
• 610286-39-0((2,6-diethylphenyl)boronic acid)
• 89787-13-3((2-tert-butylphenyl)boronic acid)
• 90002-36-1(o-Ethylphenylboronic Acid)
• 693286-55-4(2-methyl-6-(propan-2-yl)phenylboronic acid)
• 363166-79-4(2,6-Diisopropylphenylboronic acid)