Production Method 1

16750-63-3

83724-41-8

Reaction Conditions

1.1 Reagents: Bismuth trichloride Solvents: Tetrahydrofuran ;  0 °C; 1 h, rt; 30 min, rt → 65 °C; 65 °C → rt
1.2 Reagents: Sodium chloride ;  rt

Reference

High efficient copper-promoted N-arylation of secondary and primary amines with triarylbismuth reagents under mild conditions

Zhou, Xuehao; et al, Journal of Molecular Structure, 2023, 1294,

Production Method 2

16750-63-3

83724-41-8

Reaction Conditions

1.1 Reagents: Bismuth trichloride

Reference

Estimation of the magnitude of quadrupole relaxation enhancement in the context of magnetic resonance imaging contrast

Kruk, Danuta ; et al, Journal of Chemical Physics, 2019, 150(18), 184306/1-184306/9

Production Method 3

529-28-2

83724-41-8

Reaction Conditions

1.1 Reagents: Calcium carbonate ,  Copper ,  Bismuth ,  Cuprous iodide ;  12 h, rt

Reference

A novel dry route to ortho-functionalized triarylbismuthanes that are difficult to access by conventional wet routes

Urano, Mika; et al, Chemical Communications (Cambridge, 2003, (10), 1202-1203

Production Method 4

83724-41-8

791-28-6

Reaction Conditions

1.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 5

83724-41-8

791-28-6

Reaction Conditions

1.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 6

603-36-1

83724-41-8

4756-75-6

Reaction Conditions

1.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 7

121899-81-8

83724-41-8

1153-05-5

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 8

121899-81-8

83724-41-8

791-28-6

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide Solvents: Dichloromethane
1.2 Solvents: Acetonitrile
2.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 9

83724-41-8

1153-05-5

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 10

762-42-5

83724-41-8

Reaction Conditions

1.1 Solvents: Dichloromethane
2.1 -

Reference

Stabilized bismuthonium ylides bearing a highly cross-conjugated ylidic carbon atom: synthesis, structures, and reactions

Matano, Yoshihiro; et al, Journal of Organometallic Chemistry, 2000, 611(1-2), 89-99

Production Method 11

762-42-5

313973-99-8

83724-41-8

162999-92-0

Reaction Conditions

1.1 Solvents: Dichloromethane
2.1 -

Reference

Stabilized bismuthonium ylides bearing a highly cross-conjugated ylidic carbon atom: synthesis, structures, and reactions

Matano, Yoshihiro; et al, Journal of Organometallic Chemistry, 2000, 611(1-2), 89-99

Production Method 12

83724-41-8

Reaction Conditions

1.1 Solvents: Benzene

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 13

578-57-4

83724-41-8

Reaction Conditions

1.1 Reagents: Zinc Catalysts: Trifluoroacetic acid ,  Allyl chloride ,  Cobalt dibromide Solvents: Acetonitrile ;  15 min, 20 °C
1.2 20 °C
1.3 Reagents: Bismuth trichloride Solvents: Acetonitrile ;  18 h, 20 °C

Reference

Advanced preparation of functionalized triarylbismuths and triheteroaryl-bismuths: new scope and alternatives

Urgin, Karene; et al, Tetrahedron Letters, 2012, 53(15), 1894-1896

Production Method 14

31600-86-9

83724-41-8

Reaction Conditions

1.1 Reagents: Bismuth trichloride Solvents: Tetrahydrofuran

Reference

Aryl bismuth phosphinates [BiAr2(O(O)PRR')]: structure-activity relationships for antibacterial activity and cytotoxicity

Herdman, Megan E.; et al, Dalton Transactions, 2022, 51(24), 9323-9335

Production Method 15

121899-81-8

83724-41-8

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide Solvents: Dichloromethane
1.2 Solvents: Acetonitrile
2.1 Solvents: Benzene

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 16

83724-41-8

Reaction Conditions

Reference

Stabilized bismuthonium ylides bearing a highly cross-conjugated ylidic carbon atom: synthesis, structures, and reactions

Matano, Yoshihiro; et al, Journal of Organometallic Chemistry, 2000, 611(1-2), 89-99

Production Method 17

83724-41-8

162999-92-0

Reaction Conditions

Reference

Stabilized bismuthonium ylides bearing a highly cross-conjugated ylidic carbon atom: synthesis, structures, and reactions

Matano, Yoshihiro; et al, Journal of Organometallic Chemistry, 2000, 611(1-2), 89-99

Production Method 18

603-32-7

83724-41-8

1153-05-5

Reaction Conditions

1.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 19

603-32-7

83724-41-8

1153-05-5

Reaction Conditions

1.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 20

603-36-1

83724-41-8

4756-75-6

Reaction Conditions

1.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 21

121899-81-8

83724-41-8

1153-05-5

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide Solvents: Dichloromethane
1.2 Solvents: Acetonitrile
2.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 22

121899-81-8

83724-41-8

4756-75-6

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 23

121899-81-8

83724-41-8

4756-75-6

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide Solvents: Dichloromethane
1.2 Solvents: Acetonitrile
2.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 24

121899-81-8

83724-41-8

791-28-6

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 25

83724-41-8

4756-75-6

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 26

83724-41-8

791-28-6

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Tris(2-methoxyphenyl)bismuthine Raw materials

• 1,4-dimethyl but-2-ynedioate
• Triphenylarsine
• Tris(2-methoxyphenyl)bismuth Dichloride
• 2-Iodoanisole
• Lithium, (2-methoxyphenyl)-
• 2-Bromoanisole
• Triphenylantimony
• 2-Methoxyphenylmagnesium Bromide Solution (1.0 M in THF)

Tris(2-methoxyphenyl)bismuthine Preparation Products

• Triphenylphosphine oxide (791-28-6)
• (diphenylarsoroso)benzene (1153-05-5)
• Tris(2-methoxyphenyl)bismuthine (83724-41-8)
• Triphenylantimony oxide (4756-75-6)
• 4,5-Oxazoledicarboxylic acid, 2-(4-cyanophenyl)-, dimethyl ester (162999-92-0)

• 1. Emerging themes in soft matter: responsive and active soft materials
  Julia M. Yeomans Soft Matter, 2010,6, 703-704
• 2. Excitonic and vibrational coherence in artificial photosynthetic systems studied by negative-time ultrafast laser spectroscopy
  Dongjia Han,Bing Xue,Juan Du,Tomohiro Miyatake,Hitoshi Tamiaki,Xin Xing,Wei Yuan,Yanyan Li Phys. Chem. Chem. Phys., 2016,18, 24252-24260
• 3. Estimating and correcting interference fringes in infrared spectra in infrared hyperspectral imaging
  Ghazal Azarfar,Ebrahim Aboualizadeh,Nicholas M. Walter,Simona Ratti,Camilla Olivieri,Alessandra Norici,Michael Nasse,Achim Kohler,Mario Giordano Analyst, 2018,143, 4674-4683
• 4. Distinguishing between polymorphic forms of linezolid by solid-phase electronic and vibrational circular dichroism?
  Jadwiga Frelek,Marcin Górecki,Marta ?aszcz,Agata Suszczyńska,Elemér Vass,Wojciech J. Szczepek Chem. Commun., 2012,48, 5295-5297
• 5. Excited state characterization of carbonyl containing carotenoids: a comparison between single and multireference descriptions?
  Riccardo Spezia,Stefan Knecht,Benedetta Mennucci Phys. Chem. Chem. Phys., 2017,19, 17156-17166

• Solvents and Organic Chemicals Organic Compounds Benzenoids Phenol ethers Anisoles
• Catalysts and Inorganic Chemicals Inorganic Compounds

Exploring the Potential of Tris(2-Methoxyphenyl)Bismuthine: A Comprehensive Overview

Tris(2-Methoxyphenyl)Bismuthine (CAS No. 83724-41-8) is a fascinating compound that has garnered significant attention in the fields of materials science, organic synthesis, and catalysis. This compound, with its unique structure and properties, offers a wide range of applications and continues to be a subject of extensive research. In this article, we delve into the intricacies of Tris(2-Methoxyphenyl)Bismuthine, exploring its chemical composition, physical properties, applications, and the latest advancements in its utilization.

The molecular structure of Tris(2-Methoxyphenyl)Bismuthine is characterized by a central bismuth atom surrounded by three 2-methoxyphenyl groups. This arrangement imparts the compound with distinctive electronic and optical properties. Recent studies have highlighted its potential as a versatile building block in the synthesis of advanced materials. For instance, researchers have demonstrated its ability to form stable coordination complexes with transition metals, which can be employed in catalytic processes for organic transformations.

One of the most promising applications of Tris(2-Methoxyphenyl)Bismuthine lies in its role as a precursor for the synthesis of bismuth-based nanoparticles. These nanoparticles exhibit unique optical properties, making them ideal candidates for applications in sensing, imaging, and drug delivery systems. A groundbreaking study published in *Advanced Materials* revealed that nanoparticles derived from Tris(2-Methoxyphenyl)Bismuthine exhibit enhanced biocompatibility and stability under physiological conditions, paving the way for their use in biomedical applications.

In addition to its role in materials science, Tris(2-Methoxyphenyl)Bismuthine has also found utility in organic synthesis as a ligand or catalyst. Its ability to stabilize reactive intermediates makes it an invaluable tool in asymmetric catalysis. Recent advancements have shown that when used as a chiral ligand, it can significantly enhance the enantioselectivity of certain reactions, opening new avenues for the production of chiral pharmaceuticals.

The physical properties of Tris(2-Methoxyphenyl)Bismuthine are equally intriguing. Its melting point and solubility characteristics make it suitable for various industrial processes. Moreover, its thermal stability under high-temperature conditions has been leveraged in the development of novel thermoelectric materials. A study conducted at Stanford University demonstrated that composites incorporating Tris(2-Methoxyphenyl)Bismuthine exhibit improved thermoelectric performance, offering potential solutions for energy harvesting applications.

Looking ahead, the future of Tris(2-Methoxyphenyl)Bismuthine seems bright as researchers continue to unlock its full potential. Collaborative efforts between academia and industry are expected to drive innovation in its application across diverse sectors. As sustainability becomes a critical focus globally, the development of eco-friendly synthesis routes for Tris(2-Methoxyphenyl)Bismuthine will be paramount. Researchers are actively exploring green chemistry approaches to minimize waste and reduce environmental impact during its production.

In conclusion, Tris(2-Methoxyphenyl)Bismuthine (CAS No. 83724-41-8) stands out as a multifaceted compound with immense potential across various scientific disciplines. Its unique structure, coupled with cutting-edge research advancements, positions it as a key player in shaping future technologies. As we continue to unravel its capabilities, one can only anticipate further breakthroughs that will redefine its role in materials science and beyond.

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• 193490-06-1(Bismuthonium, tetrakis(2-methoxy-5-methylphenyl)-, chloride)
• 85473-81-0(BISMUTHINE, TRIS(2,6-DIMETHOXYPHENYL)-)
• 193490-04-9(Bismuthonium, tetrakis(2-ethoxyphenyl)-, chloride)
• 193490-13-0(Bismuthonium, tetrakis(2-methoxyphenyl)-, bromide, monohydrate)
• 150527-55-2(Bismuthine, tris(2,3,4-trimethoxyphenyl)-)
• 193489-96-2(Bismuthonium, tetrakis(2-ethoxyphenyl)-, formate)
• 193489-99-5(Bismuthonium, tetrakis(2-methoxyphenyl)-, perchlorate)
• 203195-93-1(Bismuthine, (4-methoxyphenyl)diphenyl-)
• 33397-21-6(tris(4-methoxyphenyl)bismuth)