Production Method 1

121899-81-8

1153-05-5

83724-41-8

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 2

121899-81-8

1153-05-5

83724-41-8

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide Solvents: Dichloromethane
1.2 Solvents: Acetonitrile
2.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 3

603-32-7

1153-05-5

83724-41-8

Reaction Conditions

1.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

Production Method 4

603-32-7

1153-05-5

83724-41-8

Reaction Conditions

1.1 Solvents: Chloroform-d

Reference

Dimeric Triarylbismuthane Oxide: A Novel Efficient Oxidant for the Conversion of Alcohols to Carbonyl Compounds

Matano, Yoshihiro; et al, Journal of the American Chemical Society, 2001, 123(26), 6443-6444

Production Method 5

1153-05-5

83724-41-8

Reaction Conditions

1.1 Reagents: Potassium tert-butoxide ,  Water Solvents: Dichloromethane ;  2 h, 0 °C
2.1 Solvents: Dichloromethane ;  30 min, rt

Reference

Diverse Structures and Remarkable Oxidizing Ability of Triarylbismuthane Oxides. Comparative Study on the Structure and Reactivity of a Series of Triarylpnictogen Oxides

Matano, Yoshihiro; et al, Organometallics, 2004, 23(23), 5471-5480

(diphenylarsoroso)benzene Raw materials

• Triphenylarsine
• Tris(2-methoxyphenyl)bismuth Dichloride

(diphenylarsoroso)benzene Preparation Products

• (diphenylarsoroso)benzene (1153-05-5)
• Tris(2-methoxyphenyl)bismuthine (83724-41-8)

• 1. Polarographic studies on some organic compounds of arsenic. Part III. Triphenylarsine oxide
  A. Watson,G. Svehla Analyst 1975 100 584
• 2. The stereochemistry of some organic derivatives of group VB elements. Part III. The crystal and molecular structure of triphenylarsine oxide monohydrate
  G. Ferguson,E. W. Macaulay J. Chem. Soc. A 1969 1
• 3. Differential-pulse voltammetric study of selected inorganic and organic arsenic compounds at a hanging mercury-drop electrode and its analytical applications
  Mohammad Rasul Jan,William Franklin Smyth Analyst 1984 109 1483
• 4. Metal–ligand frequencies in the spectra of tin complexes with triphenylphosphine oxide and triphenylarsine oxide
  J. P. Clark,V. M. Langford,C. J. Wilkins J. Chem. Soc. A 1967 792
• 5. Formation of triphenylarsinimines (AsAsAs-triphenylarsine imides) by non-nitrene routes: co-oxidation of triphenylarsine and amines or amides with lead tetra-acetate, and related reactions. Preparation of diacetoxytriphenylarsorane
  J. I. G. Cadogan,Ian Gosney J. Chem. Soc. Perkin Trans. 1 1974 466

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzene and substituted derivatives
• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives

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