Cas no 603-32-7 (Triphenylarsine)
Triphenylarsine Chemical and Physical Properties
Names and Identifiers
-
- Triphenylarsine
- triphenylarsane
- NSC 478
- Arsine, triphenyl-
- Triphenyl arsenic
- Triphenylarsene
- Arsinetriphenyl
- MN8EZ3FL74
- BPLUKJNHPBNVQL-UHFFFAOYSA-N
- C18H15As
- Triphenylarsenic
- triphenyl arsine
- triphenyl-arsine
- NSC478
- Arsenic triphenyl
- Tribenzenidoarsenic
- Ph3As
- AsPh3
- Triphenylarsine, 97%
- As(C6H5)3
- 6433AF
- InChI=1/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15
- 603-32-7
- AKOS015840394
- NSC-478
- AI3-28453
- FT-0758379
- MFCD00002994
- Triphenylarsine, 99.99% trace metals basis
- T0508
- EINECS 210-032-9
- D92354
- CS-0015153
- Q414102
- EN300-90515
- DTXSID4060529
- NS00080340
- UNII-MN8EZ3FL74
- DB-246434
- arsine, triphenyl
- >97.0%(GC pound(c)
- DTXCID6042787
-
- MDL: MFCD00002994
- Inchi: 1S/C18H15As/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
- InChI Key: BPLUKJNHPBNVQL-UHFFFAOYSA-N
- SMILES: [As](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
- BRN: 1842037
Computed Properties
- Exact Mass: 306.03900
- Monoisotopic Mass: 306.038972
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 19
- Rotatable Bond Count: 3
- Complexity: 202
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 0
Experimental Properties
- Color/Form: No data available
- Density: 1.225
- Melting Point: 60.0 to 62.0 deg-C
- Boiling Point: 175°C/1.5mmHg(lit.)
- Flash Point: 174 oC
- Refractive Index: 1.6888
- Water Partition Coefficient: Soluble in methanol. Insoluble in water.
- PSA: 0.00000
- LogP: 2.20280
- Vapor Pressure: 0.0±0.8 mmHg at 25°C
Triphenylarsine Security Information
-
Symbol:
- Prompt:dangerous
- Signal Word:Danger
- Hazard Statement: H301+H331-H410
- Warning Statement: P261-P264-P270-P271-P273-P301+P310+P330-P304+P340+P311-P391-P403+P233-P405-P501
- Hazardous Material transportation number:UN 3465 6.1/PG 2
- WGK Germany:3
- Hazard Category Code: 23/25-50/53
- Safety Instruction: S1/2-S20/21-S28-S45-S60-S61
- RTECS:CH8942500
-
Hazardous Material Identification:
- Packing Group:II
- Hazard Level:6.1
- Safety Term:6.1
- Packing Group:II
- Risk Phrases:R23/25; R50/53
- HazardClass:6.1
- PackingGroup:III
- TSCA:Yes
- Storage Condition:Store at 4°C,-4At ℃Store…Better
Triphenylarsine Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | T161749-5G |
Triphenylarsine |
603-32-7 | >97.0%(GC) | 5g |
¥484.90 | 2023-08-31 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | T161749-1g |
Triphenylarsine |
603-32-7 | >97.0%(GC) | 1g |
¥123.90 | 2023-08-31 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | T161749-25g |
Triphenylarsine |
603-32-7 | >97.0%(GC) | 25g |
¥2265.90 | 2023-08-31 | |
| TI XI AI ( SHANG HAI ) HUA CHENG GONG YE FA ZHAN Co., Ltd. | T0508-5G |
Triphenylarsine |
603-32-7 | >98.0%(GC)(T) | 5g |
¥595.00 | 2024-04-16 | |
| A FA AI SHA , SAI MO FEI SHI ER KE JI QI XIA GONG SI | L03616-5g |
Triphenylarsine, 97% |
603-32-7 | 97% | 5g |
¥538.00 | 2022-02-28 | |
| A FA AI SHA , SAI MO FEI SHI ER KE JI QI XIA GONG SI | L03616-25g |
Triphenylarsine, 97% |
603-32-7 | 97% | 25g |
¥1956.00 | 2022-02-28 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T80040-1g |
Triphenylarsine |
603-32-7 | 97% | 1g |
¥98.0 | 2023-09-06 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T80040-5g |
Triphenylarsine |
603-32-7 | 5g |
¥498.0 | 2021-09-07 | ||
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | T823396-5g |
Triphenylarsine |
603-32-7 | 98% | 5g |
¥425.00 | 2022-09-28 | |
| XI GE MA AO DE LI QI ( SHANG HAI ) MAO YI Co., Ltd. | T81906-5G |
Triphenylarsine |
603-32-7 | 5g |
¥531.15 | 2023-11-03 |
Triphenylarsine Suppliers
Triphenylarsine Related Literature
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A. Watson,G. Svehla Analyst 1975 100 584
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2. Formation of triphenylarsinimines (AsAsAs-triphenylarsine imides) by non-nitrene routes: co-oxidation of triphenylarsine and amines or amides with lead tetra-acetate, and related reactions. Preparation of diacetoxytriphenylarsoraneJ. I. G. Cadogan,Ian Gosney J. Chem. Soc. Perkin Trans. 1 1974 466
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3. 1168. Triphenylarsine–halogen adductsA. D. Beveridge,G. S. Harris J. Chem. Soc. 1964 6076
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4. Triphenylarsine hydroxyhalides and their derivativesG. S. Harris,F. Inglis J. Chem. Soc. A 1967 497
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5. Reactions of triarylarsines with nitrene precursors: formation of triarylarsinimines (AsAsAs-triarylarsine imides) and related compoundsJ. I. G. Cadogan,Ian Gosney J. Chem. Soc. Perkin Trans. 1 1974 460
Additional information on Triphenylarsine
Triphenylarsine (CAS No: 603-32-7) - A Comprehensive Overview
Triphenylarsine, with the chemical formula C18H15As, is a significant compound in the realm of organometallic chemistry and has garnered considerable attention due to its unique structural and electronic properties. Its CAS number, CAS No: 603-32-7, serves as a unique identifier, distinguishing it within the vast repository of chemical substances. This compound, characterized by its triphenylamine backbone and arsenic center, exhibits intriguing chemical behavior that has made it a subject of extensive research in various scientific disciplines.
The synthesis of Triphenylarsine typically involves the reaction of arsine with benzophenone or related aromatic ketones, a process that underscores its stability and reactivity. The compound's molecular structure, featuring three phenyl groups attached to an arsenic atom, imparts a high degree of symmetry and electronic delocalization. These features are not only central to its chemical reactivity but also make it a valuable candidate for applications in materials science and catalysis.
In recent years, Triphenylarsine has been explored for its potential in organic electronics. Its ability to act as a ligand in transition metal complexes has opened new avenues for the development of advanced catalysts. For instance, studies have demonstrated its efficacy in promoting cross-coupling reactions, which are pivotal in the synthesis of complex organic molecules. The compound's electron-donating properties and tunable steric environment make it an excellent candidate for designing molecular catalysts with enhanced efficiency and selectivity.
The field of photophysics and photochemistry has also seen significant contributions from Triphenylarsine. Its extended π-conjugation system allows for efficient absorption and emission of light, making it suitable for applications in light-emitting diodes (LEDs) and organic photovoltaics. Researchers have leveraged its photophysical properties to develop novel materials that exhibit superior luminescent characteristics. These advancements hold promise for the development of more energy-efficient lighting solutions and renewable energy technologies.
In the realm of medicinal chemistry, Triphenylarsine has attracted attention for its potential biological activities. While not directly used as a therapeutic agent, derivatives of this compound have been investigated for their antimicrobial and anti-inflammatory properties. The arsenic center in its structure is known to interact with biological targets in unique ways, leading to the discovery of novel pharmacophores. This has spurred interest in exploring further modifications to enhance its therapeutic potential while minimizing any adverse effects.
The environmental impact of Triphenylarsine is another area of growing concern. As with many organometallic compounds, its persistence in the environment and potential toxicity necessitate careful handling and disposal practices. Efforts are underway to develop sustainable synthetic routes that minimize waste and environmental footprint. Additionally, researchers are investigating methods to degrade or neutralize any residual compounds to ensure their safe integration into industrial processes.
The future prospects for Triphenylarsine appear promising, with ongoing research uncovering new applications and refining existing ones. The compound's versatility makes it a valuable tool for chemists and engineers alike, driving innovation across multiple sectors. As our understanding of its properties continues to evolve, so too will its role in advancing scientific knowledge and technological development.
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