Production Method 1

36098-65-4

1111-72-4

64577-25-9

2417951-50-7

Reaction Conditions

1.1R:18-Crown-6, S:DMF, 48 h, 135°C, 1 atm
1.2R:HCl, S:H2O, acidify

Reference

Direct reversible decarboxylation from stable organic acids in dimethylformamide solution

By Kong, Duanyang et al, Science (Washington, 2020, 369(6503), 557-561

Production Method 2

3277-89-2

1111-72-4

64577-25-9

Reaction Conditions

1.1S:Et2O, rt → 0°C; 1 h, 0°C → rt

Reference

Fragment Couplings via CO2 Extrusion-Recombination: Expansion of a Classic Bond-Forming Strategy via Metallaphotoredox

By Le, Chi "Chip" and MacMillan, David W. C., Journal of the American Chemical Society, 2015, 137(37), 11938-11941

Production Method 3

25909-68-6

64577-25-9

Reaction Conditions

1.1S:DMSO
1.2R:NaOH, S:H2O
1.3R:HCl

Reference

Synthesis and acidity constants of 13CO2H-labeled mono and dipyrrole carboxylic acids. pKa from 13C-NMR

By Holmes, Darren L. and Lightner, David A., Tetrahedron, 1995, 51(6), 1607-22

Production Method 4

145177-16-8

64577-25-9

Reaction Conditions

1.1R:KOH, S:H2O

Reference

Organic photochemistry. 91. Photoinduced methyl migrations of methylindenes in the gas phase

By Duguid, Robert J. and Morrison, Harry, Journal of the American Chemical Society, 1991, 113(9), 3519-25

Production Method 5

1111-72-4

64577-25-9

23102-86-5

260429-91-2

Reaction Conditions

1.1R:NaOBu-t, R:t-BuOH, R:S:NMP, 24 h, 25°C, 1 atm

Reference

Visible-light-driven anti-Markovnikov hydrocarboxylation of acrylates and styrenes with CO2

By Huang, He et al, CCS Chemistry, 2021, 3(6), 1746-1756

Production Method 6

36098-65-4

1111-72-4

64577-25-9

2417951-50-7

Reaction Conditions

1.1R:18-Crown-6, S:DMF, 48 h, 135°C, 1 atm
1.2R:HCl, S:H2O, acidify

Reference

Direct reversible decarboxylation from stable organic acids in solution

By Kong, Duanyang et al, ChemRxiv, 2020, From ChemRxiv, 1-11

Production Method 7

1072315-89-9

645-45-4

64577-25-9

Reaction Conditions

1.1C:(o-MeC6H4)3P, C:Pd2(dba)3, S:PhMe
1.2R:4-DMAP, C:12107-56-1, C:131274-22-1, S:NMP, 5 min, 75°C; overnight, 75°C
1.3R:H2O, 2 h, 75°C

Reference

Palladium-Catalyzed Carbon Isotope Exchange on Aliphatic and Benzoic Acid Chlorides

By Gauthier, Donald R. et al, Journal of the American Chemical Society, 2018, 140(46), 15596-15600

Production Method 8

1111-72-4

64577-25-9

Reaction Conditions

1.1R:Mg, S:Et2O
1.2
1.3R:HCl, S:H2O

Reference

Synthesis of 1-13C-1-indanone and 2-13C-1,2,3,4-tetrahydroquinoline

By Pickering, R. E. et al, Journal of Labelled Compounds and Radiopharmaceuticals, 1985, 22(8), 837-42

HYDROCINNAMIC ACID(1-13C, 99%) Raw materials

• 2-Phenethylmagnesium bromide -
• [13C]-9-Methylfluorene-9-carbonyl chloride
• 3-phenylpropanoyl chloride
• Potassium Cyanide-13C
• Propanedioic acid, 2-(phenylmethyl)-, potassium salt (1:2)
• Carbon-13C dioxide
• Benzenepropanenitrile-cyano-13C (9CI)

HYDROCINNAMIC ACID(1-13C, 99%) Preparation Products

• Sodium Formate-1-13C (23102-86-5)
• HYDROCINNAMIC ACID(1-13C, 99%) (64577-25-9)
• (2417951-50-7)
• Oxalic-13C2 Acid Disodium Salt (260429-91-2)

• 1. Exchanged ligands on the surface of a giant cluster: [(MoO3)176(H2O)63(CH3OH)17Hn](32 – n)–
  Chem. Commun., 1998, 1501-1502
• 2. EWOD-driven droplet microfluidic device integrated with optoelectronic tweezers as an automated platform for cellular isolation and analysis?
  Gaurav J. Shah,Eric P.-Y. Chiou,Ming C. Wu,Chang-Jin “CJ” Kim Lab Chip, 2009,9, 1732-1739
• 3. Dissolved oxygen sensor based on fluorescence quenching of oxygen-sensitive ruthenium complexes immobilized in sol–gel-derived porous silica coatings
  Analyst, 1996,121, 785-788
• 4. Emerging investigator series: kinetics of diopside reactivity for carbon mineralization in mafic–ultramafic rocks
  BrianaAguila,LandonHardee,H.ToddSchaef,SiavashZare,MohammadJavadAbdolhosseiniQomi,JarrodV.Crum,JadeE.HollimanJr.,ElenaTajueloRodriguez,LawrenceM.Anovitz,KevinM.Rosso,QuinR.S.Miller
• 5. Establishing new scaling relations on two-dimensional MXenes for CO2 electroreduction?
  Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890

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