Cas no 3277-89-2 (2-Phenethylmagnesium bromide -)
2-Phenethylmagnesium bromide is a Grignard reagent commonly used in organic synthesis for the formation of carbon-carbon bonds. This organomagnesium compound is particularly valuable for introducing the 2-phenethyl group into various substrates, enabling the synthesis of complex aromatic and aliphatic structures. It is typically supplied as a solution in diethyl ether or THF, ensuring ease of handling and reactivity. The reagent exhibits high selectivity and efficiency in nucleophilic additions to carbonyl compounds, such as ketones and aldehydes, as well as in reactions with epoxides and other electrophiles. Its stability under anhydrous conditions and consistent performance make it a reliable choice for advanced synthetic applications.
3277-89-2 structure
Product Name:2-Phenethylmagnesium bromide -
CAS No:3277-89-2
MF:C8H9BrMg
MW:209.366061925888
MDL:MFCD06200648
CID:295322
PubChem ID:10867537
Update Time:2025-05-27
2-Phenethylmagnesium bromide - Chemical and Physical Properties
Names and Identifiers
-
- Magnesium,bromo(2-phenylethyl)-
- PHENETHYLMAGNESIUM BROMIDE,
- 2-phenylethyl-magnesium bromide
- PhCH2CH2MgBr
- Phenethylmagnesium bromide 0.5 M in Tetrahydrofuran
- phenethylMgBr
- 2-Phenylethylmagnesium bromide, 0.5M in THF
- RKFJLAMKBRRYJG-UHFFFAOYSA-M
- phenethylmagnesiumbromide
- phenethyl-magnesium bromide
- 3277-89-2
- phenylethyl magnesium bromide
- 2-phenylethylmagnesium bromide
- SCHEMBL129338
- Phenethylmagnesium bromide, 0.50 M in 2-MeTHF
- Phenethylmagnesium bromide, 0.5M in tetrahydrofuran
- (2-phenyl)ethylmagnesium bromide
- phenethylmagnesium bromide
- 2-Phenylethyl magnesium bromide
- magnesium;ethylbenzene;bromide
- phenethyl magnesium bromide
- phenylethylmagnesium bromide
- AKOS016017816
- MFCD06200648
- 2-Phenethylmagnesium bromide -
-
- MDL： MFCD06200648
- Inchi： 1S/C8H9.BrH.Mg/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q-1;;+2/p-1
- InChI Key： DHZDXXLCWXHNOB-UHFFFAOYSA-M
- SMILES： [Br-].[Mg+2].C([CH2-])C1C=CC=CC=1
Computed Properties
- Exact Mass: 207.97400
- Monoisotopic Mass: 207.97380g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 10
- Rotatable Bond Count: 1
- Complexity: 60.3
- Covalently-Bonded Unit Count: 3
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 0?2
Experimental Properties
- Boiling Point: °Cat760mmHg
- Flash Point: °C
- PSA: 0.00000
- LogP: 3.04230
2-Phenethylmagnesium bromide - Customs Data
- HS CODE：2931900090
- Customs Data：
China Customs Code:
2931900090Overview:
2931900090. Other organic-Inorganic compound. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods). MFN tariff:6.5%. general tariff:30.0%
Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
2-Phenethylmagnesium bromide - Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Fluorochem | 214252-50ml |
Phenethylmagnesium bromide 0.5 M in Tetrahydrofuran |
3277-89-2 | 50ml |
￡273.00 | 2022-03-01 | ||
| Fluorochem | 214252-100ml |
Phenethylmagnesium bromide 0.5 M in Tetrahydrofuran |
3277-89-2 | 100ml |
￡478.00 | 2022-03-01 | ||
| TRC | P229745-5g |
2-Phenethylmagnesium bromide - |
3277-89-2 | 5g |
210.00 | 2021-07-20 | ||
| TRC | P229745-10g |
2-Phenethylmagnesium bromide - |
3277-89-2 | 10g |
350.00 | 2021-07-20 | ||
| TRC | P229745-25g |
2-Phenethylmagnesium bromide - |
3277-89-2 | 25g |
700.00 | 2021-07-20 | ||
| abcr | AB518428-25 ml |
Phenethylmagnesium bromide, 0.5M in 2-MeTHF |
3277-89-2 | 25 ml |
€323.80 | 2023-09-01 | ||
| abcr | AB518428-50 ml |
Phenethylmagnesium bromide, 0.5M 2-MeTHF; . |
3277-89-2 | 50 ml |
€476.90 | 2024-04-17 | ||
| abcr | AB518428-100 ml |
Phenethylmagnesium bromide, 0.5M 2-MeTHF; . |
3277-89-2 | 100 ml |
€783.80 | 2024-04-17 | ||
| abcr | AB518428-500 ml |
Phenethylmagnesium bromide, 0.5M in 2-MeTHF |
3277-89-2 | 500 ml |
€1348.80 | 2023-09-01 | ||
| abcr | AB361565-25 ml |
Phenethylmagnesium bromide, 0.5M in tetrahydrofuran; . |
3277-89-2 | 25 ml |
€266.40 | 2023-09-06 |
2-Phenethylmagnesium bromide - Suppliers
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:3277-89-2)2-Phenethylmagnesium bromide -
Order Number:A1153475
Stock Status:in Stock
Quantity:50ml/100ml
Purity:99%
Pricing Information Last Updated:Thursday, 29 August 2024 23:21
Price ($):753.0/1318.0
Email:[email protected]
2-Phenethylmagnesium bromide - Related Literature
-
1. Hydrodehalogenation of 1,1-dibromocyclopropanes by Grignard reagents promoted by titanium compoundsJuma’a R. Al Dulayymi,Mark S. Baird,Ivan G. Bolesov,Alexey V. Nizovtsev,Viacheslav V. Tverezovsky J. Chem. Soc. Perkin Trans. 2 2000 1603
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Jean-Baptiste Langlois,Daniel Emery,Jiri Mareda,Alexandre Alexakis Chem. Sci. 2012 3 1062
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Jean-Baptiste Langlois,Alexandre Alexakis Chem. Commun. 2009 3868
-
Brian J. Knight,Zachary A. Tolchin,Joel M. Smith Chem. Commun. 2021 57 2693
-
Carlos Vila,Valentín Hornillos,Martín Fa?anás-Mastral,Ben L. Feringa Chem. Commun. 2013 49 5933
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Recommended suppliers
Amadis Chemical Company Limited
(CAS:3277-89-2)2-Phenethylmagnesium bromide -
Purity:99%/99%
Quantity:50ml/100ml
Price ($):753.0/1318.0