Production Method 1

610-97-9

112239-00-6

93415-79-3

Reaction Conditions

1.1 Reagents: 5-Methyl-1,3-dinitro-1H-pyrazole Catalysts: Indium triflate Solvents: 1,1,1,3,3,3-Hexafluoro-2-propanol ;  16 h, rt → 80 °C

Reference

From N-H Nitration to Controllable Aromatic Mononitration and Dinitration-The Discovery of a Versatile and Powerful N-Nitropyrazole Nitrating Reagent

Yang, Tao; Li, Xiaoqian; Deng, Shuang; Qi, Xiaotian ; Cong, Hengjiang ; et al, JACS Au, 2022, 2(9), 2152-2161

Production Method 2

88-67-5

112239-00-6

93415-79-3

Reaction Conditions

1.1 Reagents: Nitric acid Catalysts: Sulfuric acid Solvents: Water ;  10 min, 0 °C; 15 min, 0 °C; 0 °C → 23 °C; 30 min, 23 °C; 23 °C → 130 °C; 1 h, 130 °C; 130 °C → rt
1.2 Reagents: Potassium iodide Catalysts: Sulfuric acid Solvents: Water ;  rt; 1 h, 100 °C
1.3 Catalysts: Sulfuric acid Solvents: Water ;  overnight, reflux; reflux → rt
1.4 Reagents: Sodium bicarbonate Solvents: Water ;  pH 3; pH 5

Reference

A photoredox-neutral Smiles rearrangement of 2-aryloxybenzoic acids

Gonzalez-Gomez, Jose. C.; Ramirez, Nieves P.; Lana-Villarreal, Teresa; Bonete, Pedro, Organic & Biomolecular Chemistry, 2017, 15(45), 9680-9684

Methyl 2-iodo-5-nitrobenzoate Raw materials

• o-Iodobenzoic acid
• Methyl 2-iodobenzoate

Methyl 2-iodo-5-nitrobenzoate Preparation Products

• Methyl 2-iodo-3-nitrobenzoate (93415-79-3)
• Methyl 2-iodo-5-nitrobenzoate (112239-00-6)

• 1. An ion-gating multinanochannel system based on a copper-responsive self-cleaving DNAzyme?
  Yang Chen,Di Zhou,Zheyi Meng,Jin Zhai Chem. Commun., 2016,52, 10020-10023
• 2. An anti-leakage liquid metal thermal interface material
  Kaiyuan Huang,Wangkang Qiu,Meilian Ou,Xiaorui Liu,Zenan Liao,Sheng Chu RSC Adv., 2020,10, 18824-18829
• 3. An integrated droplet-digital microfluidic system for on-demand droplet creation, mixing, incubation, and sorting?
  Lab Chip, 2019,19, 524-535
• 4. An artificial photosynthetic system for photoaccumulation of two electrons on a fused dipyridophenazine (dppz)–pyridoquinolinone ligand?
  Philipp Traber,Stephan Kupfer,Stefanie Gr?fe,Isabelle Baussanne,Martine Demeunynck,Jean-Marie Mouesca,Serge Gambarelli,Vincent Artero,Murielle Chavarot-Kerlidou Chem. Sci., 2018,9, 4152-4159
• 5. An insight into the hybridization mechanism of hairpin DNA physically immobilized on chemically modified graphenes
  Adeline Huiling Loo,Alessandra Bonanni,Martin Pumera Analyst, 2013,138, 467-471

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Nitrobenzoic acids and derivatives
• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzoic acids and derivatives Nitrobenzoic acids and derivatives

• 89976-27-2(methyl 4-iodo-3-nitro-benzoate)
• 5398-69-6(2-Iodo-3-nitrobenzoic acid)
• 93415-79-3(Methyl 2-iodo-3-nitrobenzoate)
• 5471-78-3( )
• 835916-53-5(Benzoic acid, 2-iodo-5-nitro-, ethyl ester)
• 19230-50-3(2-Iodo-5-nitrobenzoic acid)
• 50765-19-0(3-Iodo-5-nitro-methylbenzoate)
• 21323-99-9(3-iodo-4-methyl-5-nitromethyl benzoate)
• 89459-38-1(2-Iodo-4-nitrobenzoic acid)
• 6326-42-7(2-Iodo-4-nitro-benzoic Acid Methyl Ester)