Regio- and Stereo-chemical Effects in the Hydroboration ofΔ2 -Steroidal Allylic and HomoallylicAlcohols?
Journal of Chemical Research, Synopses Pub Date: DOI: 10.1039/A702014G
Abstract
A comparison between the hydroboration ofΔ
2
-steroidal 1α-allylic and5α-homoallylic alcohols reveals that whereas both have astereochemical directing effect, only the allylic alcoholmodifies the regiospecificity of the reaction.
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Journal Name：Journal of Chemical Research, Synopses
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