Recent advances in free radical cyclizations of 2-alkenyl benzaldehydes to synthesize benzocycloketones
New Journal of Chemistry Pub Date: 2022-09-30 DOI: 10.1039/D2NJ04021B
Abstract
The radical cyclization of 2-alkenyl benzaldehyde derivatives has received great attention over the past few decades and it provides a new route for the synthesis of a large number of functionalized benzocycloketone compounds. Herein, we systematically summarize the recent radical reactions involving 2-alkenyl benzaldehydes, including intramolecular and intermolecular cyclization, which give unique access to structurally valuable benzocycloketone compounds. This review may promote the participation of vinyl-attached carbonyls in radical reactions and thereby accelerate their applications in related fields.
Recommended Literature
- [1] Excited state dynamics of symmetric and asymmetric Cr3(dpa)4Cl2 measured using femtosecond transient absorption spectroscopy? Chao-Han Cheng,Wen-Zhen Wang,Shie-Ming Peng,I-Chia ChenPhys. Chem. Chem. Phys., 2017,19, 25471-25477 10.1039/C7CP03968A
- [2] Enantiomeric helical TiO2 nanofibers modulate different peptide assemblies and subsequent cellular behaviors? Xu Jie,Deng Xu,Weili WeiRSC Adv., 2019,9, 29149-29153 10.1039/C9RA04660G
- [3] Excellent energy storage performance in NaNbO3-based relaxor antiferroeic ceramics under a low electric field XuxinCheng,XiaomingChen,PengyuanFan 10.1007/s10832-022-00283-w
- [4] Excited state potential energy surfaces and their interactions in FeIVO active sites Shaun D. Wong,Edward I. SolomonDalton Trans., 2014,43, 17567-17577 10.1039/C4DT01366B
- [5] Exceptionally high temperature spin crossover in amide-functionalised 2,6-bis(pyrazol-1-yl)pyridine iron(ii) complex revealed by variable temperature Raman spectroscopy and single crystal X-ray diffraction? Max Attwood,Hiroki Akutsu,Lee Martin,Toby J. Blundell,Pierre Le Maguere,Scott S. TurnerDalton Trans., 2021,50, 11843-11851 10.1039/D1DT01743H
- [6] Excitable dynamics in the bromate–sulfite–ferrocyanide reaction J. Zagora,M. Vosla?,L. Schreiberová,I. SchreiberPhys. Chem. Chem. Phys., 2002,4, 1284-1291 10.1039/B110048C
- [7] Evolved polymerases facilitate selection of fully 2′-OMe-modified aptamers? Zhixia Liu,Tingjian Chen,Floyd E. RomesbergChem. Sci., 2017,8, 8179-8182 10.1039/C7SC03747C
- [8] Examination of the hydrogen-bonding networks in small water clusters (n = 2–5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis? Erika A. Cobar,Paul R. Horn,Robert G. Bergman,Martin Head-GordonPhys. Chem. Chem. Phys., 2012,14, 15328-15339 10.1039/C2CP42522J
- [9] Emerging investigator series: kinetics of diopside reactivity for carbon mineralization in mafic–ultramafic rocks BrianaAguila,LandonHardee,H.ToddSchaef,SiavashZare,MohammadJavadAbdolhosseiniQomi,JarrodV.Crum,JadeE.HollimanJr.,ElenaTajueloRodriguez,LawrenceM.Anovitz,KevinM.Rosso,QuinR.S.Miller 10.1039/d3en00087g
- [10] Evidence of pre-micellar aggregates in aqueous solution of amphiphilic PDMS–PEO block copolymer? Domenico Lombardo,Gianmarco Munaò,Pietro Calandra,Luigi Pasqua,Maria Teresa CaccamoPhys. Chem. Chem. Phys., 2019,21, 11983-11991 10.1039/C9CP02195G
Journal Name:New Journal of Chemistry
research_products
-
CAS no.: 89640-58-4