Selectfluor?-enabled photochemical selective C(sp3)–H(sulfonyl)amidation?
Chemical Communications Pub Date: 2022-11-29 DOI: 10.1039/D2CC05569D
Abstract
Transition metal- and photosensitizer-free C(sp3)–H (sulfonyl)amidation reactions have been realized by employing Selectfluor? as a versatile reagent, functioning as a photoactive component, a HAT precursor and an oxidant. Various toluene derivatives, cycloalkanes, natural products and bioactive molecules can be converted into N-containing products under mild conditions in good yield and with high chemo- and site-selectivity.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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