An unexpected stereoisomerism in enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern?
Chemical Communications Pub Date: 2014-01-02 DOI: 10.1039/C3CC48941H
Abstract
We have synthesized and isolated two C2-symmetric enantiomerically pure trisadducts of C60 with an inherently chiral trans-3,trans-3,trans-3 addition pattern with the aid of an enantiopure cyclo-tris-malonate tether. An unexpected stereoisomerism was observed which was attributed to the spatial arrangement of spacers in the tether.
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Journal Name：Chemical Communications
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CAS no.: 89640-58-4
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