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Synthesis and structures of luminescent ladder-like lanthanide coordination polymers of 4-hydroxybenzenesulfonate??

New Journal of Chemistry Pub Date: 2008-02-08 DOI: 10.1039/B718590A

Abstract

Reaction of sodium 4-hydroxybenzenesulfonate dihydrate (NaL·2H₂O) with LnCl₃·6H₂O (3 ∶ 1) in refluxing methanol gives the novel isomorphous 1-D framework compounds {[LnL₃(H₂O)₂]·2H₂O}_∞ (Ln = Tb, Er and Yb) in 46–60% yields; the structures of the compounds have been determined by X-ray crystallography and their luminescence properties determined.

Graphical abstract: Synthesis and structures of luminescent ladder-like lanthanide coordination polymers of 4-hydroxybenzenesulfonate

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