Trapping of atomic hydrogens in cage-shaped silsesquioxanes by electric discharge

Chemical Communications Pub Date: 2010-02-16 DOI: 10.1039/B917165G

Abstract

A simple and safe technique which is based on glow discharge is demonstrated for stable encapsulation of H atoms in cage-shaped silsesquioxanes at room temperature, leading to the encapsulation yield of ca. 10?4 H atoms per molecule for 10-minute discharging, much faster than the conventional γ-ray irradiation technique.

Graphical abstract: Trapping of atomic hydrogens in cage-shaped silsesquioxanes by electric discharge
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