Strong field control of predissociation dynamics

Faraday Discussions Pub Date: 2012-12-21 DOI: 10.1039/C2FD20143G

Abstract

Strong field control scenarios are investigated in the CH3I predissociation dynamics at the origin of the second absorption B-band, in which state-selective electronic predissociation occurs through the crossing with a valence dissociative state. Dynamic Stark control (DSC) and pump–dump strategies are shown capable of altering both the predissociation lifetime and the product branching ratio

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