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The useful properties of H2O as a ligand of a hydrogenase mimic?

Dalton Transactions Pub Date: 2010-01-12 DOI: 10.1039/B921273F

Abstract

This paper investigates the required properties of Ru-coordinated ligands of a Ni–Ru based hydrogenase mimic. A series of ligands, including MeCN, pyridine, H₂O and OH^? were coordinated to Ru, with H₂O being the only ligand to promote H₂-activation. In addition, a tethered pyridyl moiety was synthesised and found to completely inhibit H₂-activation. We conclude, therefore, that H₂O is the ideal ligand for this mimic as a result of both its mild basicity and the availability of two lone pairs for simultaneous binding to Ru and H₂.

Graphical abstract: The useful properties of H2O as a ligand of a hydrogenase mimic

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Dalton Transactions

Journal Name：Dalton Transactions

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