Iodine-mediated oxidative N–N coupling of secondary amines to hydrazines?
Organic & Biomolecular Chemistry Pub Date: 2019-03-12 DOI: 10.1039/C9OB00279K
Abstract
An I2-mediated N–N coupling reaction has been established for oxidative dimerization of N-aryl aminopyridines to a variety of novel hydrazine derivatives under mild conditions. This synthetic method does not require use of transition metals and can be conveniently carried out on a gram scale. It is also applicable to diphenylamine and N-alkyl aniline substrates.
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Journal Name：Organic & Biomolecular Chemistry
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CAS no.: 89640-58-4
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