Ionic liquid/water mixture promoted organic transformations
RSC Advances Pub Date: 2015-06-02 DOI: 10.1039/C5RA08625F
Abstract
Ionic liquids (ILs) have been used in numerous applications in chemistry. Wet ILs constitute a new class of solvents with their own new and interesting properties. The properties of ILs are significantly influenced by the addition of water and also affect reaction rates and selectivity. IL/water mixing makes it easy to control the properties of the solution and the formation of these ionic liquid mixtures increases synthetic flexibility. In this review, mixtures of IL/water solvent system promoted organic reactions have been described and the results are compared with other solvent systems. In many cases IL/water combinations were superior compared to conventional organic solvents and biphasic IL/organic co-solvent media with respect to catalytic performance as well as to catalyst separation and recycling.
Recommended Literature
- [1] Aluminium alkyl and aryloxide complexes of pyrazine and bipyridines: synthesis and structure? Doug Ogrin,Laura H. van Poppel,Simon G. Bott,Andrew R. BarronDalton Trans., 2004, 3689-3694 10.1039/B410662H
- [2] An Assessment of the Laminar Hypersonic Double-Cone Experiments in the LENS-XX Tunnel JaideepRay,PatrickBlonigan,EricT.Phipps,KathrynMaupin 10.2514/1.j062802
- [3] An asymmetric supercapacitor based on controllable WO3 nanorod bundle and alfalfa-derived porous carbon? Kanjun Sun,Fengting Hua,Shuzhen Cui,Yanrong Zhu,Hui Peng,Guofu MaRSC Adv., 2021,11, 37631-37642 10.1039/D1RA04788D
- [4] An amide probe as a selective Al3+ and Fe3+ sensor inside the HeLa and a549 cell lines: Pictet–Spengler reaction for the rapid detection of tryptophan amino acid? Bidyut Kumar Kundu,Rinky Singh,Ritudhwaj Tiwari,Debasis NayakNew J. Chem., 2019,43, 4867-4877 10.1039/C9NJ00138G
- [5] An aptasensor for detection of potassium ions based on RecJf exonuclease mediated signal amplification Bidou Wang,Xifeng ChenAnalyst, 2014,139, 5695-5699 10.1039/C4AN01350F
- [6] An integrated microfluidic 3D tumor system for parallel and high-throughput chemotherapy evaluation? Dan Liu,Rui Hu,Zhongchao Huang,Meilin Sun,Kai HanAnalyst, 2020,145, 6447-6455 10.1039/D0AN01229G
- [7] Aluminium complexes with thio-phosphorus ligands: syntheses and characterisations of [Al2(CyPS3)2(CyPHS2)2] and [Al(S2PPh2)3]? Robert P. Davies,Maria A. Giménez,Laura Patel,Andrew J. P. WhiteDalton Trans., 2008, 5705-5707 10.1039/B813427H
- [8] Alumina grafted SBA-15 sustainable bifunctional catalysts for direct cross-coupling of benzylic alcohols to diarylmethanes? Chandran Rajendran,Govindaswamy Satishkumar,Charlotte Lang,Eric M. GaigneauxCatal. Sci. Technol., 2020,10, 2583-2592 10.1039/D0CY00471E
- [9] An intensified π-hole in beryllium-doped boron nitride meshes: its determinant role in CO2 conversion into hydrocarbon fuels? Luis Miguel Azofra,Douglas R. MacFarlane,Chenghua SunChem. Commun., 2016,52, 3548-3551 10.1039/C5CC07942J
- [10] Acetylcholinesterase amperometric detection system based on a cobalt(II) tetraphenylporphyrin-modified electrode Analyst, 1996,121, 1123-1126 10.1039/AN9962101123
Journal Name：RSC Advances
research_products
-
CAS no.: 89640-58-4
![N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide](https://ossimg.kuujia.com/scimg/1444500/1444113-98-7x500.png)
![1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol](https://ossimg.kuujia.com/scimg/1271000/1270529-38-8x500.png)
![2,2-Difluoro-3-[methyl(2-methylbutyl)amino]propanoic acid](https://ossimg.kuujia.com/scimg/2138500/2138166-62-6x500.png)
![2-(1H-indol-3-yl)-N-{[6-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]methyl}acetamide](https://ossimg.kuujia.com/scimg/2034500/2034271-14-0x500.png)