Transition metal hydroxides
Transition metal hydroxides are inorganic compounds that consist of a transition metal ion and one or more hydroxide (OH?) ions. These materials exhibit diverse chemical properties due to the varying oxidation states and coordination geometries of the transition metals, which include elements from groups 4 to 12 on the periodic table. Common examples include ferric hydroxide (Fe(OH)?), cupric hydroxide (Cu(OH)?), and nickel(II) hydroxide (Ni(OH)?).
Transition metal hydroxides are widely used in various applications, such as catalysis, energy storage devices like batteries and capacitors, adsorption of heavy metals, and drug delivery systems. In catalytic processes, these compounds can act as catalysts or promoters due to their Lewis acid properties and redox capabilities. For energy storage, their ability to intercalate and de-intercalate metal ions makes them promising materials for lithium-ion batteries and other rechargeable cells.
These hydroxides are typically synthesized through precipitation methods using aqueous solutions of transition metal salts and bases, followed by drying or calcination to obtain solid materials with specific morphologies. The properties of the resulting compounds can be fine-tuned by varying reaction conditions such as pH, temperature, and concentration, making them versatile in both fundamental research and practical applications.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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Platinum(2+),tetraammine-, hydroxide (1:2), (SP-4-1)- | 15651-37-3 | H14N4O2Pt |
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Yttrium hydroxide(Y(OH)3) | 16469-22-0 | H3O3Y |
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Hexaaquavanadium(III)(3+) | 21374-21-0 | H6O6V |
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Copper chloride hydroxide (Cu2Cl(OH)3); Mineral-form | 12186-00-4 | ClCu2H3O3 |
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copper chloride oxide | 1332-40-7 | Cl2Cu4H6O6 |
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Zinc hydroxide | 20427-58-1 | H2O2Zn |
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cobalt trihydroxide | 1307-86-4 | CoH6O3 |
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Iron hydroxide(Fe(OH)2) | 18624-44-7 | FeH4O2 |
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Copper Oxychloride | 1332-65-6 | ClCuHO |
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Cadmium hydroxide | 21041-95-2 | CdH2O2 |
Related Literature
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Luke L. Lairson,Warren W. Wakarchuk Chem. Commun., 2007, 365-367
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Bidou Wang,Xifeng Chen Analyst, 2014,139, 5695-5699
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Dhamodaran Manikandan,S. Amirthapandian,I. S. Zhidkov,A. I. Kukharenko,S. O. Cholakh,Ramaswamy Murugan Phys. Chem. Chem. Phys., 2018,20, 6500-6514
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Bo Cao,Yin Wei Chem. Commun., 2018,54, 2870-2873
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Lei Yang,Yuan Zeng,Haibo Wu,Chunwu Zhou,Lei Tao J. Mater. Chem. B, 2020,8, 1383-1388
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