Transition metal oxoanionic compounds
Transition metal oxoanionic compounds are a diverse class of inorganic compounds that consist of a transition metal ion coordinated with one or more oxoanions. These compounds are characterized by the presence of an anion derived from oxygen, such as peroxo (O2^2-), superoxo (O2^-), or hydroperxo (HO2^-) groups, along with a central transition metal atom. Transition metals in these complexes can vary widely across different groups, providing a rich array of electronic and structural properties.
The geometry around the transition metal can range from tetrahedral to octahedral, depending on the nature of the ligands involved. These compounds often exhibit unique redox behaviors due to their multiple oxidation states, making them valuable in catalysis, spectroscopy, and materials science applications. For instance, they are used as catalysts in organic synthesis reactions, particularly in the hydrogenation and oxidation processes.
Furthermore, transition metal oxoanionic compounds play a crucial role in environmental chemistry, where their redox properties can be harnessed for contaminant remediation. Their ability to undergo reversible redox transformations allows them to act as powerful oxidizing agents or reducing agents, making them indispensable tools in various scientific and industrial processes.
- Transition metal nitrates
- Transition metal phosphates
- Transition metal perchlorates
- Transition metal sulfates
- Transition metal sulfites
- Transition metal hydroxides
- Transition metal perrhenates
- Transition metal bromates
- Transition metal molybdates
- Transition metal pyrophosphates
- Transition metal aluminates
- Transition metal chromates
- Transition metal silicates
- Transition metal metavanadates
- Transition metal tungstates
- Transition metal stannates
- Transition metal nitrites
- Transition metal tellurates
- Transition metal arsenates
- Transition metal chlorates
- Transition metal iodates
- Transition metal borates
- Transition metal selenites
- Transition metal phosphonates
- Transition metal tellurites
- Transition metal selenates
- Transition metal hypophosphites
Related Literature
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Yong Ping Huang,Tao Tao,Zheng Chen,Wei Han,Ying Wu,Chunjiang Kuang,Shaoxiong Zhou,Ying Chen J. Mater. Chem. A, 2014,2, 18831-18837
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Fereshteh Bayat Environ. Sci.: Nano, 2021,8, 367-389
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Xing Zhao,Lu Bai,Rui-Ying Bao,Zheng-Ying Liu,Ming-Bo Yang,Wei Yang RSC Adv., 2017,7, 46297-46305
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Yaling Zhang,Chunhui Dai,Shiwei Zhou,Bin Liu Chem. Commun., 2018,54, 10092-10095
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