Tetraorganoarsonium salts
Tetraorganosulfurium salts, also known as tetraorganothiophosphonium salts or tetraorganoselenonium salts depending on the substituent group, are a class of organometallic compounds. These salts feature a positively charged central sulfur, selenium, or phosphorus atom surrounded by four organic groups, typically alkyl or aryl derivatives. Tetraorganosulfurium salts exhibit various applications in synthetic chemistry, particularly in the synthesis and functionalization of organic molecules due to their unique Lewis acidic properties. They play crucial roles as catalysts in certain organometallic reactions, facilitating transformations that are otherwise challenging. Additionally, these compounds have found uses in materials science for their potential in electrochemical and sensor applications, showcasing their broad utility across different scientific disciplines.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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Bromide-Tetramethylarsonium(1+) | 34618-96-7 | C4H13AsO |
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Arsonium,(carboxymethyl)trimethyl-, inner salt | 64436-13-1 | C5H11AsO2 |
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2-(trimethylarsonio)propanoate | 117929-08-5 | C6H13AsO2 |
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Lactyltrimethylarsonium betaine | 68688-60-8 | C6H13AsO3 |
Related Literature
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Robert P. Davies,Maria A. Giménez,Laura Patel,Andrew J. P. White Dalton Trans., 2008, 5705-5707
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Eunhak Lim,Jiyoung Heo,Seong Keun Kim Nanoscale, 2019,11, 11369-11378
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José M. Rivera,Mariana Martín-Hidalgo,Jean C. Rivera-Ríos Org. Biomol. Chem., 2012,10, 7562-7565
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Jialiang Yuan,Ran Dong,Yuan Li,Yang Liu,Zhuo Zheng,Yuxia Liu,Yan Sun,Benhe Zhong,Zhenguo Wu,Xiaodong Guo Chem. Commun., 2021,57, 13004-13007
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Kaiyuan Huang,Wangkang Qiu,Meilian Ou,Xiaorui Liu,Zenan Liao,Sheng Chu RSC Adv., 2020,10, 18824-18829
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