Production Method 1

867-13-0

1030268-24-6

123-11-5

98017-60-8

Reaction Conditions

1.1 Reagents: Tetrabutylammonium fluoride Solvents: Tetrahydrofuran ;  30 °C
1.2 Reagents: Sodium hydride Solvents: Dimethyl sulfoxide ;  rt

Reference

Photoredox-catalyzed oxo-amination of aryl cyclopropanes

Ge, Liang; Wang, Ding-Xing; Xing, Renyi; Ma, Di; Walsh, Patrick J. ; et al, Nature Communications (2019, 2019, 10(1), 1-9

Production Method 2

637-69-4

98017-60-8

Reaction Conditions

1.1 Reagents: Sodium dithionite Solvents: Water ;  16 h, pH 7, rt

Reference

Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution

Wei, Yang; Tinoco, Antonio ; Steck, Viktoria; Fasan, Rudi ; Zhang, Yong, Journal of the American Chemical Society (2018, 2018, 140(5), 1649-1662

Production Method 3

637-69-4

98017-60-8

Reaction Conditions

1.1 Catalysts: Copper, [dihydrobis(1H-pyrazolato-κN1)borato(1-)-κN2,κN2′]- Solvents: 1,2-Dichloroethane

Reference

BpCu-Catalyzed Cyclopropanation of Olefins: A Simple System That Operates under Homogeneous and Heterogeneous Conditions (Bp = Dihydridobis(pyrazolyl)borate)

Diaz-Requejo, M. Mar; Nicasio, M. Carmen; Perez, Pedro J., Organometallics (1998, 1998, 17(14), 3051-3057

Production Method 4

637-69-4

98017-60-8

1520-50-9

Reaction Conditions

1.1 Catalysts: 2803878-20-6 Solvents: N,N-Dimethylformamide-d7 ;  30 h, 40 °C

Reference

A Novel M8L6 Cubic Cage That Binds Tetrapyridyl Porphyrins: Cage and Solvent Effects in Cobalt-Porphyrin-Catalyzed Cyclopropanation Reactions

Mouarrawis, Valentinos; Bobylev, Eduard O.; de Bruin, Bas; Reek, Joost N. H., Chemistry - A European Journal (2021, 2021, 27(32), 8390-8397

Production Method 5

637-69-4

98017-60-8

Reaction Conditions

1.1 Reagents: Sodium dodecyl sulfate Catalysts: Iron(4+), chloro[[4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis[1-… Solvents: Water ;  15 min, rt
1.2 1 h, rt

Reference

Cationic iron porphyrins with sodium dodecyl sulphate for micellar catalysis of cyclopropanation reactions

Maaskant, Ruben V.; Polanco, Ehider A.; van Lier, Roos C. W.; Roelfes, Gerard, Organic & Biomolecular Chemistry (2020, 2020, 18(4), 638-641

Production Method 6

1774-47-6

1929-30-2

98017-60-8

Reaction Conditions

1.1 Reagents: Sodium hydride Solvents: Tetrahydrofuran ;  25 °C; 1 h
1.2 Solvents: Dimethyl sulfoxide ;  12 h, rt
1.3 -

Reference

A Gold- and Bronsted Acid Catalytic Interplay Towards the Synthesis of Highly Substituted Tetrahydrocarbazoles

Garayalde, David; Rusconi, Giulia; Nevado, Cristina, Helvetica Chimica Acta (2017, 2017, 100(3),

Production Method 7

637-69-4

98017-60-8

Reaction Conditions

1.1 Catalysts: Palladium diacetate ;  rt

Reference

Intermolecular metal-catalyzed carbenoid cyclopropanations

Davies, Huw M. L.; Antoulinakis, Evan G., Organic Reactions (Hoboken, 2001, ,

Production Method 8

637-69-4

98017-60-8

Reaction Conditions

1.1 Catalysts: Ruthenium(1+), aquabromodicarbonyl[1-(5,7-dimethyl-1,8-naphthyridin-2-yl-κN1)-1,… Solvents: Dichloromethane ;  6 h, 40 °C

Reference

A RuII-N-heterocyclic carbene (NHC) complex from metal-metal singly bonded diruthenium(I) precursor: Synthesis, structure and catalytic evaluation

Sinha, Arup; Daw, Prosenjit; Rahaman, S. M. Wahidur; Saha, Biswajit; Bera, Jitendra K., Journal of Organometallic Chemistry (2011, 2011, 696(6), 1248-1257

Production Method 9

637-69-4

98017-60-8

97-71-2

Reaction Conditions

1.1 Catalysts: 2097677-62-6 Solvents: Dichloromethane ;  rt

Reference

The elusive palladium-diazo adduct captured: synthesis, isolation and structural characterization of [(ArNHC-PPh2)Pd(η2-N2C(Ph)CO2Et)]

Rull, Silvia G.; Alvarez, Eleuterio; Fructos, Manuel R.; Belderrain, Tomas R.; Perez, Pedro J., Chemistry - A European Journal (2017, 2017, 23(32), 7667-7671

ethyl 2-(4-methoxyphenyl)cyclopropane-1-carboxylate Raw materials

• Triethyl phosphonoacetate
• Trimethylsulfoxonium iodide
• 4-Methoxycinnamic Acid Ethyl Ester
• Sulfur, iodotrimethyloxo-
• p-Methoxybenzaldehyde
• p-Methoxystyrene

ethyl 2-(4-methoxyphenyl)cyclopropane-1-carboxylate Preparation Products

• 2-Butenedioic acid, diethyl ester (1520-50-9)
• ethyl 2-phenylcyclopropanecarboxylate (97-71-2)
• ethyl 2-(4-methoxyphenyl)cyclopropane-1-carboxylate (98017-60-8)

• 1. An Assessment of the Laminar Hypersonic Double-Cone Experiments in the LENS-XX Tunnel
  JaideepRay,PatrickBlonigan,EricT.Phipps,KathrynMaupin
• 2. An aquatic host–guest complex between a supramolecular G-quadruplex and the anticancer drug doxorubicin?
  José M. Rivera,Mariana Martín-Hidalgo,Jean C. Rivera-Ríos Org. Biomol. Chem., 2012,10, 7562-7565
• 3. An investigation of the electrochemical delithiation process of carbon coated α-Fe2O3nanoparticles
  Adrian Brandt,Florian Winter,Sebastian Klamor,Frank Berkemeier,Jatinkumar Rana,Rainer P?ttgen,Andrea Balducci J. Mater. Chem. A, 2013,1, 11229-11236
• 4. An amphipathic trans-acting phosphorothioate RNA element delivers an uncharged phosphorodiamidate morpholino sequence in mdx mouse myotubes?
  H. V. Jain,D. Verthelyi,S. L. Beaucage RSC Adv., 2017,7, 42519-42528
• 5. Aluminium alkyl and aryloxide complexes of pyrazine and bipyridines: synthesis and structure?
  Doug Ogrin,Laura H. van Poppel,Simon G. Bott,Andrew R. Barron Dalton Trans., 2004, 3689-3694

• Solvents and Organic Chemicals Organic Compounds Benzenoids Phenol ethers Anisoles

• 78473-70-8(3,4-Bismethoxy rac Enterolactone)
• 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
• 2680771-01-9(4-cyclopentyl-3-{(prop-2-en-1-yloxy)carbonylamino}butanoic acid)
• 1444113-98-7(N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide)
• 332062-08-5(Fmoc-S-3-amino-4,4-diphenyl-butyric acid)
• 1270529-38-8(1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol)
• 941977-17-9(N'-(3-chloro-2-methylphenyl)-N-2-(dimethylamino)-2-(naphthalen-1-yl)ethylethanediamide)
• 2138166-62-6(2,2-Difluoro-3-[methyl(2-methylbutyl)amino]propanoic acid)
• 89640-58-4(2-Iodo-4-nitrophenylhydrazine)
• 1449132-38-0(3-Fluoro-5-(2-fluoro-5-methylbenzylcarbamoyl)benzeneboronic acid)