Cas no 97534-82-2 ((S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid)

(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid structure
97534-82-2 structure
Product Name:(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid
CAS No:97534-82-2
MF:C12H13NO5
MW:251.235323667526
MDL:MFCD00274193
CID:91141
PubChem ID:24870606
Update Time:2024-10-25

(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid Chemical and Physical Properties

Names and Identifiers

    • (S)-3-((Benzyloxy)carbonyl)oxazolidine-4-carboxylic acid
    • (S)-()-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid
    • (S)-CBZ-Oxaproline
    • (S)-(-)-3-(Benzyloxycarbonyl)oxazolidine-4-carboxylic acid
    • (S)-(-)-3-Z-4-Oxazolidinecarboxylic acid
    • (S)-Z-oxaproline
    • 3,4-Oxazolidinedicarboxylic acid 3-(phenylmethyl) ester
    • 3,4-Oxazolidinedicarboxylic acid, 3-(phenylmethyl) ester, (S)- (ZCI)
    • (-)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid
    • (4S)-3-[(Benzyloxy)carbonyl]-1,3-oxazolidine-4-carboxylic acid
    • (S)-3-Benzyloxycarbonyl-4-oxazolidine carboxylic acid
    • 97534-82-2
    • XRRRGBIMHQARMF-JTQLQIEISA-N
    • CS-0204772
    • DTXSID60350876
    • G69458
    • (S)-(-)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid, 98%
    • SCHEMBL628051
    • AKOS015889181
    • (s)-3-(benzyloxycarbonyl)oxazolidine-4-carboxylic acid
    • MFCD00274193
    • (S)-(-)-3-(Benzyloxycarbonyl)-4-oxazolidinecarboxylic acid
    • (S)-(+)-3-Benzyloxycarbonyl-4-oxazolidinecarboxylic acid
    • AS-70276
    • (4S)-3-phenylmethoxycarbonyl-1,3-oxazolidine-4-carboxylic acid
    • (S)-Oxazolidine-3,4-dicarboxylic acid 3-benzyl ester
    • S-N-Benzyloxycarbonyl-oxaproline
    • (S)-3-((Benzyloxy)carbonyl)oxazolidine-4-carboxylicacid
    • (S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid
    • MDL： MFCD00274193
    • Inchi： 1S/C12H13NO5/c14-11(15)10-7-17-8-13(10)12(16)18-6-9-4-2-1-3-5-9/h1-5,10H,6-8H2,(H,14,15)/t10-/m0/s1
    • InChI Key： XRRRGBIMHQARMF-JTQLQIEISA-N
    • SMILES： C(N1COC[C@H]1C(=O)O)(=O)OCC1C=CC=CC=1

Computed Properties

  • Exact Mass: 251.079
  • Monoisotopic Mass: 251.079
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 1
  • Hydrogen Bond Acceptor Count: 6
  • Heavy Atom Count: 18
  • Rotatable Bond Count: 5
  • Complexity: 314
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 1
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Surface Charge: 0
  • XLogP3: 1
  • Topological Polar Surface Area: 76.1

Experimental Properties

  • Color/Form: White powder
  • Density: 1.385
  • Melting Point: 74-78?°C (lit.)
  • Boiling Point: 454.8±45.0 °C at 760 mmHg
  • Flash Point: 228.9±28.7 °C
  • Refractive Index: 1.582
  • PSA: 76.07000
  • LogP: 1.00400
  • Optical Activity: [α]20/D ?92°, c =?1 in chloroform
  • Solubility: Insoluble in water
  • Vapor Pressure: 0.0±1.2 mmHg at 25°C

(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid Security Information

  • Signal Word：warning
  • Hazard Statement： H303+H313+H333
  • Warning Statement： P264+P280+P305+P351+P338+P337+P313
  • Hazardous Material transportation number：NONH for all modes of transport
  • WGK Germany：3
  • Safety Instruction： 24/25
  • Storage Condition：storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)

(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid Pricemore >>

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(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid Production Method

Production Method 1

Reaction Conditions
Reference
Aralkylcarbamoyl peptide alcohols
, United States, , ,

Production Method 2

Reaction Conditions
1.1 Reagents: Sodium hydroxide Solvents: Water
1.2 Reagents: Sodium bicarbonate Solvents: Acetone
1.3 -
1.4 Reagents: Hydrochloric acid Solvents: Water
Reference
Optically active 4-oxaproline derivatives: new useful chiral synthons derived from serine and threonine
Falorni, Massimo; Conti, Sandra; Giacomelli, Giampaolo; Cossu, Sergio; Soccolini, Francesco, Tetrahedron: Asymmetry, 1995, 6(1), 287-94

Production Method 3

Reaction Conditions
1.1 Reagents: Camphorsulfonic acid Solvents: Benzene
1.2 -
1.3 Solvents: Ethyl acetate
1.4 Reagents: Sodium bicarbonate Solvents: Water
Reference
The facile production of N-methyl amino acids via oxazolidinones
Aurelio, Luigi; Brownlee, Robert T. C.; Hughes, Andrew B.; Sleebs, Brad E., Australian Journal of Chemistry, 2000, 53(5), 425-433

(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid Raw materials

(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid Preparation Products

(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid Suppliers

Amadis Chemical Company Limited
Gold Member
Audited Supplier Audited Supplier
(CAS:97534-82-2)(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid
Order Number:A1207728
Stock Status:in Stock
Quantity:5g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 03:47
Price ($):202.0

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Amadis Chemical Company Limited
(CAS:97534-82-2)(S)-(-)-3-Z-4-Oxazolidinecarboxylic Acid
A1207728
Purity:99%
Quantity:5g
Price ($):202.0
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