- A convenient synthesis of 2'-5'-linked oligoribonucleotidesBy Hayakawa, Y. et al, Tetrahedron Letters, 1985, 26(6), 761-4
Cas no 97205-04-4 (2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI))
![2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI) structure](https://ossimg.kuujia.com/scimg/97500/97205-04-4x500.png)
97205-04-4 structure
Product Name:2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI)
CAS No:97205-04-4
MF:C48H50ClN6O10PSi
MW:965.457072734833
CID:5598695
Update Time:2023-09-01
2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI) Chemical and Physical Properties
Names and Identifiers
-
- 2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI)
-
- Inchi： 1S/C48H50ClN6O10PSi/c1-47(2,3)67(5,6)65-42-40(29-60-48(32-15-9-7-10-16-32,33-17-11-8-12-18-33)34-21-25-36(59-4)26-22-34)61-46(54-31-53-41-44(50)51-30-52-45(41)54)43(42)64-66(58,63-39-20-14-13-19-38(39)49)62-37-27-23-35(24-28-37)55(56)57/h7-28,30-31,40,42-43,46H,29H2,1-6H3,(H2,50,51,52)/t40-,42-,43-,46-,66?/m1/s1
- InChI Key： IAPNMTIEACEUHA-UTESLAMRSA-N
- SMILES： C(C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC(OC)=CC=1)OC[C@H]1O[C@@H](N2C=NC3C(=NC=NC2=3)N)[C@H](OP(=O)(OC2C=CC=CC=2Cl)OC2C=CC(N(=O)=O)=CC=2)[C@@H]1O[Si](C)(C)C(C)(C)C
2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI) Production Method
Production Method 1
Reaction Conditions
1.1R:t-BuMgCl, S:THF
Reference
2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI) Raw materials
- Adenosine, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-
- PHOSPHOROCHLORIDIC ACID, 2-CHLOROPHENYL 4-NITROPHENYL ESTER
2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI) Preparation Products
2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI) Related Literature
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Guiying Zhang,Maosheng Cheng,Yanni Li,Keliang Liu,Lifeng Cai Chem. Commun., 2013,49, 11086-11088
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Jason Wan Lab Chip, 2020,20, 4528-4538
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Tengfei Yu,Yuehan Wu,Wei Li,Bin Li RSC Adv., 2014,4, 34134-34143
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Qiaoe Wang,Meiling Lian,Xiaowen Zhu,Xu Chen RSC Adv., 2021,11, 192-197
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Joo Chuan Yeo,Kenry Lab Chip, 2016,16, 4082-4090
97205-04-4 (2'-Adenylic acid, 3'-O-[(1,1-dimethylethyl)dimethylsilyl]-5'-O-[(4-methoxyphenyl)diphenylmethyl]-, 2-chlorophenyl 4-nitrophenyl ester (9CI)) Related Products
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