Production Method 1

33906-65-9

960-71-4

Reaction Conditions

1.1 15 min, 200 °C

Reference

Stabilization and Transfer of the Transient [Mes*P4]- Butterfly Anion Using BPh3

Borger, Jaap E.; Ehlers, Andreas W.; Lutz, Martin; Slootweg, J. Chris; Lammertsma, Koop, Angewandte Chemie, 2016, 55(2), 613-617

Production Method 2

960-71-4

Reaction Conditions

1.1 Reagents: Triisopropyl borate ,  Sodium Solvents: Toluene ;  4 h, 65 °C

Reference

Preparation of triphenylboron

Xu, Jiantao; Han, Minghan; Wang, Guogao, Shiyou Huagong, 2013, 42(4), 415-418

Production Method 3

33906-65-9

960-71-4

Reaction Conditions

1.1 -78 °C → 200 °C; 15 min, 200 °C

Reference

Iron Complexes of a Proton-Responsive SCS Pincer Ligand with a Sensitive Electronic Structure

Skubi, Kazimer L. ; Hooper, Reagan X.; Mercado, Brandon Q.; Bollmeyer, Melissa M.; MacMillan, Samantha N. ; et al, Inorganic Chemistry, 2022, 61(3), 1644-1658

Production Method 4

87005-57-0

960-71-4

Reaction Conditions

Reference

Preparation of triarylboranes

, United States, , ,

Production Method 5

960-71-4

Reaction Conditions

1.1 Reagents: Boron trifluoride etherate ,  Magnesium ,  Iodine Solvents: Xylene

Reference

Cost-effective preparation method of triphenylboron using magnesium powder and bromobenzene

, China, , ,

Production Method 6

960-71-4

Reaction Conditions

1.1 Reagents: Boron trifluoride

Reference

Hydroxylamine-O-sulfonic acid

Erdik, Ender; Saczewski, Jaroslaw, e-EROS Encyclopedia of Reagents for Organic Synthesis, 2013, 1, 1-10

Production Method 7

960-71-4

Reaction Conditions

1.1 Reagents: Boron trifluoride etherate Solvents: Tetrahydrofuran ;  -20 °C

Reference

Photobase generator

, World Intellectual Property Organization, , ,

Production Method 8

33906-65-9

960-71-4

Reaction Conditions

1.1 Reagents: Mesitylene ;  3 h, 170 °C

Reference

Preparation of triarylboranes and their complexes by thermal decomposition of trialkylammonium borates

, Japan, , ,

Production Method 9

971-66-4

960-71-4

Reaction Conditions

1.1 Reagents: Mesitylene ;  180 °C

Reference

Preparation of ionic-impurity-free triarylborane complexes

, Japan, , ,

Production Method 10

960-71-4

Reaction Conditions

1.1 Reagents: Boron trifluoride etherate ,  Magnesium ,  Iodine Solvents: Diethyl ether

Reference

Organoboranes. 44. A convenient, highly efficient synthesis of triorganylboranes via a modified organometallic route

Brown, Herbert C.; Racherla, Uday S., Journal of Organic Chemistry, 1986, 51(4), 427-32

Production Method 11

960-71-4

Reaction Conditions

Reference

Boron compounds. V. Hydrogenation of trialkyl- and triarylboranes

Koester, Roland; Bruno, Guenter; Binger, Paul, Justus Liebigs Annalen der Chemie, 1961, 644, 1-22

Production Method 12

960-71-4

Reaction Conditions

1.1 Reagents: Triisopropyl borate ,  Sodium Solvents: Benzene ,  Cyclohexane ;  rt → 80 °C; 40 min, 80 °C

Reference

Preparation method of triarylborane

, China, , ,

Production Method 13

3262-89-3

960-71-4

Reaction Conditions

1.1 Reagents: Potassium carbonate Solvents: Dimethylformamide ;  1 h, 130 °C

Reference

Unexpected Formation of Triphenylborane from Phenylboronic Acid and Its Use as an Intermediate in Palladium-Catalyzed Cross Coupling Reaction

Motokura, Ken; Fukuda, Takuma; Manaka, Yuichi, ChemistrySelect, 2019, 4(35), 10501-10505

Production Method 14

960-71-4

Reaction Conditions

1.1 Reagents: Boron trifluoride Solvents: Diethyl ether ;  0 °C; 2 h, 0 °C; 0 °C → rt; overnight, rt

Reference

Controlling the Lewis Acidity and Polymerizing Effectively Prevent Frustrated Lewis Pairs from Deactivation in the Hydrogenation of Terminal Alkynes

Liu, Qiang; Yang, Liu; Yao, Chenfei; Geng, Jiao; Wu, Youting; et al, Organic Letters, 2021, 23(9), 3685-3690

Production Method 15

33906-65-9

960-71-4

Reaction Conditions

Reference

Crystal structure of tetraphenyldiboroxane a monomer diboroxane

Lange, Thomas; Bohme, Uwe; Roewer, Gerhard, Inorganic Chemistry Communications, 2002, 5(6), 377-379

Production Method 16

960-71-4

Reaction Conditions

Reference

Photosensitive resin composition with excellent curability

, Japan, , ,

Production Method 17

960-71-4

Reaction Conditions

Reference

Product subclass 26: aryl- and hetarylboranes

Miyaura, N., Science of Synthesis, 2004, 6, 677-696

Production Method 18

960-71-4

Reaction Conditions

1.1 Solvents: Chloroform-d

Reference

Borylated carbodiimides

Einholz, Wolfgang; Haubold, Wolfgang, Zeitschrift fuer Naturforschung, 1986, (11), 1367-72

Production Method 19

960-71-4

Reaction Conditions

1.1 Reagents: Boron trifluoride etherate ,  Magnesium Solvents: Diethyl ether

Reference

Ultrasonics in organoborane chemistry. Rapid synthesis of triorganylboranes via a modified organometallic route

Brown, Herbert C.; Racherla, Uday S., Tetrahedron Letters, 1985, 26(36), 4311-14

Production Method 20

501-65-5

4151-77-3

960-71-4

Reaction Conditions

1.1 Catalysts: Acetic acid

Reference

Bora-aromatic systems. VI. Dehalogenation of organoboron dihalides in the search for borenes

Eisch, John J.; Becker, Hans P., Journal of Organometallic Chemistry, 1979, 171(2), 141-53

Triphenylborane Raw materials

• Boroxin,2,4,6-triphenyl-
• Diphenylacetylene
• Nickel, bis[(cyano-C)triphenylborato(1-)-N]bis(hexanedinitrile-N)-
• Borate(1-), tetraphenyl-, hydrogen (1:1)
• dibromo(phenyl)borane
• Pyridine-triphenylborane

Triphenylborane Preparation Products

• Triphenylborane (960-71-4)

• 1. EWOD-driven droplet microfluidic device integrated with optoelectronic tweezers as an automated platform for cellular isolation and analysis?
  Gaurav J. Shah,Eric P.-Y. Chiou,Ming C. Wu,Chang-Jin “CJ” Kim Lab Chip, 2009,9, 1732-1739
• 2. Emulsion technologies for multicellular tumour spheroid radiation assays?
  Kay S. McMillan,Anthony G. McCluskey,Annette Sorensen,Marie Boyd,Michele Zagnoni Analyst, 2016,141, 100-110
• 3. Dissociative dynamics of O2 on Ag(110)?
  Ivor Lon?ari? Phys. Chem. Chem. Phys., 2015,17, 9436-9445
• 4. Excellent humidity sensor based on ultrathin HKUST-1 nanosheets?
  Qiaoe Wang,Meiling Lian,Xiaowen Zhu,Xu Chen RSC Adv., 2021,11, 192-197
• 5. Excitable dynamics in the bromate–sulfite–ferrocyanide reaction
  J. Zagora,M. Vosla?,L. Schreiberová,I. Schreiber Phys. Chem. Chem. Phys., 2002,4, 1284-1291

• Solvents and Organic Chemicals Organic Compounds Hydrocarbons

• 3244-41-5(Potassium tetraphenylborate 97%)
• 62025-67-6(Boranthrene, 5,10-dihydro-5,10-dimethyl-)
• 3087-82-9(Borate(1-),tetraphenyl-, cesium (1:1))
• 51016-92-3(Trimethylammonium tetraphenylborate)
• 143-66-8(Sodium Tetraphenylboroate)
• 14485-20-2(Borate(1-),tetraphenyl-, lithium (1:1))
• 14637-34-4(Borate(1-),tetraphenyl-, ammonium (1:1))
• 15525-13-0(Tetramethylammonium Tetraphenylborate(1-))
• 68132-95-6(Lithium dimethyldiphenylborate(1-))
• 6962-78-3(Borane,tri-1-naphthalenyl-)