Production Method 1

25015-63-8

942069-95-6

Reaction Conditions

1.1 Catalysts: 2489284-98-0 Solvents: Cyclohexene ;  18 h, 110 °C

Reference

Direct C-H Borylation of Arenes Catalyzed by Saturated Hydride-Boryl-Iridium-POP Complexes: Kinetic Analysis of the Elemental Steps

Esteruelas, Miguel A. ; Martinez, Antonio; Olivan, Montserrat; Onate, Enrique, Chemistry - A European Journal, 2020, 26(55), 12632-12644

Production Method 2

25015-63-8

942069-95-6

1165935-95-4

Reaction Conditions

1.1 Reagents: 4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine Catalysts: Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium ;  1 min, rt
1.2 2 h, 80 °C

Reference

Harnessing C-H Borylation/Deborylation for Selective Deuteration, Synthesis of Boronate Esters, and Late Stage Functionalization

Kallepalli, Venkata A.; Gore, Kristin A.; Shi, Feng; Sanchez, Luis; Chotana, Ghayoor A.; et al, Journal of Organic Chemistry, 2015, 80(16), 8341-8353

Production Method 3

73183-34-3

942069-95-6

Reaction Conditions

1.1 Reagents: 2,6-Bis(1-methylethyl)-N-(2-pyridinylmethylene)benzenamine Catalysts: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium Solvents: Heptane ;  < 1 min, rt; 18 h, rt → reflux

Reference

Preparation of cyanotriazolylphenylisoxazolines as pesticides.

, World Intellectual Property Organization, , ,

3,4,5-Trichlorophenylboronic Acid Pinacol Ester Raw materials

• Bis(pinacolato)diborane
• Pinacolborane

3,4,5-Trichlorophenylboronic Acid Pinacol Ester Preparation Products

• 4,4,5,5-Tetramethyl-2-(2,3,4-trichlorophenyl)-1,3,2-dioxaborolane (1165935-95-4)
• 3,4,5-Trichlorophenylboronic Acid Pinacol Ester (942069-95-6)

• 1. An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage
  Mark D. Allendorf,Alauddin Ahmed,Tom Autrey,Jeffrey Camp,Eun Seon Cho,Maciej Haranczyk,Abhi Karkamkar,Di-Jia Liu,Katie R. Meihaus,Iffat H. Nayyar,Roman Nazarov,Donald J. Siegel,Vitalie Stavila,Jeffrey J. Urban,Srimukh Prasad Veccham,Brandon C. Wood Energy Environ. Sci., 2018,11, 2784-2812
• 2. An atom efficient route to N-aryl and N-alkyl pyrrolines by transition metal catalysis?
  Supaporn Sawadjoon,Joseph S. M. Samec Org. Biomol. Chem., 2011,9, 2548-2554
• 3. An analyte-triggered artificial peroxidase system based on dimanganese complex for a versatile enzyme assay?
  Suji Lee,Min Su Han Chem. Commun., 2021,57, 9450-9453
• 4. An approach to 7-aza-1-phosphanorbornane complexes: strain promoted rearrangement of 1-iminylphosphirane complexes and cycloaddition with olefins?
  Yang Xu,Min Wang,Donghui Wei,Rongqiang Tian,Zheng Duan,Fran?ois Mathey Dalton Trans., 2019,48, 5523-5526
• 5. An air-stable organometallic polymer containing titanafluorene moieties obtained by the Sonogashira–Hagihara cross-coupling polycondensation?
  Alvin Tanudjaja,Shinsuke Inagi,Fusao Kitamura,Toshikazu Takata,Ikuyoshi Tomita Dalton Trans., 2021,50, 3037-3043

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Chlorobenzenes
• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Halobenzenes Chlorobenzenes

• 502630-89-9(1,3,2-Dioxaborolane, 2-(3-chloro-5-methylphenyl)-4,4,5,5-tetramethyl-)
• 68716-51-8(2-(3,5-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 942069-73-0(3,5-Dichloro-4-methylphenylboronic acid, pinacol ester)
• 870195-94-1(2-(2-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 445303-10-6(3-Chloro-4-methylphenylboronic acid pinacol ester)
• 942069-71-8(3,4-Dichloro-5-methylphenylphenylboronic acid, pinacol ester)
• 635305-47-4(2-(3-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 68716-50-7(2,4-Dichlorophenylboronic acid, pinacol ester)
• 195062-61-4(4-Chlorophenylboronic acid, pinacol ester)
• 401797-02-2(2-(3,4-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)