- Novel organic electroluminescent compounds having high luminous efficiency for improved driving lifespan and greater efficiency in electroluminescent devices, and organic electroluminescent devices comprising the organic electroluminescent compounds, World Intellectual Property Organization, , ,
Cas no 934545-80-9 (3-Bromo-9-(naphthalen-2-yl)-9H-carbazole)
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole is a high-purity organic compound primarily utilized in the synthesis of advanced materials, particularly for optoelectronic applications. Its structure combines a carbazole core with a naphthalene substituent and a bromine functional group, offering excellent charge-transport properties and tunable electronic characteristics. This compound is valued for its role in developing organic light-emitting diodes (OLEDs), organic photovoltaics (OPVs), and other semiconductor devices. The bromine moiety further enhances its reactivity, facilitating cross-coupling reactions for tailored molecular design. With high thermal stability and efficient luminescence, it serves as a key intermediate in materials science research and industrial applications requiring precise molecular engineering.
934545-80-9 structure
Product Name:3-Bromo-9-(naphthalen-2-yl)-9H-carbazole
CAS No:934545-80-9
MF:C22H14BrN
MW:372.257264614105
MDL:MFCD26127422
CID:1982382
PubChem ID:253661442
Update Time:2025-05-27
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Chemical and Physical Properties
Names and Identifiers
-
- 3-bromo-9-(naphthalen-2-yl)-9H-carbazole
- 3-Bromo-9-(2-naphthyl)carbazole
- 3-bromo-9-naphthalen-2-ylcarbazole
- 9-(2-Naphthyl)-3-bromocarbazole
- N-(2-naphthyl)-3-bromocarbazole
- 3-bromo-9-(2-naphthalenyl)-9H-Carbazole
- 3-Bromo-9-(2-naphthyl)-9H-carbazole
- OL10003
- AK151472
- AX8288078
- J3.546.470K
- 3-broMo-9-(phthalen-2-yl)-9H-carbazole (B2NC)
- 3-Bromo-9-(2-naphthalenyl)-9H-carbazole (ACI)
- 3-Bromo-9-(naphthalen-2-yl)-9H-carbazole
-
- MDL: MFCD26127422
- Inchi: 1S/C22H14BrN/c23-17-10-12-22-20(14-17)19-7-3-4-8-21(19)24(22)18-11-9-15-5-1-2-6-16(15)13-18/h1-14H
- InChI Key: MBGUQKKYEOAENA-UHFFFAOYSA-N
- SMILES: BrC1C=C2C3C(N(C2=CC=1)C1C=C2C(C=CC=C2)=CC=1)=CC=CC=3
Computed Properties
- Exact Mass: 371.03100
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 24
- Rotatable Bond Count: 1
- Complexity: 451
- Topological Polar Surface Area: 4.9
Experimental Properties
- Melting Point: 131.0 to 135.0 deg-C
- PSA: 4.93000
- LogP: 6.69940
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Security Information
-
Symbol:
- Prompt:warning
- Hazard Statement: H315-H319
- Warning Statement: P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Customs Data
- HS CODE:2933990090
- Customs Data:
China Customs Code:
2933990090Overview:
2933990090. Other heterocyclic compounds containing only nitrogen heteroatoms. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:20.0%
Declaration elements:
Product Name, component content, use to, Please indicate the appearance of Urotropine, 6- caprolactam please indicate the appearance, Signing date
Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Alichem | A219005482-5g |
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole |
934545-80-9 | 95% | 5g |
$199.80 | 2023-08-31 | |
| abcr | AB474139-1 g |
3-Bromo-9-(2-naphthyl)carbazole, 97%; . |
934545-80-9 | 97% | 1g |
€83.60 | 2023-07-18 | |
| abcr | AB474139-5 g |
3-Bromo-9-(2-naphthyl)carbazole, 97%; . |
934545-80-9 | 97% | 5g |
€235.90 | 2023-07-18 | |
| Chemenu | CM140747-5g |
3-bromo-9-(naphthalen-2-yl)-9H-carbazole |
934545-80-9 | 95%+ | 5g |
$184 | 2022-09-28 | |
| TRC | B701073-50mg |
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole |
934545-80-9 | 50mg |
$ 50.00 | 2022-06-06 | ||
| TRC | B701073-100mg |
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole |
934545-80-9 | 100mg |
$ 65.00 | 2022-06-06 | ||
| TRC | B701073-500mg |
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole |
934545-80-9 | 500mg |
$ 135.00 | 2022-06-06 | ||
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | B857700-1g |
3-Bromo-9-(2-naphthyl)carbazole |
934545-80-9 | ≥98% | 1g |
¥53.10 | 2022-09-29 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B5028-5g |
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole |
934545-80-9 | 97.0%(LC&N) | 5g |
1090.0CNY | 2021-08-04 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B5028-1g |
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole |
934545-80-9 | 97.0%(LC&N) | 1g |
275.0CNY | 2021-08-04 |
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide ; 4 h, rt
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Potassium carbonate Catalysts: Copper , 18-Crown-6 Solvents: Dimethylformamide ; 24 h, 140 °C; 140 °C → rt
1.2 Reagents: Hydrochloric acid Solvents: Water ; 30 min, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ; 30 min, rt
Reference
- Preparation of carbazole compounds for electronic device, World Intellectual Property Organization, , ,
Production Method 3
Reaction Conditions
1.1 Reagents: Sodium tert-butoxide Catalysts: Tris(dibenzylideneacetone)dipalladium , 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl Solvents: Toluene ; rt → 108 °C; 3 h, 108 °C
Reference
- Adamantyl-containing carbazole-type organic compounds, organic electroluminescent device and electronic device comprising the same, China, , ,
Production Method 4
Reaction Conditions
1.1 Reagents: Potassium carbonate , Sodium sulfate Catalysts: Copper Solvents: Nitrobenzene ; 200 °C
Reference
- Amine based hole transport layer and carbazole-based light emitting auxiliary layer for organic electroluminescent device, Korea, , ,
Production Method 5
Reaction Conditions
1.1 Reagents: Sodium tert-butoxide Catalysts: Tri-tert-butylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: o-Xylene ; 16 h, 135 - 140 °C
Reference
- Preparation of (dibenzofuranyl)indolo[2,3-b]carbazole derivatives as organic light emitting layer and its applications in OLEDs, China, , ,
Production Method 6
Reaction Conditions
1.1 Reagents: Potassium carbonate Catalysts: 1,10-Phenanthroline , Cuprous iodide Solvents: Dimethylformamide ; 16 h, 150 °C
Reference
- Organic electroluminescence device and amine compound for organic electroluminescence device, United States, , ,
Production Method 7
Reaction Conditions
1.1 Reagents: Potassium acetate Catalysts: 1,10-Phenanthroline , Cuprous iodide Solvents: Dimethylformamide ; 18 h, rt → reflux
Reference
- Two organic host materials for organic optoelectronic element and display device, World Intellectual Property Organization, , ,
Production Method 8
Reaction Conditions
1.1 Reagents: Potassium carbonate Catalysts: 1,10-Phenanthroline , Cuprous iodide Solvents: Xylene ; 6 h, reflux
Reference
- Preparation of phosphindolo[2,3-b]carbazole 7-oxide derivatives for organic electroluminescent devices, Korea, , ,
Production Method 9
Reaction Conditions
1.1 Reagents: Sodium tert-butoxide Catalysts: Copper , 18-Crown-6 Solvents: Toluene ; 24 h, 100 °C
Reference
- Azacarbazole compounds as organic electronic device materials, World Intellectual Property Organization, , ,
Production Method 10
Reaction Conditions
1.1 Reagents: Potassium carbonate Catalysts: 1,10-Phenanthroline , Cuprous iodide , 18-Crown-6 Solvents: Dimethylformamide ; overnight, rt → reflux
Reference
- Preparation of heterocyclic compounds for organic electroluminescent devices, China, , ,
Production Method 11
Reaction Conditions
1.1 Catalysts: Tributylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene , Water ; 12 h, rt
Reference
- Organic light-emitting devices and displays with emitting layers employing multiple hosts, United States, , ,
Production Method 12
Reaction Conditions
1.1 Reagents: N-Bromosuccinimide Solvents: Tetrahydrofuran ; 20 h, rt
Reference
- Hole transport materials and organic electroluminescent devices using them, Korea, , ,
Production Method 13
Reaction Conditions
1.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl peroxide Solvents: Dichloromethane ; 12 h, rt
Reference
- New bipolar green host materials containing benzimidazole-carbazole moiety in phosphorescent OLEDsPark, Jung Hwan; Kim, Eun Kyung; El-Deeb, Ibrahim M.; Jung, Su Jin; Choi, Dae Hyuk; et al, Bulletin of the Korean Chemical Society, 2011, 32(3), 841-846
Production Method 14
Reaction Conditions
1.1 Reagents: Potassium carbonate , Cuprous iodide Catalysts: 18-Crown-6 Solvents: 1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone ; 5 h, reflux; reflux → rt
1.2 Reagents: Water ; rt; 30 min, rt
1.3 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide ; 40 min, 0 °C; overnight, rt
1.4 Reagents: Water
1.2 Reagents: Water ; rt; 30 min, rt
1.3 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide ; 40 min, 0 °C; overnight, rt
1.4 Reagents: Water
Reference
- preparation of 1,2-benzo[a]anthracene derivatives as organic electroluminescent materials, China, , ,
Production Method 15
Reaction Conditions
1.1 Reagents: Potassium carbonate Catalysts: Copper Solvents: Toluene ; rt → 150 °C; 24 h, 150 °C
Reference
- Preparation of anthracene-based compounds useful as electroluminescent material in OLED, China, , ,
Production Method 16
Reaction Conditions
1.1 Reagents: Potassium carbonate , Sodium sulfate Catalysts: Copper Solvents: Nitrobenzene ; 200 °C
Reference
- Heteroaryl compounds as organic electronic device materials, World Intellectual Property Organization, , ,
Production Method 17
Reaction Conditions
1.1 Reagents: Potassium carbonate , Sodium sulfate Catalysts: Copper Solvents: Nitrobenzene ; 200 °C
Reference
- Carbazole compounds for organic electronic device, Korea, , ,
Production Method 18
Reaction Conditions
1.1 Reagents: Sodium tert-butoxide Catalysts: Triphenylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: Toluene ; 100 °C
Reference
- Preparation of carbazole compounds as organic electronic device materials, World Intellectual Property Organization, , ,
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Raw materials
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Preparation Products
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Suppliers
Amadis Chemical Company Limited
Gold Member
(CAS:934545-80-9)3-Bromo-9-(naphthalen-2-yl)-9H-carbazole
Order Number:A851187
Stock Status:in Stock
Quantity:100g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 07:34
Price ($):211.0
Email:[email protected]
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
(CAS:934545-80-9)N-(2-萘基)-3-溴咔唑
Order Number:LE26860937
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:59
Price ($):discuss personally
Email:[email protected]
3-Bromo-9-(naphthalen-2-yl)-9H-carbazole Related Literature
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1. An amorphous lanthanum–iridium solid solution with an open structure for efficient water splitting?Wei Sun,Chenglong Ma,Xinlong Tian,Jianjun Liao,Ji Yang,Chengjun Ge,Weiwei Huang J. Mater. Chem. A, 2020,8, 12518-12525
-
Bidou Wang,Xifeng Chen Analyst, 2014,139, 5695-5699
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Quan Xiang,Yiqin Chen,Zhiqin Li,Kaixi Bi,Guanhua Zhang,Huigao Duan Nanoscale, 2016,8, 19541-19550
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J. M. Granadino-Roldán,M. Fernández-Gómez,A. Navarro,T. Pe?a Ruiz,U. A. Jayasooriya Phys. Chem. Chem. Phys., 2004,6, 1133-1143
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