Production Method 1

1089-59-4

17946-71-3

934-56-5

Reaction Conditions

1.1 Solvents: Tetrahydrofuran

Reference

Reactions of trialkylstannane anions, R3Sn-, with arylstannanes, ArSnR3

Mochida, Kunio, Bulletin of the Chemical Society of Japan, 1987, 60(9), 3299-306

Production Method 2

98-04-4

16643-09-7

934-56-5

Reaction Conditions

1.1 Solvents: Ammonia

Reference

Synthesis of Arylstannanes from Arylamines

Chopa, Alicia B.; Lockhart, Maria T.; Silbestri, Gustavo, Organometallics, 2001, 20(15), 3358-3360

Production Method 3

1066-45-1

2510-86-3

934-56-5

Reaction Conditions

1.1 Reagents: Sodium Solvents: Ammonia
1.2 -

Reference

Phenols as Starting Materials for the Synthesis of Arylstannanes via SRN1

Chopa, Alicia B.; Lockhart, Maria T.; Dorn, Viviana B., Organometallics, 2002, 21(7), 1425-1429

Production Method 4

1066-45-1

934-56-5

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Diethyl ether ,  Hexane
1.2 Solvents: Tetrahydrofuran

Reference

Phenyl-substituted 2,2':6',2''-terpyridine as a new series of fluorescent compounds-their photophysical properties and fluorescence tuning

Mutai, Toshiki; Cheon, Jin-Dong; Arita, Shinpei; Araki, Koji, Journal of the Chemical Society, 2001, (7), 1045-1050

Production Method 5

120086-07-9

934-56-5

Reaction Conditions

1.1 Catalysts: Bis(1,5-cyclooctadiene)nickel Solvents: Toluene

Reference

Nickel-Catalyzed Acylstannylation of 1,3-Dienes: Synthesis and Reaction of ε-Oxoallylstannanes

Shirakawa, Eiji; Nakao, Yoshiaki; Yoshida, Hiroto; Hiyama, Tamejiro, Journal of the American Chemical Society, 2000, 122(37), 9030-9031

Production Method 6

1066-45-1

934-56-5

Reaction Conditions

1.1 Reagents: Sodium Solvents: Hexamethylphosphoramide ;  20 min, rt; 2 - 3 h, rt
1.2 20 min, rt

Reference

Reactions of trimethylstannide and trimethylsiliconide anions with aromatic and heteroaromatic substrates

Postigo, Al; Vaillard, Santiago E.; Rossi, Roberto A., Journal of Physical Organic Chemistry, 2002, 15(12), 889-893

Production Method 7

873-55-2

661-69-8

934-56-5

Reaction Conditions

1.1 Reagents: Silver carbonate Catalysts: Bis(tri-tert-butylphosphine)palladium Solvents: Dimethylacetamide ;  1 h, 140 °C

Reference

Synthesis of arylstannanes by palladium-catalyzed desulfitative coupling reaction of sodium arylsulfinates with distannanes

Lian, Chang; Yue, Guanglu; Zhang, Haonan; Wei, Liyan; Liu, Danyang; et al, Tetrahedron Letters, 2018, 59(45), 4019-4023

Production Method 8

1066-45-1

934-56-5

Reaction Conditions

1.1 Solvents: Tetrahydrofuran
1.2 Reagents: Ammonium chloride Solvents: Water

Reference

Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines

Hayashi, T.; Ishigedani, M., Tetrahedron, 2001, 57(13), 2589-2595

Production Method 9

591-50-4

661-69-8

934-56-5

Reaction Conditions

1.1 Catalysts: Dibromobis(triphenylphosphine)palladium Solvents: Toluene

Reference

The Stille reaction

Farina, Vittorio; Krishnamurthy, Venkat; Scott, William J., Organic Reactions (Hoboken, 1997, 50,

Production Method 10

1066-45-1

934-56-5

Reaction Conditions

1.1 Solvents: Diethyl ether ;  overnight, reflux

Reference

Synthesis of Thiophene 1,1-Dioxides and Tuning Their Optoelectronic Properties

Tsai, Chia-Hua; Chirdon, Danielle N.; Maurer, Andrew B.; Bernhard, Stefan; Noonan, Kevin J. T., Organic Letters, 2013, 15(20), 5230-5233

Production Method 11

23265-32-9

661-69-8

934-56-5

Reaction Conditions

1.1 Solvents: Acetonitrile ;  rt

Reference

Visible-Light-Driven Synthesis of Arylstannanes from Arylazo Sulfones

Lian, Chang; Yue, Guanglu; Mao, Jinshan; Liu, Danyang; Ding, Yi; et al, Organic Letters, 2019, 21(13), 5187-5191

Production Method 12

36719-40-1

661-69-8

934-56-5

Reaction Conditions

1.1 Reagents: Boron trifluoride etherate Solvents: Acetonitrile ;  rt; 30 min, rt

Reference

Synthesis of Aryl Trimethylstannane via BF3·OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature

Mao, Shuai ; Chen, Zhengkai ; Wang, Lu; Khadka, Daulat Bikram; Xin, Minhang ; et al, Journal of Organic Chemistry, 2019, 84(1), 463-471

Production Method 13

1066-45-1

934-56-5

Reaction Conditions

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran

Reference

Synthesis and spectroscopic characteristics of aryltrimethylsilicon, -germanium, and -tin compounds

Moerlein, S. M., Journal of Organometallic Chemistry, 1987, 319(1), 29-39

Production Method 14

455-32-3

661-69-8

934-56-5

Reaction Conditions

1.1 Catalysts: Palladium chloride ,  1,1′-(1,4-Butanediyl)bis[1,1-dicyclohexylphosphine] Solvents: o-Xylene ;  10 h, 140 °C

Reference

Synthesis of Arylstannanes via Palladium-Catalyzed Decarbonylative Coupling of Aroyl Fluorides

Kayumov, Muzaffar; Zhao, Jian-Nan; Mirzaakhmedov, Sharafitdin; Wang, Dong-Yu; Zhang, Ao, Advanced Synthesis & Catalysis, 2020, 362(4), 776-781

Production Method 15

591-50-4

661-69-8

934-56-5

Reaction Conditions

1.1 Reagents: Diisopropylethylamine Solvents: Acetonitrile ;  1 h, rt

Reference

Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

Chen, Kai; He, Pei; Zhang, Shuai; Li, Pengfei, Chemical Communications (Cambridge, 2016, 52(58), 9125-9128

Production Method 16

661-69-8

934-56-5

Reaction Conditions

1.1 Reagents: tert-Butyl nitrite Catalysts: p-Toluenesulfonic acid Solvents: 1,2-Dichloroethane ;  4 h, 0 °C

Reference

Synthesis method of aryltin compounds from aromatic amine, distannane and alkyl nitrite

, China, , ,

Production Method 17

661-69-8

934-56-5

Reaction Conditions

1.1 Reagents: p-Toluenesulfonic acid ,  tert-Butyl nitrite Solvents: 1,2-Dichloroethane ;  4 h, 0 °C

Reference

Synthesis of aryl trimethylstannanes from aryl amines: a Sandmeyer-type stannylation reaction

Qiu, Di; Meng, He; Jin, Liang; Wang, Shuai; Tang, Shengbo; et al, Angewandte Chemie, 2013, 52(44), 11581-11584

Production Method 18

1066-45-1

591-51-5

934-56-5

Reaction Conditions

Reference

Stille coupling via C-N bond cleavage

Wang, Dong-Yu; Kawahata, Masatoshi; Yang, Ze-Kun; Miyamoto, Kazunori; Komagawa, Shinsuke; et al, Nature Communications, 2016, 7,

Production Method 19

1066-45-1

934-56-5

Reaction Conditions

1.1 Reagents: Magnesium

Reference

A Molecular Tetrapod for Organic Photovoltaics

Yang, Jianzhong; Zhang, Zhen; Qin, Yang, ACS Applied Materials & Interfaces, 2016, 8(34), 22392-22401

Production Method 20

25149-64-8

591-51-5

934-56-5

Reaction Conditions

1.1 Solvents: Diethyl ether

Reference

Organometallic compounds. LXXII. Reactions of racemic tetraorganotin compounds with butyllithium and with lithium aluminum hydride

Gielen, Marcel; Tondeur, Yves, Journal of Organometallic Chemistry, 1981, 216(3), 371-6

Trimethylphenyltin Raw materials

• Trimethylphenylammonium Iodide
• Trimethyltin chloride
• Iodobenzene
• Benzoyl fluoride
• (1E)-1-phenyl-3,3-di(propan-2-yl)triaz-1-ene
• Benzenesulfinic acid, sodium salt
• Diazene,1-(methylsulfonyl)-2-phenyl-
• Phosphoric acid,diethyl phenyl ester
• Stannane,methyltriphenyl-
• Sodium, (trimethylstannyl)-
• Hexamethylditin
• phenyllithium
• Stannane, benzoyltrimethyl-
• Lithium, (trimethylstannyl)-

Trimethylphenyltin Preparation Products

• Trimethylphenyltin (934-56-5)

• 1. Evolution of dealloying induced strain in nanoporous gold crystals?
  Ross Harder,David C. Dunand,Ian McNulty Nanoscale, 2017,9, 5686-5693
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• 4. Fe(iii)-mediated isomerization of α,α-diarylallylic alcohols to ketones via radical 1,2-aryl migration?
  Ziyang Deng,Changwei Chen,Sunliang Cui RSC Adv., 2016,6, 93753-93755
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• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzene and substituted derivatives
• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives

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