Production Method 1

53059-74-8

930-35-8

Reaction Conditions

Reference

Synthesis of tetrathiofulvalene

Anzai, Hiroyuki, Denshi Gijutsu Sogo Kenkyusho Iho, 1975, 39(9), 667-72

Production Method 2

16919-18-9

104793-62-6

930-35-8

Reaction Conditions

1.1 Reagents: Sodium hydrosulfide Solvents: Acetic acid ,  Dimethylformamide

Reference

Broadband near-IR absorbing Au-dithiolene complexes bearing redox-active oligothiophene ligands

Wright, Iain A.; Wilson, Claire; Coles, Simon J.; Skabara, Peter J., Dalton Transactions, 2019, 48(1), 107-116

Production Method 3

104284-11-9

930-35-8

Reaction Conditions

Reference

Thiocarbonic acids and derivatives

Sato, S.; Furukawa, N., Science of Synthesis, 2005, 18, 821-968

Production Method 4

17934-70-2

930-35-8

Reaction Conditions

1.1 Solvents: Tetrahydrofuran

Reference

Proton, carbon-13, and selenium-77 NMR of sulfur and selenium containing cyclic 6π-cations

Poleschner, Helmut; Radeglia, Reiner, Phosphorus and Sulfur and the Related Elements, 1987, 29(2-4), 187-200

Production Method 5

930-35-8

Reaction Conditions

Reference

Excited-state structural dynamics and vibronic coupling of 1,3-dithiole-2-thione - resonance Raman spectroscopy and density functional theory calculation study

Wang, Huigang; Liu, Bo; Wan, Junmin; Xu, Jun; Zheng, Xuming, Journal of Raman Spectroscopy, 2009, 40(8), 992-997

Production Method 6

930-35-8

Reaction Conditions

Reference

Synthesis of the electron donor tetrathiafulvalene using acetylene as the starting material

Li, Hsue-Fen; Li, Su-Zheng; Yao, Eu-Shing; Ye, Chang, Ziran Zazhi, 1979, 2(3),

Production Method 7

930-35-8

Reaction Conditions

Reference

A voltammetric study of several oxygen, sulfur and selenium heterocyclic carbonium ions in acetonitrile

Braun, Robert D.; Green, Dennis C., Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1977, 79(2), 381-90

Production Method 8

930-35-8

Reaction Conditions

Reference

Improved synthesis of tetrathiafulvalene

Melby, L. Russell; Hartzler, Harris D.; Sheppard, William A., Journal of Organic Chemistry, 1974, 39(16), 2456-8

Production Method 9

4358-26-3

62122-82-1

930-35-8

Reaction Conditions

1.1 Reagents: Sodium hydrosulfide

Reference

Convenient synthesis of 1,3-dithiole-2-thione and related compounds

Ueno, Yoshio; Nakayama, Akira; Okawara, Makoto, Synthesis, 1975, (4), 277-8

Production Method 10

1066-54-2

930-35-8

Reaction Conditions

1.1 Reagents: Butyllithium ,  N,N,N′,N′-Tetramethylethylenediamine Solvents: Tetrahydrofuran ,  Hexane
1.2 Reagents: Sulfur
1.3 -

Reference

A convenient preparation of 1,3-dithiole-2-thione and 1,3-diselenole-2-selone derivatives

Takimiya, K.; Morikami, A.; Otsubo, T., Synlett, 1997, (3), 319-321

Production Method 11

2314-40-1

930-35-8

Reaction Conditions

1.1 Reagents: Phosphorus sulfide (P2S5) Solvents: Toluene

Reference

Sulfur heterocycles. XXXIII. Preparative synthesis and subsequent reactions of isotrithione [1,3-dithiole-2-thione] and isodithione [1,3-dithiol-2-one]

Mayer, Roland; Gebhardt, Berno, Chemische Berichte, 1964, 97(5), 1298-1307

Production Method 12

4358-26-3

104793-62-6

930-35-8

Reaction Conditions

1.1 Reagents: Sodium hydrosulfide Solvents: Acetic acid ,  Dimethylformamide

Reference

Key intermediates for the synthesis of organic semiconductors: a direct dithiocarbamate route to unsubstituted 1,3-dithiol-2-one derivatives

Guziec, Frank S. Jr.; Russo, Joseph M.; Torres, Felix F.; Long, G. Cornell; Tellez, Mario R., Journal of the Chemical Society, 1989, (5), 1068-70

Production Method 13

104284-11-9

930-35-8

Reaction Conditions

1.1 Reagents: Pyridine Solvents: Benzene

Reference

Some aspects of the chemistry of dioxa- and dithiagermoles

Lavayssiere, H.; Dousse, G.; Satge, J., Recueil des Travaux Chimiques des Pays-Bas, 1988, 107(6), 440-8

Production Method 14

930-35-8

Reaction Conditions

Reference

Thiocarbonyl ylide intermediates generated by deprotonation of 2-(phenacylthio)- and 2-(p-bromophenacylthio)-1,3-dithiolylium and 2-(p-bromophenacylthio)-1,3-dithiolanylium bromides

Nakayama, Juzo; Takemasa, Toshiro; Hoshino, Masamatsu, Bulletin of the Chemical Society of Japan, 1980, 53(8), 2281-4

Production Method 15

930-35-8

Reaction Conditions

Reference

Unsaturated thiolates in cycloaddition reactions. II. Reaction of α,β-ethylene thiolates of alkali metals with carbon disulfide

Bunina, N. A.; Petrov, M. L.; Petrov, A. A., Zhurnal Organicheskoi Khimii, 1979, 15(11), 2306-12

Production Method 16

930-35-8

Reaction Conditions

Reference

5,8-Dithiafulvalene-1,4-quinone [2-(1,3-dithiol-2-ylidene)-4-cyclopentene-1,3-dione]

Nakayama, Jyuzo; Ishihara, Miyoko; Hoshino, Masamatsu, Chemistry Letters, 1977, (1), 77-80

Production Method 17

930-35-8

Reaction Conditions

Reference

Easy synthesis of 1,3-dithiole-2-thione

Chen, C. H., Journal of the Chemical Society, 1976, (22), 920-1

Production Method 18

930-35-8

Reaction Conditions

Reference

Anomalous reaction of selenium and carbon disulfide with sodium acetylide. Synthesis of selenium analogs of 1,3-dithiole-2-thione

Engler, Edward M.; Patel, Vishnu V., Journal of Organic Chemistry, 1975, 40(3), 387-9

Production Method 19

930-35-8

Reaction Conditions

Reference

Reactions of ethylene di- and trithiocarbonates with acetylenes. Anomalous reaction with bromocyanoacetylene to give a thioacyl bromide

O'Connor, Brian R.; Jones, Frank Norton, Journal of Organic Chemistry, 1970, 35(6), 2002-5

Vinylene Trithiocarbonate Raw materials

• tetraphenylborate
• Phosphate(1-),hexafluoro-
• Methanaminium, N-1,3-dithiol-2-ylidene-N-methyl-
• 1,2-Ethenedithiol, disodium salt, (Z)-
• ethynyltrimethylsilane
• 1,3-Dithiol-2-one
• 1,3-Dithiol-1-ium, 2-(methylthio)-, iodide
• Piperidinium, 1-(1,3-dithiol-2-ylidene)-
• 1,3,2-Dithiagermole, 2,2-dimethyl-

Vinylene Trithiocarbonate Preparation Products

• Vinylene Trithiocarbonate (930-35-8)

• 1. Establishing plasmon contribution to chemical reactions: alkoxyamines as a thermal probe?
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• 2. Emergence of microfluidic wearable technologies
  Joo Chuan Yeo,Kenry Lab Chip, 2016,16, 4082-4090
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  Liao Xiaoqing,Li Ruiyi,Li Zaijun,Sun Xiulan,Wang Zhouping,Liu Junkang New J. Chem., 2015,39, 5240-5248
• 4. Evolution of calcium phosphate precipitation in hanging drop vapor diffusion by in situRaman microspectroscopy
  Gloria Belén Ramírez-Rodríguez,José Manuel Delgado-López,Jaime Gómez-Morales CrystEngComm, 2013,15, 2206-2212
• 5. Fast synthesis of red Li3BaSrLn3(WO4)8:Eu3+ phosphors for white LEDs under near-UV excitation by a microwave-assisted solid state reaction method and photoluminescence studies
  Bo Wei,Zhenyu Liu,Chen Xie,Shu Yang,Wentao Tang,Aiwei Gu,Wing-Tak Wong,Ka-Leung Wong J. Mater. Chem. C, 2015,3, 12322-12327

• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Heteroaromatic compounds Heteroaromatic compounds
• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Heteroaromatic compounds
• Material Chemicals Electrical Materials Biosensor Materials
• Material Chemicals Electrical Materials

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