Production Method 1

1072-63-5

16919-18-9

700795-41-1

Reaction Conditions

Reference

Impact of substituents attached to N-heterocyclic carbenes on the catalytic activity of copper complexes in the reduction of carbonyl compounds with triethoxysilane

Peng, Jiajian; Chen, Lingzhen; Xu, Zheng; Hu, Yingqian; Li, Jiayun; et al, Chinese Journal of Chemistry, 2009, 27(11), 2121-2124

Production Method 2

34311-90-5

16919-18-9

700795-41-1

Reaction Conditions

1.1 Reagents: Potassium hexafluorophosphate Solvents: Water ;  24 h, rt

Reference

CO2 Responsive Imidazolium-Type Poly(Ionic Liquid) Gels

Zhang, Jing; Xu, Dan; Guo, Jiangna; Sun, Zhe; Qian, Wenjing; et al, Macromolecular Rapid Communications, 2016, 37(14), 1194-1199

Production Method 3

16919-18-9

700795-41-1

Reaction Conditions

Reference

An efficient Heck reaction in water catalyzed by palladium nanoparticles immobilized on imidazolium-styrene copolymers

Qiao, Kun; Sugimura, Rie; Bao, Quanxi; Tomida, Daisuke; Yokoyama, Chiaki, Catalysis Communications, 2008, 9(15), 2470-2474

Production Method 4

74173-48-1

16919-18-9

Reaction Conditions

1.1 Reagents: Ruthenium trichloride

Reference

Novel synthesis and characterization of ruthenium tris(4-methyl-4'-vinyl-2,2'-bipyridine) complexes

Williams, C. E.; Lowry, R. B.; Braven, J.; Belt, S. T., Inorganica Chimica Acta, 2001, 315(1), 112-119

Production Method 5

417705-49-8

366-18-7

16919-18-9

Reaction Conditions

1.1 Solvents: Methanol ;  overnight, reflux; reflux → rt
1.2 Reagents: Ammonium hexafluorophosphate ;  1 h, rt

Reference

Green-emitting iridium(III) complexes containing sulfanyl- or sulfone-functionalized cyclometallating 2-phenylpyridine ligands

Constable, Edwin C.; Ertl, Cathrin D.; Housecroft, Catherine E.; Zampese, Jennifer A., Dalton Transactions, 2014, 43(14), 5343-5356

Production Method 6

417705-49-8

366-18-7

16919-18-9

Reaction Conditions

1.1 Solvents: Ethylene glycol ;  24 h, 150 °C; 150 °C → rt
1.2 Reagents: Ammonium hexafluorophosphate Solvents: Water

Reference

Scrutinizing Design Principles toward Efficient, Long-Term Stable Green Light-Emitting Electrochemical Cells

Namanga, Jude E.; Gerlitzki, Niels; Mudring, Anja-Verena, Advanced Functional Materials, 2017, 27(17),

Production Method 7

16919-18-9

16919-18-9

83-56-7

Reaction Conditions

1.1 Solvents: Nitromethane-d3 ;  rt

Reference

[2]Catenanes and inclusion complexes derived from self-assembled rectangular PdII and PtII metallocycles

Alvarino, Cristina; et al, Dalton Transactions, 2012, 41(39), 11992-11998

Production Method 8

512-56-1

103993-60-8

16919-18-9

161118-31-6

98015-45-3

Reaction Conditions

1.1
< 100 °C; 7 h, 100 °C; 100 °C → rt
1.2
Reagents:
Pivaloyl chloride
; 
rt
1.3
Reagents:
Potassium hydroxide
Solvents:
Water
; 
3 h, rt
1.4
Reagents:
Hexafluorophosphoric acid
Solvents:
Water

Reference

Chemische Berichte (1994'Novel, very strong, uncharged auxiliary bases; design and synthesis of monomeric and polymer-bound triaminoiminophosphorane bases of broadly varied steric demand' Schwesinger, Reinhard; Willaredt, Juergen; Schlemper, Helmut; Keller, Manfred; Schmitt, Dieter; et al, 1994 , vol.127(12), # 4 p.2435-54

Production Method 9

16919-18-9

16919-18-9

87-01-4

Reaction Conditions

1.1 Solvents: Acetonitrile

Reference

Preparation, photochemistry, and electronic structures of coumarin laser dye complexes of cyclopentadienylruthenium(II)

Koefod, Robert S.; et al, Inorganic Chemistry, 1989, 28(12), 2285-90

Production Method 10

16919-18-9

16919-18-9

91-44-1

Reaction Conditions

1.1 Solvents: Acetonitrile

Reference

Preparation, photochemistry, and electronic structures of coumarin laser dye complexes of cyclopentadienylruthenium(II)

Koefod, Robert S.; et al, Inorganic Chemistry, 1989, 28(12), 2285-90

Production Method 11

34311-90-5

16919-18-9

700795-41-1

Reaction Conditions

1.1 Reagents: Potassium hexafluorophosphate Solvents: Water ;  6 h, 25 °C

Reference

Thermo- and pH-responsive poly(ionic liquid) membranes

Chen, Fei; Guo, Jiangna; Xu, Dan; Yan, Feng, Polymer Chemistry, 2016, 7(6), 1330-1336

Production Method 12

657394-63-3

16919-18-9

700795-41-1

Reaction Conditions

1.1 Reagents: Sodium hexafluorophosphate Solvents: Water ;  rt; 1 d, rt

Reference

Efficient synthesis of styrene carbonate from CO2 and styrene oxide using zinc catalysts immobilized on soluble imidazolium-styrene copolymers

Qiao, Kun; Ono, Fumitaka; Bao, Quanxi; Tomida, Daisuke; Yokoyama, Chiaki, Journal of Molecular Catalysis A: Chemical, 2009, 303(1-2), 30-34

Production Method 13

58861-53-3

366-18-7

16919-18-9

Reaction Conditions

1.1 Reagents: Iridium trichloride Solvents: 2-Methoxyethanol ,  Water ;  overnight, 120 °C; 120 °C → rt
1.2 Solvents: Ethylene glycol ;  15 h, 150 °C; 0 °C; 5 min, 0 °C → 85 °C
1.3 Reagents: Ammonium hexafluorophosphate Solvents: Water

Reference

Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis

Singh, Anuradha; Teegardin, Kip; Kelly, Megan; Prasad, Kariate S.; Krishnan, Sadagopan; et al, Journal of Organometallic Chemistry, 2015, 776, 51-59

Production Method 14

58861-53-3

366-18-7

16919-18-9

Reaction Conditions

1.1 Reagents: Iridium trichloride Solvents: Ethylene glycol ;  1 min, rt; 50 min, 200 °C; 200 °C → rt
1.2 30 min, 200 °C
1.3 Reagents: Ammonium hexafluorophosphate Solvents: Water ;  cooled

Reference

Microwave-assisted synthesis of heteroleptic Ir(III)+ polypyridyl complexes

Monos, Timothy M.; Sun, Alexandra C.; McAtee, Rory C.; Devery, James J.; Stephenson, Corey R. J., Journal of Organic Chemistry, 2016, 81(16), 6988-6994

Production Method 15

4755-77-5

20989-17-7

579-66-8

16919-18-9

1630816-94-2

Reaction Conditions

1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran ;  0 °C; 12 h, 22 °C
1.2 Solvents: Dichloromethane ;  12 h, 50 °C; 50 °C → 22 °C
1.3 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran ;  0 °C; 30 min, 0 °C; 14 h, 80 °C; 80 °C → 22 °C
1.4 Reagents: Potassium sodium tartrate Solvents: Water ;  cooled; 4 h, 22 °C
1.5 Reagents: Hydrochloric acid Solvents: Diethyl ether ,  Methanol ;  30 min, 0 °C
1.6 Solvents: Toluene ;  14 h, 90 °C; 90 °C → 22 °C
1.7 Reagents: Potassium hexafluorophosphate Solvents: Water ;  2 h, 22 °C

Reference

Multifunctional organoboron compounds for scalable natural product synthesis

Meng, Fanke; McGrath, Kevin P.; Hoveyda, Amir H., Nature (London, 2014, 513(7518), 367-374

Production Method 16

16919-18-9

83-56-7

Reaction Conditions

1.1 Reagents: Potassium hexafluorophosphate ;  rt
2.1 Solvents: Nitromethane-d3 ;  rt

Reference

[2]Catenanes and inclusion complexes derived from self-assembled rectangular PdII and PtII metallocycles

Alvarino, Cristina; et al, Dalton Transactions, 2012, 41(39), 11992-11998

Phosphate(1-),hexafluoro- Raw materials

• Phosphate(1-),hexafluoro-
• Iridium, di-μ-chlorotetrakis[5-fluoro-2-(2-pyridinyl-κN)phenyl-κC]di-
• Trimethyl phosphate
• ethyl 2-chloro-2-oxo-acetate
• 2-(4-Fluorophenyl)pyridine
• 2,2'-Bipyridine
• 2-(4-ethenylpyridin-2-yl)-4-methylpyridine
• (S)-(+)-2-Phenylglycinol
• 1-Vinylimidazole
• 1,3,2-Diazaphosphorine,2-(diethylamino)-2-[(1,1-dimethylethyl)amino]-1,2,2,4,5,6-hexahydro-1-methyl-
• 1H-Imidazolium, 1-butyl-3-ethenyl-, chloride
• 1-Butyl-3-Vinylimidazolium Bromide
• 2,6-Diethylaniline

Phosphate(1-),hexafluoro- Preparation Products

• Phosphate(1-),hexafluoro- (16919-18-9)
• 3-(2,6-Diethylphenyl)-4,5-dihydro-1-[(1S)-2-hydroxy-1-phenylethyl]-1H-imidazolium (1630816-94-2)
• 1,3,2-Diazaphosphorinium, 2-(diethylamino)-2-[(1,1-dimethylethyl)methylamino]-2,2,3,4,5,6-hexahydro-1,3-dimethyl- (9CI) (161118-31-6)
• 1H-Imidazolium, 1-butyl-3-ethenyl- (700795-41-1)
• 1,5-Dihydroxynaphtalene (83-56-7)
• 7-(Dimethylamino)-4-methylcoumarin (87-01-4)
• 7-Diethylamino-4-methylcoumarin (91-44-1)
• BEMP (98015-45-3)

• 1. Evidence that the availability of an allylic hydrogen governs the regioselectivity of the Wacker oxidation
  Matthew J. Gaunt,Jinquan Yu,Jonathan B. Spencer Chem. Commun., 2001, 1844-1845
• 2. Fe/Fe3C@C nanoparticles encapsulated in N-doped graphene–CNTs framework as an efficient bifunctional oxygen electrocatalyst for robust rechargeable Zn–air batteries?
  Zhiyan Chen,Nan Wu,Yaobing Wang,Bing Wang,Yingde Wang J. Mater. Chem. A, 2018,6, 516-526
• 3. Exciplex emission from the mixed dimer of naphthalene and 2-cyanonaphthalene in a supersonic jet
  Aloke Das,K. K. Mahato,Chayan K. Nandi,Tapas Chakraborty,Shridhar R. Gadre,Nikhil A. Gokhale Phys. Chem. Chem. Phys., 2002,4, 2162-2168
• 4. Excited state dynamics of symmetric and asymmetric Cr3(dpa)4Cl2 measured using femtosecond transient absorption spectroscopy?
  Chao-Han Cheng,Wen-Zhen Wang,Shie-Ming Peng,I-Chia Chen Phys. Chem. Chem. Phys., 2017,19, 25471-25477
• 5. Evolution of cellulose into flexible conductive green electronics: a smart strategy to fabricate sustainable electrodes for supercapacitors
  Tengfei Yu,Yuehan Wu,Wei Li,Bin Li RSC Adv., 2014,4, 34134-34143

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• 2680771-01-9(4-cyclopentyl-3-{(prop-2-en-1-yloxy)carbonylamino}butanoic acid)
• 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
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