Production Method 1

10385-78-1

92618-89-8

Reaction Conditions

1.1 Catalysts: Methanesulfonic acid, 1,1,1-trifluoro-, samarium(3+) salt (3:1) ;  15 min, rt
1.2 Reagents: Sodium bicarbonate Solvents: Water

Reference

Samarium trifluoromethanesulfonate: an efficient moisture tolerant acylation catalyst under solvent-free condition

Roy, Bimalendu; Dasgupta, Somnath; Rajput, Vishal Kumar; Mukhopadhyay, Balaram, Journal of Carbohydrate Chemistry, 2008, 27(1), 1-9

Production Method 2

10385-78-1

92618-89-8

Reaction Conditions

1.1 Catalysts: 4,6-Bis(sulfoamino)-1,3,5-triazin-2-yl sulfamate Solvents: Dichloromethane ;  3 - 145 min, rt

Reference

Efficient Acetylation of Alcohols, Phenols, and Amines Catalyzed by Melamine Trisulfonic Acid (MTSA)

Shirini, Farhad; Zolfigol, Mohammad Ali; Aliakbar, Ali-Reza; Albadi, Jalal, Synthetic Communications, 2010, 40(7), 1022-1028

Production Method 3

76-22-2

92618-89-8

Reaction Conditions

1.1 Reagents: (SP-5-12)-(Pyridine)bis[tetrahydroborato(1-)-κH,κH′]zinc Solvents: Tetrahydrofuran ,  Ethyl acetate ;  2 h, reflux

Reference

Reductive acetylation of carbonyl compounds to acetates with pyridine zinc borohydride

Zeynizadeh, Behzad; Setamdideh, Davood; Faraji, Fariba, Bulletin of the Korean Chemical Society, 2008, 29(1), 76-80

Production Method 4

85106-60-1

10385-78-1

92618-89-8

Reaction Conditions

1.1 Solvents: Chloroform

Reference

1-Acyl-3-substituted imidazolium salts as highly reactive acylating agents

Kamijo, Tetsuhide; Yamamoto, Ryoji; Harada, Hiromu; Iizuka, Kinji, Chemical & Pharmaceutical Bulletin, 1982, 30(11), 4242-4

Production Method 5

465-31-6

92618-89-8

Reaction Conditions

1.1 Reagents: Sulfuric acid

Reference

Camphene

Moycho, Stefan; Zienkowski, Franz, Justus Liebigs Annalen der Chemie, 1905, 340, 17-63

Production Method 6

465-31-6

92618-89-8

Reaction Conditions

1.1 Reagents: Sulfuric acid

Reference

Camphene

Wagner, G.; Moycho, St.; Zienkowski, Fr., Berichte der Deutschen Chemischen Gesellschaft, 1904, 37, 1032-1037

Production Method 7

92618-89-8

Reaction Conditions

Reference

Terpenic esters from terpenic olefins

, India, , ,

Production Method 8

79-92-5

92618-89-8

872316-53-5

Reaction Conditions

1.1 165 - 170 °C; 126 - 127 °C; 1 h, 126 - 127 °C

Reference

Method for producing camphorquinone from byproduct generated during camphor synthesis process as raw material

, China, , ,

Production Method 9

10385-78-1

92618-89-8

Reaction Conditions

1.1 9.9 s, 5 MPa, 225 °C

Reference

Environmental benign application to organic syntheses using high-pressure, high-temperature water microfluidic system

Matsushima, Keiichiro; Hirano, Shigeki; Uchiyama, Tomoyuki; Sato, Masahiro; Kawanami, Hajime; et al, Hokkaidoritsu Kogyo Shikenjo Hokoku, 2009, 308, 23-31

Production Method 10

10385-78-1

92618-89-8

Reaction Conditions

1.1 Solvents: Acetic acid ,  Water ;  9.9 s, 5 MPa, 200 °C

Reference

A highly selective, high-speed, and hydrolysis-free O-acylation in subcritical water in the absence of a catalyst

Sato, Masahiro; Matsushima, Keiichiro; Kawanami, Hajime; Ikuhsima, Yutaka, Angewandte Chemie, 2007, 46(33), 6284-6288

Production Method 11

76-22-2

92618-89-8

Reaction Conditions

1.1 Catalysts: (SP-4-1)-Bis[[2,3-butanedione 2,3-di(oximato-κN)](1-)]copper Solvents: Ethyl acetate ;  10 min, reflux
1.2 Reagents: Sodium borohydride ;  3.25 h, reflux

Reference

Reductive acetylation of carbonyl compounds to acetates with NaBH4/Cu(dmg)2 system

Zeynizadeh, Behzad; Zarrin, Saviz; Ashuri, Shahriar, Organic Chemistry: An Indian Journal, 2013, 9(6), 244-248

Production Method 12

10385-78-1

92618-89-8

Reaction Conditions

1.1 35 min, 80 °C

Reference

Rice husk ash. A new, cheap, efficient, and reusable reagent for the protection of alcohols, phenols, amines, and thiols

Shirini, F.; Akbari-Dadamahaleh, Somayeh; Mohammad-Khah, Ali, Phosphorus, 2014, 189(5), 577-586

Production Method 13

10385-78-1

92618-89-8

Reaction Conditions

1.1 1.5 h, 80 °C

Reference

Rice husk: Introduction of a green, cheap and reusable catalyst for the protection of alcohols, phenols, amines and thiols

Shirini, Farhad; Akbari-Dadamahaleh, Somayeh; Mohammad-Khah, Ali; Aliakbar, Ali-Reza, Comptes Rendus Chimie, 2014, 17(2), 164-170

Production Method 14

92618-89-8

Reaction Conditions

1.1 Catalysts: 4-(Dimethylamino)pyridine Solvents: Dichloromethane ;  rt; overnight, rt

Reference

Carboxyl esterase enantioselective hydrolysis of monoterpenols

, World Intellectual Property Organization, , ,

Production Method 15

10385-78-1

92618-89-8

Reaction Conditions

1.1 Catalysts: (±)-Camphorsulfonic acid ,  Graphite ;  30 min, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  neutralized

Reference

Solvent-free Acetylation Procedure

Bhat, Sujata V.; Gupta, Manisha O.; Yadav, Jyoti K.; Vaze, Kedar R., Organic Preparations and Procedures International, 2021, 53(6), 590-594

Production Method 16

79-92-5

92618-89-8

Reaction Conditions

Reference

Study on camphene esterification catalyzed by natural zeolite. (I). Reaction conditions

Chen, Qingzhi; Li, Yunlong; Lin, Jianming; Cao, Shulin; Zeng, Meizhen; et al, Linchan Huaxue Yu Gongye, 1990, 10(4), 241-7

Production Method 17

92618-89-8

Reaction Conditions

Reference

Effect of organic base on one-step acylation of camphene

Liu, Hui; Xiao, Zhuanquan; Huang, Yonghong, Huaxue Shiji, 2003, 25(1), 33-34

Production Method 18

92618-89-8

Reaction Conditions

Reference

Terpenoid reactions in the presence of synthetic zeolite catalysts. 26. Acylation of (+)-2-pinene, (-)-2(10)-pinene and (+)-1-p-menthene by synthetic zeolite catalysts

Nomura, Masato; Hisatomi, Satoshi; Hamada, Toshimasa; Fujihara, Yoshihito, Nihon Yukagakkaishi, 1997, 46(5), 583-587

Production Method 19

92618-89-8

Reaction Conditions

Reference

A facile conversion of halides, alcohols and olefins to esters using iron(III) perchlorate

Kumar, Baldev; Kumar, Harish; Parmar, Anupma, Synthetic Communications, 1992, 22(7), 1087-94

Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-, 2-acetate Raw materials

• Camphor
• DL-Camphene
• 1-acetyl-3-benzylimidazolium bromide
• Bicyclo[2.2.1]heptan-2-ol,2,3,3-trimethyl-
• 1,7,7-trimethylbicyclo2.2.1heptan-2-ol

Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-, 2-acetate Preparation Products

• Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-, 2-acetate (92618-89-8)
• Bicyclo[2.2.1]heptan-2-ol, 4,7,7-trimethyl-, 2-acetate (872316-53-5)

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• Solvents and Organic Chemicals Organic Compounds Lipids and lipid-like molecules Prenol lipids Bicyclic monoterpenoids
• Solvents and Organic Chemicals Organic Compounds Lipids and lipid-like molecules Prenol lipids Monoterpenoids Bicyclic monoterpenoids
• Natural Products and Extracts Plant Extracts Plant based Rhanterium epapposum
• Natural Products and Extracts Plant Extracts Plant based Ferulago trachycarpa

• 76-49-3(Bornyl acetate)
• 2623-23-6(Menthyl acetate)
• 76-50-6(Bornyl isovalerate)
• 77-54-3((+)-cedryl acetate)
• 89-48-5((±)-Menthyl Acetate)
• 2756-56-1(Isobornyl propanoate)
• 5726-19-2(2-Methylcyclohexyl Acetate)
• 7779-73-9(Isobornyl isovalerate)
• 125-12-2(isobornyl acetate)
• 88-41-5(2-Tert-Butylcyclohexyl acetate)