Cas no 91270-69-8 (7-Bromonaphthalen-1-ol)

7-Bromonaphthalen-1-ol structure
7-Bromonaphthalen-1-ol structure
Product Name:7-Bromonaphthalen-1-ol
CAS No:91270-69-8
MF:C10H7BrO
MW:223.065982103348
MDL:MFCD17012439
CID:1962431
PubChem ID:13215711
Update Time:2024-10-26

7-Bromonaphthalen-1-ol Chemical and Physical Properties

Names and Identifiers

    • 1-Naphthalenol, 7-bromo-
    • 7-Bromo-1-hydroxynaphthalene
    • 7-Bromonaphthalen-1-ol
    • 7-bromo-1-Naphthalenol
    • 2-Bromo-8-naphthol
    • STJXOXMPODAEAK-UHFFFAOYSA-N
    • BCP25448
    • AK398915
    • F10246
    • 7-Bromo-1-naphthalenol (ACI)
    • 7-Bromo-1-naphthol
    • 8-Hydroxy-2-bromonaphthalene
    • Z1269193289
    • 91270-69-8
    • DS-14515
    • SCHEMBL3982743
    • EN300-114088
    • F16512
    • MFCD17012439
    • CS-0030221
    • DB-083889
    • AKOS022506522
    • DTXSID10528861
    • SY260438
    • SB66974
    • MDL: MFCD17012439
    • Inchi: 1S/C10H7BrO/c11-8-5-4-7-2-1-3-10(12)9(7)6-8/h1-6,12H
    • InChI Key: STJXOXMPODAEAK-UHFFFAOYSA-N
    • SMILES: BrC1C=C2C(C=CC=C2O)=CC=1

Computed Properties

  • Exact Mass: 221.96803g/mol
  • Monoisotopic Mass: 221.96803g/mol
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 1
  • Hydrogen Bond Acceptor Count: 1
  • Heavy Atom Count: 12
  • Rotatable Bond Count: 0
  • Complexity: 160
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • XLogP3: 3
  • Topological Polar Surface Area: 20.2

Experimental Properties

  • Density: 1.615
  • Boiling Point: 353.821 °C at 760 mmHg
  • Flash Point: 167.785 °C
  • PSA: 20.23000
  • LogP: 3.30790

7-Bromonaphthalen-1-ol Security Information

7-Bromonaphthalen-1-ol Pricemore >>

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7-Bromonaphthalen-1-ol Production Method

Production Method 1

Reaction Conditions
1.1 Reagents: 2,4,6-Trimethylpyridine ,  Triisopropylsilyl triflate Catalysts: (OC-6-42)-Bis[[2,3-butanedione 2,3-di(oximato-κN)](1-)]chloro(N,N-dimethyl-4-pyr… ,  Iridium(1+), [4,4′-bis(trifluoromethyl)-2,2′-bipyridine-κN1,κN1′]bis[3-fluoro-5-… Solvents: Dichloromethane ,  1,2-Dichloroethane ;  10 h, rt
1.2 Reagents: Tetrabutylammonium fluoride Solvents: Tetrahydrofuran ;  20 min, rt
Reference
Rapid Access to Free Phenols by Photocatalytic Acceptorless Dehydrogenation of Cyclohexanones at Room Temperature
Min, Lin; Lin, Jiani; Shu, Wei, Chinese Journal of Chemistry, 2023, 41(21), 2773-2778

Production Method 2

Reaction Conditions
1.1 Reagents: m-Chloroperbenzoic acid Catalysts: Manganese(1+), [5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphinato(2-)-κN… Solvents: Acetonitrile ,  Dichloromethane ;  1 h, rt; 27 °C
Reference
Substituent-induced regioselective hydroxylation of the aromatic C-H bond on naphthalene with metachloroperbenzoic acid catalyzed by F20TPPMnCl
Chen, Chang-Di; Sheng, Wen-Bing; Shi, Guo-Jun; Guo, Can-Cheng, Journal of Physical Organic Chemistry, 2013, 26(1), 23-29

Production Method 3

Reaction Conditions
1.1 Reagents: Perchloric acid Solvents: Acetonitrile ;  rt
Reference
Acid-Catalyzed Dehydration of Naphthalene-cis-1,2-dihydrodiols: Origin of Impaired Resonance Effect of 3-Substituents
Kudavalli, Jaya Satyanarayana; Boyd, Derek R.; Sharma, Narain D.; More O'Ferrall, Rory A., Journal of Organic Chemistry, 2011, 76(22), 9338-9343

Production Method 4

Reaction Conditions
Reference
Arynic species: effect of substituents on the reactivity of monosubstituted dehydrobenzenes
Gavina, F.; Luis, S. V.; Costero, A. M.; Gil, P., Tetrahedron, 1986, 42(1), 155-66

Production Method 5

Reaction Conditions
1.1 Solvents: 1,4-Dioxane
Reference
Arynic species. II. Tosyl and triazene as leaving group in the generation of arynes from polymer-bound reagents
Gavina, F.; Luis, S. V.; Ferrer, P.; Costero, A. M.; Gil, P., Tetrahedron, 1986, 42(20), 5641-8

Production Method 6

Reaction Conditions
1.1 Reagents: Triethylamine Catalysts: Palladium diacetate ,  1,1′-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[1,1-diphenylphosphine] Solvents: 1,2-Dichloroethane ;  rt → 70 °C; 18 h, 70 °C
Reference
Total Synthesis of Elmenols A and B and Related Rearranged Angucyclinones
Ikonnikova, Viktoria A. ; Solyev, Pavel N. ; Terekhov, Stanislav S.; Alferova, Vera A.; Tyurin, Anton P.; et al, ChemistrySelect, 2021, 6(42), 11775-11778

Production Method 7

Reaction Conditions
1.1 Reagents: Hydrochloric acid Solvents: Ethanol ;  20 h, 50 °C
Reference
Substituted 9-Diethylaminobenzo[a]phenoxazin-5-ones (Nile Red Analogues): Synthesis and Photophysical Properties
Hornum, Mick ; Mulberg, Mads W.; Szomek, Maria; Reinholdt, Peter ; Brewer, Jonathan R. ; et al, Journal of Organic Chemistry, 2021, 86(2), 1471-1488

Production Method 8

Reaction Conditions
Reference
New chiral synthons from the microbial oxidation of bromonaphthalenes
Hudlicky, Tomas; Endoma, Mary Ann A.; Butora, Gabor, Tetrahedron: Asymmetry, 1996, 7(1), 61-8

7-Bromonaphthalen-1-ol Raw materials

7-Bromonaphthalen-1-ol Preparation Products

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