Production Method 1

831-23-2

91-60-1

Reaction Conditions

1.1 Catalysts: Perchloric acid Solvents: Benzene ;  1 h, 80 °C

Reference

Integration of a Four-Step Reaction into One-Pot under the Coexistence of Silica-Gel-Supported Acid and Base Reagents: Synthesis of Benzo- and Naphthothiophenes Using NaHSO4/SiO2 and Na2CO3/SiO2

Hayakawa, Mamiko; Aoyama, Tadashi; Nakaoka, Kyohei; Kosuge, Masayuki; Ouchi, Akihiko, Synthesis, 2019, 51(12), 2572-2578

Production Method 2

811-51-8

580-13-2

91-60-1

Reaction Conditions

1.1 Reagents: Hydrochloric acid

Reference

Simple syntheses of aryl alkyl thioethers and of aromatic thiols from unactivated aryl halides and efficient methods for selective dealkylation of aryl alkyl ethers and thioethers

Testaferri, L.; Tiecco, M.; Tingoli, M.; Chianelli, D.; Montanucci, M., Synthesis, 1983, (9), 751-5

Production Method 3

612-55-5

91-60-1

Reaction Conditions

1.1 Reagents: 1,2-Ethanedithiol ,  Potassium hydroxide Catalysts: Copper sulfate Solvents: Dimethyl sulfoxide ,  Water ;  20 h, 90 °C

Reference

Copper(II)-Catalyzed Single-Step Synthesis of Aryl Thiols from Aryl Halides and 1,2-Ethanedithiol

Liu, Yajun; Kim, Jihye; Seo, Heesun; Park, Sunghyouk; Chae, Junghyun, Advanced Synthesis & Catalysis, 2015, 357(10), 2205-2212

Production Method 4

62141-80-4

91-60-1

Reaction Conditions

1.1 Catalysts: Triphenylphosphine ,  Iodine Solvents: Benzene ;  reflux

Reference

Triphenylphosphine-Iodine

Dormoy, Jean-Robert; Castro, Bertrand, e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001, ,

Production Method 5

93-11-8

91-60-1

Reaction Conditions

1.1 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran

Reference

Radical ions. 89. One-electron oxidation of diaryl disulfides with aluminum trichloride/dichloromethane

Bock, Hans; Rittmeyer, Peter, Phosphorus, 1992, 68(1-4), 261-91

Production Method 6

93-11-8

91-60-1

Reaction Conditions

1.1 Reagents: Hydrogen Catalysts: Cobalt sulfide Solvents: Chlorobenzene

Reference

Catalytic reduction of 2-naphthalenesulfonyl chloride to 2-thionaphthol by hydrogen

Tret'yakov, V. P.; Zimtseva, G. P.; Chudaev, V. V.; Rudakov, E. S.; Ponomarev, V. N.; et al, Zhurnal Prikladnoi Khimii (Sankt-Peterburg, 1988, 61(4), 948-51

Production Method 7

5188-07-8

580-13-2

91-60-1

Reaction Conditions

Reference

A convenient synthesis of aromatic thiols from unactivated aryl halides

Testaferri, L.; Tingoli, M.; Tiecco, M., Tetrahedron Letters, 1980, 21(32), 3099-100

Production Method 8

580-13-2

91-60-1

Reaction Conditions

1.1 Reagents: Cesium carbonate ,  Sodium thiosulfate Catalysts: Tris(dibenzylideneacetone)dipalladium ,  X-Phos Solvents: tert-Butanol ,  Toluene ,  Water ;  rt; 24 h, 80 °C
1.2 Reagents: Zinc ,  Hydrochloric acid Solvents: Water ;  1 h, cooled

Reference

Palladium catalyzed synthesis of aryl thiols: Sodium thiosulfate as a cheap and nontoxic mercapto surrogate

Yi, Jun; Fu, Yao; Xiao, Bin; Cui, Wei-Chen; Guo, Qing-Xiang, Tetrahedron Letters, 2011, 52(2), 205-208

Production Method 9

93-11-8

91-60-1

Reaction Conditions

1.1 Reagents: Triphenylphosphine Solvents: Heptane ;  85 °C; 1 h, 85 °C; 85 °C → 50 °C
1.2 Reagents: Water ;  10 min, 50 °C

Reference

Preparation and characterization of thiophenol compounds

Feng, Baicheng; Liu, Peng; Jing, Liqian, Qingdao Keji Daxue Xuebao, 2011, 32(3), 252-255

Production Method 10

5586-15-2

91-60-1

Reaction Conditions

1.1 Reagents: Hydrogen Catalysts: Cobalt Solvents: Tetrahydrofuran

Reference

Reduction of sulfonyl chlorides to thiols

Mylroie, Victor L.; Doles, Joseph K., Chemical Industries (Dekker), 1990, 40, 189-96

Production Method 11

201036-12-6

91-60-1

Reaction Conditions

1.1 Solvents: Acetonitrile

Reference

Photochemistry and photophysics of aromatic sulfoxides. 9. Photochemistry of benzyl β-naphthyl sulfoxide and characterization of the β-naphthylsulfinyl radical

Guo, Yushen; Darmanyan, Alexandre P.; Jenks, William S., Tetrahedron Letters, 1997, 38(50), 8619-8622

Production Method 12

580-13-2

91-60-1

Reaction Conditions

1.1 Reagents: Ethanethiol ,  Sodium hydride Solvents: Dimethylformamide ;  0 °C; 30 min, rt
1.2 Solvents: Dimethylformamide ;  24 h, reflux; cooled
1.3 Reagents: Hydrochloric acid Solvents: Water

Reference

Camphor-Based Schiff Base Of 3-Endo-Aminoborneol (SBAB): Novel Ligand for Vanadium-Catalyzed Asymmetric Sulfoxidation and Subsequent Kinetic Resolution

Chuo, Ting Hung; Boobalan, Ramalingam; Chen, Chinpiao, ChemistrySelect, 2016, 1(10), 2174-2180

Production Method 13

607-53-4

91-60-1

Reaction Conditions

1.1 Catalysts: 1-Naphthalenethiol

Reference

Aqueous high-temperature chemistry of carbo- and heterocycles. Part 16. Model sulfur compounds: a study of hydrogen sulfide generation

Katritzky, Alan R.; Murugan, Ramiah; Balasubramanian, Marudai; Greenhill, John V.; Siskin, Michael; et al, Energy & Fuels, 1991, 5(6), 823-34

2-Naphtalenethiol Raw materials

• Ethanethioic acid,S-2-naphthalenyl ester
• 2-Iodonaphthalene
• Naphthalene, 1,1'-thiobis-
• Sodium Ethanethiolate
• Sodium Methanethiolate (~20% in Water)
• Naphthalene-2-sulfonyl chloride
• 2-Bromonaphthalene
• Disulfide,1,2-di-2-naphthalenyl
• 2-Naphthalenesulfonic acid, phenyl ester
• Naphthalene, 2-[(phenylmethyl)sulfinyl]-

2-Naphtalenethiol Preparation Products

• 2-Naphtalenethiol (91-60-1)

• 1. Excitation dependent bidirectional electron transfer in phthalocyanine-functionalised MoS2 nanosheets?
  Christopher J. Harrison,Kyle J. Berean,Enrico Della Gaspera,Jian Zhen Ou,Richard B. Kaner,Kourosh Kalantar-zadeh,Torben Daeneke Nanoscale, 2016,8, 16276-16283
• 2. Evolution of important glucosinolates in three common Brassica vegetables during their processing into vegetable powder and in vitro gastric digestion
  Nan Fu,Naphaporn Chiewchan,Xiao Dong Chen Food Funct., 2020,11, 211-220
• 3. Fe(ii)-Assisted one-pot synthesis of ultra-small core–shell Au–Pt nanoparticles as superior catalysts towards the HER and ORR?
  Yi Cao,Yujiao Xiahou,Lixiang Xing,Xiang Zhang,Hong Li,ChenShou Wu,Haibing Xia Nanoscale, 2020,12, 20456-20466
• 4. Evolution of cellulose into flexible conductive green electronics: a smart strategy to fabricate sustainable electrodes for supercapacitors
  Tengfei Yu,Yuehan Wu,Wei Li,Bin Li RSC Adv., 2014,4, 34134-34143
• 5. Evolution study of photo-synthesized gold nanoparticles by spectral deconvolution model: a quantitative approach
  Chung-Sung Yang,Mong-Shian Shih,Fang-Yi Chang New J. Chem., 2006,30, 729-735

• Solvents and Organic Chemicals Organic Compounds Benzenoids Naphthalenes Naphthalenes
• Solvents and Organic Chemicals Organic Compounds Benzenoids Naphthalenes
• Solvents and Organic Chemicals Organic Compounds Alcohol/Ether

• 529-36-2(1-Naphthalenethiol)
• 61708-79-0(9-Phenanthrenethiol)
• 85736-23-8(1-Naphthalenylthio)
• 71977-56-5(2,7-Naphthalenedithiol)
• 90590-00-4(2-Anthracenethiol)
• 27460-00-0(Naphthalenethiol)
• 17534-14-4(9-Anthracenethiol)
• 5325-88-2(1,5-Dimercaptonaphthalene)
• 96892-95-4(Naphthalene-2,6-dithiol)
• 89781-11-3(2-Naphthalenethiol, potassium salt)