Production Method 1

1571-08-0

90484-53-0

Reaction Conditions

1.1 Reagents: N-Bromosuccinimide ,  Trifluoromethanesulfonic acid Catalysts: 2-Amino-4-nitrobenzoic acid ,  Silver trifluoroacetate ,  Palladium diacetate Solvents: 1,2-Dichloroethane ;  24 h, 90 °C

Reference

Diverse ortho-C(sp2)-H Functionalization of Benzaldehydes Using Transient Directing Groups

Liu, Xi-Hai; et al, Journal of the American Chemical Society, 2017, 139(2), 888-896

Production Method 2

1571-08-0

90484-53-0

Reaction Conditions

1.1 Reagents: N-Bromosuccinimide ,  2-Amino-4-nitrobenzoic acid ,  Trifluoromethanesulfonic acid ,  Silver trifluoroacetate Catalysts: Palladium diacetate Solvents: 1,2-Dichloroethane ;  36 h, 90 °C

Reference

Annulated bacteriochlorins for near-infrared photophysical studies

Fujita, Hikaru; et al, New Journal of Chemistry, 2019, 43(19), 7209-7232

Production Method 3

1001200-40-3

90484-53-0

Reaction Conditions

1.1 Reagents: Pyridine Solvents: Pyridine ;  70 min, 100 °C
1.2 Solvents: Water ;  cooled

Reference

A versatile method for the hydrolysis of gem-dibromomethylarenes bearing carboxylate or boronate group into aldehydes

Augustine, John Kallikat; et al, Tetrahedron, 2007, 64(4), 688-695

Production Method 4

1001200-40-3

90484-53-0

Reaction Conditions

1.1 Reagents: Silver nitrate Solvents: Ethanol ,  Water ;  90 min, reflux; reflux → rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  < pH 1
1.3 Catalysts: Hydrochloric acid Solvents: Acetonitrile ,  Water ;  2 h, 70 °C

Reference

Synthesis, radiolabeling and preliminary in vivo evaluation of multimodal radiotracers for PET imaging and targeted radionuclide therapy of pigmented melanoma

Billaud, Emilie M. F.; et al, European Journal of Medicinal Chemistry, 2015, 92, 818-838

Methyl 3-bromo-4-formylbenzoate Raw materials

• Methyl 4-formylbenzoate
• Methyl 3-bromo-4-(dibromomethyl)benzoate

Methyl 3-bromo-4-formylbenzoate Preparation Products

• Methyl 3-bromo-4-formylbenzoate (90484-53-0)

• 1. Excimer formation effects and trap-assisted charge recombination loss channels in organic solar cells of perylene diimide dimer acceptors?
  Min Kim,Jae-Joon Lee,Tengling Ye,Panagiotis E. Keivanidis,Kilwon Cho J. Mater. Chem. C, 2020,8, 1686-1696
• 2. Excellent mechanical performance and enhanced dielectric properties of OBC/SiO2 elastomeric nanocomposites: effect of dispersion of the SiO2 nanoparticles?
  Xing Zhao,Lu Bai,Rui-Ying Bao,Zheng-Ying Liu,Ming-Bo Yang,Wei Yang RSC Adv., 2017,7, 46297-46305
• 3. Fe(iii)-mediated isomerization of α,α-diarylallylic alcohols to ketones via radical 1,2-aryl migration?
  Ziyang Deng,Changwei Chen,Sunliang Cui RSC Adv., 2016,6, 93753-93755
• 4. Elusive 2-aminofuran Diels–Alder substrates for a straightforward synthesis of polysubstituted anilines?
  Ana G. Neo,Ana Bornadiego,Jesús Díaz,Stefano Marcaccini,Carlos F. Marcos Org. Biomol. Chem., 2013,11, 6546-6555
• 5. Fc microparticles can modulate the physical extent and magnitude of complement activity?
  David White,Sean R. Stowell Biomater. Sci., 2017,5, 463-474

• 610-94-6(Methyl 2-bromobenzoate)
• 104901-43-1(Methyl 3-bromo-4-methylbenzoate)
• 131001-86-0(Methyl 2-bromo-3-methylbenzoate)
• 18643-86-2(1,4-dimethyl 2-bromobenzene-1,4-dicarboxylate)
• 245549-92-2(Benzoic acid,2,5-dibromo-4-methyl-, methyl ester)
• 74896-66-5(Methyl 3,5-dibromo-4-methylbenzoate)
• 18014-00-1(Dimethyl 2,5-dibromoterephthalate)
• 87808-49-9(Methyl 2-bromo-4-methylbenzoate)
• 90971-88-3(Methyl 2-bromo-5-methylbenzoate)
• 57381-43-8(Methyl 2,5-dibromobenzoate)