Production Method 1

6967-82-4

18107-18-1

90971-88-3

Reaction Conditions

1.1 Solvents: Diethyl ether ,  Methanol ,  Toluene ;  rt; 2 h, rt

Reference

Supramolecular Control of Selectivity in Hydroformylation of Vinyl Arenes: Easy Access to Valuable β-Aldehyde Intermediates

Dydio, Pawel; Reek, Joost N. H., Angewandte Chemie, 2013, 52(14), 3878-3882

Production Method 2

6967-82-4

90971-88-3

Reaction Conditions

1.1 Reagents: Oxalyl chloride Solvents: Dimethylformamide ,  Dichloromethane ;  0 °C; 1 h, rt
1.2 Solvents: Methanol ;  3 h, rt
1.3 Reagents: Sodium carbonate Solvents: Water ;  neutralized, rt

Reference

CuCl-catalyzed one-pot synthesis of 5,6-dihydropyrazolo[1,5-c]quinazolines

Guo, Shenghai; Wang, Jiliang; Li, Yan; Fan, Xuesen, Tetrahedron, 2014, 70(14), 2383-2388

Production Method 3

6967-82-4

90971-88-3

Reaction Conditions

1.1 Reagents: Thionyl chloride Solvents: Methanol ;  65 °C; 8 - 9 h, 65 °C

Reference

Synthesis, docking and biological evaluation of thiadiazole and oxadiazole derivatives as antimicrobial and antioxidant agents

Zabiulla; Nagesh Khadri, M. J.; Bushra Begum, A.; Sunil, M. K.; Khanum, Shaukath Ara, Results in Chemistry, 2020, 2,

Production Method 4

6967-82-4

90971-88-3

Reaction Conditions

1.1 Reagents: Sulfuric acid Solvents: Methanol ;  3 h, reflux

Reference

3-(Adenosylthio)benzoic Acid Derivatives as SARS-CoV-2 Nsp14 Methyltransferase Inhibitors

Bobileva, Olga ; Bobrovs, Raitis ; Sirma, Evelina Elva; Kanepe, Iveta ; Bula, Anna L.; et al, Molecules, 2023, 28(2),

Production Method 5

6967-82-4

90971-88-3

Reaction Conditions

1.1 Catalysts: Sulfuric acid Solvents: Methanol ;  16 h, 65 °C; 65 °C → rt
1.2 Solvents: Water ;  rt

Reference

Selenium-Catalyzed C(sp3)-H Acyloxylation: Application in the Expedient Synthesis of Isobenzofuranones

Kraetzschmar, Felix; Kassel, Martin; Delony, Daniel; Breder, Alexander, Chemistry - A European Journal, 2015, 21(19), 7030-7034

Methyl 2-bromo-5-methylbenzoate Raw materials

• 2-Bromo-5-methylbenzoic acid
• (diazomethyl)trimethylsilane

Methyl 2-bromo-5-methylbenzoate Preparation Products

• Methyl 2-bromo-5-methylbenzoate (90971-88-3)

• 1. Examination of deposit in commercial diluted phosphoric acid
  Analyst, 1880,5, 146-147
• 2. Enabling chloride salts for thermal energy storage: implications of salt purity?
  J. Matthew Kurley,Phillip W. Halstenberg,Abbey McAlister,Stephen Raiman,Richard T. Mayes RSC Adv., 2019,9, 25602-25608
• 3. EWOD-driven droplet microfluidic device integrated with optoelectronic tweezers as an automated platform for cellular isolation and analysis?
  Gaurav J. Shah,Eric P.-Y. Chiou,Ming C. Wu,Chang-Jin “CJ” Kim Lab Chip, 2009,9, 1732-1739
• 4. Fate of single walled carbon nanotubes in wetland ecosystems?
  Joseph H. Bisesi,Tara Sabo-Attwood Environ. Sci.: Nano, 2014,1, 574-583
• 5. Excellent humidity sensor based on ultrathin HKUST-1 nanosheets?
  Qiaoe Wang,Meiling Lian,Xiaowen Zhu,Xu Chen RSC Adv., 2021,11, 192-197

• Solvents and Organic Chemicals Organic Compounds Organic Halides

• 610-94-6(Methyl 2-bromobenzoate)
• 131001-86-0(Methyl 2-bromo-3-methylbenzoate)
• 18643-86-2(1,4-dimethyl 2-bromobenzene-1,4-dicarboxylate)
• 245549-92-2(Benzoic acid,2,5-dibromo-4-methyl-, methyl ester)
• 873994-34-4(Methyl 2,6-dibromobenzoate)
• 18014-00-1(Dimethyl 2,5-dibromoterephthalate)
• 87808-49-9(Methyl 2-bromo-4-methylbenzoate)
• 90766-77-1(1,3-Benzenedicarboxylic acid, 4,6-dibromo-, dimethyl ester)
• 54335-33-0(Methyl 2,4-dibromobenzoate)
• 57381-43-8(Methyl 2,5-dibromobenzoate)