- Mild Silver(I)-Mediated Regioselective Iodination and Bromination of Arylboronic AcidsAl-Zoubi, Raed M.; Hall, Dennis G., Organic Letters, 2010, 12(11), 2480-2483
Cas no 89694-44-0 (2-Bromo-5-methoxyphenylboronic acid)
89694-44-0 structure
Product Name:2-Bromo-5-methoxyphenylboronic acid
CAS No:89694-44-0
MF:C7H8BBrO3
MW:230.851621627808
MDL:MFCD06659859
CID:654283
PubChem ID:25266062
Update Time:2024-10-26
2-Bromo-5-methoxyphenylboronic acid Chemical and Physical Properties
Names and Identifiers
-
- 2-Bromo-5-methoxybenzene boronic acid
- (2-BROMO-5-METHOXY)BENZENEBORONIC ACID
- (2-Bromo-5-methoxyphenyl)boronic acid
- 2-Bromo-5-methoxyphenylboronic acid
- 2-Brom-5-methoxy-benzol-boronsaeure
- OR1188
- AMTB841
- BJQKEDXKQVNQPR-UHFFFAOYSA-N
- 2-Bromo-5-methoxyphenylboranic acid
- FCH1323668
- AB26490
- BC001371
- Boronic acid,B-(2-bromo-5-methoxyphenyl)-
- Z1036
- ST24040162
- F
- B-(2-Bromo-5-methoxyphenyl)boronic acid (ACI)
- Benzeneboronic acid, 2-bromo-5-methoxy- (7CI)
- Boronic acid, (2-bromo-5-methoxyphenyl)- (9CI)
- DTXSID70649526
- MFCD06659859
- (2-Bromo-5-methoxy-phenyl)boronic acid
- 2-Bromo-5-methoxybenzeneboronic acid
- AKOS015835195
- DB-000455
- SY122905
- CS-0038152
- SCHEMBL645367
- 2-Bromo-5-methoxybenzeneboronicacid
- AS-2888
- 89694-44-0
-
- MDL： MFCD06659859
- Inchi： 1S/C7H8BBrO3/c1-12-5-2-3-7(9)6(4-5)8(10)11/h2-4,10-11H,1H3
- InChI Key： BJQKEDXKQVNQPR-UHFFFAOYSA-N
- SMILES： BrC1C(B(O)O)=CC(OC)=CC=1
Computed Properties
- Exact Mass: 229.97500
- Monoisotopic Mass: 229.97499 g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 2
- Hydrogen Bond Acceptor Count: 3
- Heavy Atom Count: 12
- Rotatable Bond Count: 2
- Complexity: 145
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 49.7
- Molecular Weight: 230.85
Experimental Properties
- Melting Point: 214-216
- Boiling Point: 376.6°C at 760 mmHg
- PSA: 49.69000
- LogP: 0.13750
2-Bromo-5-methoxyphenylboronic acid Security Information
- Signal Word：Warning
- Hazard Statement： H315-H319-H335
- Warning Statement： P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501
-
Hazardous Material Identification：
- Storage Condition：Inert atmosphere,2-8°C
2-Bromo-5-methoxyphenylboronic acid Customs Data
- HS CODE：2931900090
- Customs Data：
China Customs Code:
2931900090Overview:
2931900090. Other organic-Inorganic compound. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods). MFN tariff:6.5%. general tariff:30.0%
Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
2-Bromo-5-methoxyphenylboronic acid Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-AD622-200mg |
2-Bromo-5-methoxyphenylboronic acid |
89694-44-0 | 97% | 200mg |
74.0CNY | 2021-08-04 | |
| Chemenu | CM327237-5g |
(2-bromo-5-methoxyphenyl)boronic acid |
89694-44-0 | 95%+ | 5g |
$98 | 2022-08-31 | |
| Chemenu | CM327237-10g |
(2-bromo-5-methoxyphenyl)boronic acid |
89694-44-0 | 95%+ | 10g |
$182 | 2022-08-31 | |
| Chemenu | CM327237-25g |
(2-bromo-5-methoxyphenyl)boronic acid |
89694-44-0 | 95%+ | 25g |
$440 | 2022-08-31 | |
| abcr | AB154235-250 mg |
2-Bromo-5-methoxyphenylboronic acid, 97%; . |
89694-44-0 | 97% | 250mg |
€78.90 | 2023-05-08 | |
| abcr | AB154235-1 g |
2-Bromo-5-methoxyphenylboronic acid, 97%; . |
89694-44-0 | 97% | 1g |
€122.10 | 2023-05-08 | |
| abcr | AB154235-5 g |
2-Bromo-5-methoxyphenylboronic acid, 97%; . |
89694-44-0 | 97% | 5g |
€299.40 | 2023-05-08 | |
| abcr | AB154235-10 g |
2-Bromo-5-methoxyphenylboronic acid, 97%; . |
89694-44-0 | 97% | 10g |
€484.20 | 2023-05-08 | |
| Apollo Scientific | OR1188-250mg |
2-Bromo-5-methoxybenzeneboronic acid |
89694-44-0 | 250mg |
￡30.00 | 2025-02-19 | ||
| Apollo Scientific | OR1188-1g |
2-Bromo-5-methoxybenzeneboronic acid |
89694-44-0 | 1g |
￡66.00 | 2025-02-19 |
2-Bromo-5-methoxyphenylboronic acid Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Bromine , Silver sulfate Solvents: Ethanol ; rt; 3 - 15 min, rt
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: N-Bromosuccinimide Catalysts: N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[2-(diphenylphosphinothioyl)phenyl]thioure… Solvents: Dibromomethane , Chloroform-d ; 1 h, rt
1.2 Reagents: 2-Methyl-2-butene ; rt
1.2 Reagents: 2-Methyl-2-butene ; rt
Reference
- Total Synthesis of (+)-Hinckdentine A: Harnessing Noncovalent Interactions for Organocatalytic BrominationRuan, Zhuwei; Wang, Min; Yang, Chen; Zhu, Lili; Su, Zhishan ; et al, JACS Au, 2022, 2(4), 793-800
Production Method 3
Reaction Conditions
1.1 Reagents: N-Bromosuccinimide Catalysts: Triphenylphosphine sulfide Solvents: Chloroform-d , Methanol-d ; 1 h, rt
Reference
- A Practical Lewis Base Catalyzed Electrophilic Chlorination of Arenes and HeterocyclesMaddox, Sean M.; Nalbandian, Christopher J.; Smith, Davis E.; Gustafson, Jeffrey L., Organic Letters, 2015, 17(4), 1042-1045
2-Bromo-5-methoxyphenylboronic acid Raw materials
2-Bromo-5-methoxyphenylboronic acid Preparation Products
2-Bromo-5-methoxyphenylboronic acid Related Literature
-
Craig A. Kelly,David R. Rosseinsky Phys. Chem. Chem. Phys., 2001,3, 2086-2090
-
Yu Long,Bing Yuan,Jianrui Niu,Xin Tong,Jiantai Ma New J. Chem., 2015,39, 1179-1185
-
Pavel Karásek,Jakub Grym,Michal Roth,Josef Planeta,Franti?ek Foret Lab Chip, 2015,15, 311-318
-
Ana G. Neo,Ana Bornadiego,Jesús Díaz,Stefano Marcaccini,Carlos F. Marcos Org. Biomol. Chem., 2013,11, 6546-6555
-
Christopher B. Rodell,Christopher B. Highley,Minna H. Chen,Neville N. Dusaj,Chao Wang,Lin Han,Jason A. Burdick Soft Matter, 2016,12, 7839-7847
89694-44-0 (2-Bromo-5-methoxyphenylboronic acid) Related Products
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- 89677-46-3(2,4-Dibromo-5-methoxyphenylboronic acid)
- 89694-45-1(5-Bromo-2-methoxyphenylboronic acid)
- 1256345-59-1(4-bromo-3-methoxyphenylboronic acid)
- 1217501-37-5(2,5-Dibromo-4-methoxyphenylboronic Acid)
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