- Synthesis of Alkylated Pyrimidines via Photoinduced Coupling Using Benzophenone as a MediatorKamijo, Shin ; Kamijo, Kaori; Murafuji, Toshihiro, Journal of Organic Chemistry, 2017, 82(5), 2664-2671
Cas no 89283-48-7 (4-chloro-6-methylsulfanyl-pyrimidine)
89283-48-7 structure
Product Name:4-chloro-6-methylsulfanyl-pyrimidine
CAS No:89283-48-7
MF:C5H5ClN2S
MW:160.624598264694
MDL:MFCD09870036
CID:61245
PubChem ID:329826143
Update Time:2024-10-26
4-chloro-6-methylsulfanyl-pyrimidine Chemical and Physical Properties
Names and Identifiers
-
- 4-Chloro-6-(methylthio)pyrimidine
- 4-Chloro-6-methylthiopyrimidine
- 4-chloro-6-methylsulfanylpyrimidine
- Pyrimidine, 4-chloro-6-(methylthio)-
- 4-Chlor-methylmercapto-pyrimidin
- 4-chloro-6-methylsulfanyl-pyrimidine
- 4-chloro-6-thiomethylpyrimidine
- 6-chloro-4-methylthiopyrimidine
- Pyrimidine,4-chloro-6-(methylthio)
- 4-chloro-6-(methylsulfanyl)pyrimidine
- Pyrimidine,4-chloro-6-(methylthio)-
- BMQSAIGMUNXTKZ-UHFFFAOYSA-N
- 4-(Methylthio)-6-chloropyrimidine
- TRA0083799
- WT81915
- AB0027391
- ST2
- 4-Chloro-6-(methylthio)pyrimidine (ACI)
- 4-Chloro-6-methylthiopyrimidine, AldrichCPR
- J-515119
- DTXSID50618311
- CS-W009206
- SY034811
- 89283-48-7
- SB57446
- AKOS010530156
- SCHEMBL1660128
- DS-10658
- MFCD09870036
-
- MDL： MFCD09870036
- Inchi： 1S/C5H5ClN2S/c1-9-5-2-4(6)7-3-8-5/h2-3H,1H3
- InChI Key： BMQSAIGMUNXTKZ-UHFFFAOYSA-N
- SMILES： ClC1C=C(SC)N=CN=1
Computed Properties
- Exact Mass: 159.98600
- Monoisotopic Mass: 159.986
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 3
- Heavy Atom Count: 9
- Rotatable Bond Count: 1
- Complexity: 91
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: 2
- Topological Polar Surface Area: 51.1
Experimental Properties
- Density: 1.37
- Boiling Point: 260 oC
- Flash Point: 111 oC
- Refractive Index: 1.595
- PSA: 51.08000
- LogP: 1.85190
4-chloro-6-methylsulfanyl-pyrimidine Customs Data
- HS CODE：2933599090
- Customs Data：
China Customs Code:
2933599090Overview:
2933599090. Other compounds with pyrimidine ring in structure(Including other compounds with piperazine ring on the structure. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:20.0%
Declaration elements:
Product Name, component content, use to, Please indicate the appearance of Urotropine, 6- caprolactam please indicate the appearance, Signing date
Summary:
2933599090. other compounds containing a pyrimidine ring (whether or not hydrogenated) or piperazine ring in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
4-chloro-6-methylsulfanyl-pyrimidine Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Fluorochem | 076470-10g |
4-Chloro-6-methylthiopyrimidine |
89283-48-7 | 95% | 10g |
￡185.00 | 2022-03-01 | |
| Fluorochem | 076470-25g |
4-Chloro-6-methylthiopyrimidine |
89283-48-7 | 95% | 25g |
￡288.00 | 2022-03-01 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C136932-1g |
4-chloro-6-methylsulfanyl-pyrimidine |
89283-48-7 | 97% | 1g |
￥239.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C136932-250mg |
4-chloro-6-methylsulfanyl-pyrimidine |
89283-48-7 | 97% | 250mg |
￥86.90 | 2023-09-03 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | C136932-5g |
4-chloro-6-methylsulfanyl-pyrimidine |
89283-48-7 | 97% | 5g |
￥738.90 | 2023-09-03 | |
| Fluorochem | 076470-1g |
4-Chloro-6-methylthiopyrimidine |
89283-48-7 | 95% | 1g |
￡35.00 | 2022-03-01 | |
| Fluorochem | 076470-5g |
4-Chloro-6-methylthiopyrimidine |
89283-48-7 | 95% | 5g |
￡93.00 | 2022-03-01 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R024459-1g |
4-chloro-6-methylsulfanyl-pyrimidine |
89283-48-7 | 97% | 1g |
￥125 | 2024-05-21 | |
| TRC | C381670-10mg |
4-Chloro-6-methylthiopyrimidine |
89283-48-7 | 10mg |
$ 50.00 | 2022-06-06 | ||
| TRC | C381670-50mg |
4-Chloro-6-methylthiopyrimidine |
89283-48-7 | 50mg |
$ 65.00 | 2022-06-06 |
4-chloro-6-methylsulfanyl-pyrimidine Production Method
Production Method 1
Reaction Conditions
1.1 Solvents: Tetrahydrofuran , Water ; 3 °C; 4 h, 3 °C → rt
1.2 Reagents: Water ; rt
1.2 Reagents: Water ; rt
Reference
Production Method 2
Reaction Conditions
1.1 16 - 72 h, 60 °C
1.2 Solvents: Methanol
1.2 Solvents: Methanol
Reference
- BF3·SMe2 for Thiomethylation, Nitro Reduction and Tandem Reduction/SMe Insertion of Nitrogen HeterocyclesSoederstroem, Marcus; Zamaratski, Edouard; Odell, Luke R., European Journal of Organic Chemistry, 2019, 2019(31-32), 5402-5408
Production Method 3
Reaction Conditions
1.1 Solvents: Tetrahydrofuran , Water ; 4 h, rt
Reference
- Design, synthesis and herbicidal evaluation of novel 4-(1H-pyrazol-1-yl)pyrimidine derivativesMa, Hong-Ju; Zhang, Jian-Hua; Xia, Xiang-Dong; Kang, Jing; Li, Jian-Hong, Pest Management Science, 2015, 71(8), 1189-1196
4-chloro-6-methylsulfanyl-pyrimidine Raw materials
- Sodium Methanethiolate (~20% in Water)
- 4,6-Dichloropyrimidine
- Boron trifluoride methyl sulfide complex
4-chloro-6-methylsulfanyl-pyrimidine Preparation Products
4-chloro-6-methylsulfanyl-pyrimidine Related Literature
-
Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890
-
Long Deng,Qian Zou,Biao Liu,Wenhui Ye,Chengfei Zhuo,Li Chen,Ze-Yuan Deng,Ya-Wei Fan,Jing Li Food Funct., 2018,9, 4234-4245
-
Kay S. McMillan,Anthony G. McCluskey,Annette Sorensen,Marie Boyd,Michele Zagnoni Analyst, 2016,141, 100-110
-
Byungho Lim,Jaewon Jin,Jin Yoo,Seung Yong Han,Kyeongyeol Kim,Sungah Kang,Nojin Park,Sang Moon Lee,Hae Jin Kim,Seung Uk Son Chem. Commun., 2014,50, 7723-7726
-
5. Excimer emission and magnetoluminescence of radical-based zinc(ii) complexes doped in host crystals?Shojiro Kimura,Tetsuro Kusamoto Chem. Commun., 2020,56, 11195-11198
89283-48-7 (4-chloro-6-methylsulfanyl-pyrimidine) Related Products
- 263276-29-5(Pyrimidine, 4-chloro-6-(propylthio)-)
- 1137576-60-3(2,4-dichloro-6-(methylsulfanyl)pyrimidine)
- 197241-67-1(Pyrimidine, 4-chloro-6-[(4-chlorophenyl)thio]-)
- 607723-60-4(Pyrimidine, 4-chloro-6-(phenylthio)-)
- 98027-08-8(4-Pyrimidinethiol, 6-chloro- (6CI))
- 257957-18-9(4-chloro-2,6-bis(methylsulfanyl)pyrimidine)
- 1249496-79-4(4-chloro-2-methyl-6-(propan-2-ylsulfanyl)pyrimidine)
- 37489-39-7(5-Pyrimidinamine, 4-chloro-6-(methylthio)-)
- 6307-36-4(4-chloro-6-methylsulfanyl-pyrimidin-2-amine)
- 867131-59-7(4-Chloro-2-methyl-6-(methylsulfanyl)pyrimidine)
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