Cas no 88345-89-5 (3-Bromo-4-phenylpyridine)

3-Bromo-4-phenylpyridine structure

Product Name:3-Bromo-4-phenylpyridine

CAS No:88345-89-5

MF:C₁₁H₈BrN

MW:234.091921806335

MDL:MFCD04114247

CID:721055

PubChem ID:2762928

Update Time:2024-10-26

3-Bromo-4-phenylpyridine Chemical and Physical Properties

Names and Identifiers

- Pyridine,3-bromo-4-phenyl-
- 3-BROMO-4-PHENYLPYRIDINE
- 3-bromanyl-4-phenyl-pyridine
- 4-Phenyl-3-bromopyridine
- Pyridine,3-bromo-4-phenyl
- 3-Bromo-4-phenylpyridine (ACI)
- AKOS023671717
- J-511946
- SY036468
- DB-015235
- SCHEMBL1203821
- DTXSID70376582
- BL000497
- 88345-89-5
- MFCD04114247
- CS-0156411
- LVNPADQPUYHCOR-UHFFFAOYSA-N
- AS-45740
- 3-Bromo-4-phenylpyridine
- MDL： MFCD04114247
- Inchi： 1S/C11H8BrN/c12-11-8-13-7-6-10(11)9-4-2-1-3-5-9/h1-8H
- InChI Key： LVNPADQPUYHCOR-UHFFFAOYSA-N
- SMILES： BrC1C(C2C=CC=CC=2)=CC=NC=1

Computed Properties

Exact Mass: 232.98400
Monoisotopic Mass: 232.984
Isotope Atom Count: 0
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 1
Heavy Atom Count: 13
Rotatable Bond Count: 1
Complexity: 154
Covalently-Bonded Unit Count: 1
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count : 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Topological Polar Surface Area: 12.9A^2
XLogP3: 3.2

Experimental Properties

Density: 1.426
Melting Point: 49-50
Boiling Point: 293 oC
Flash Point: 131 oC
Refractive Index: 1.606
PSA: 12.89000
LogP: 3.51110

3-Bromo-4-phenylpyridine Security Information

Hazard Statement： Irritant
Hazardous Material Identification：

3-Bromo-4-phenylpyridine Customs Data

HS CODE：2933399090
Customs Data：

China Customs Code:
2933399090

Overview:

2933399090. Other compounds with non fused pyridine rings in structure. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:20.0%

Declaration elements:

Product Name, component content, use to, Please indicate the appearance of Urotropine, 6- caprolactam please indicate the appearance, Signing date

Summary:

2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

3-Bromo-4-phenylpyridine Pricemore >>

Related Categories	No.	Product Name	Cas No.	Purity	Specification	Price	update time
Matrix Scientific	187928-1g	3-Bromo-4-phenylpyridine	88345-89-5		1g	$298.00	2023-09-07
Matrix Scientific	187928-5g	3-Bromo-4-phenylpyridine	88345-89-5		5g	$810.00	2023-09-07
Matrix Scientific	187928-10g	3-Bromo-4-phenylpyridine	88345-89-5		10g	$1296.00	2023-09-07
TRC	B750993-10mg	3-Bromo-4-phenylpyridine	88345-89-5		10mg	$ 50.00	2022-06-06
TRC	B750993-50mg	3-Bromo-4-phenylpyridine	88345-89-5		50mg	$ 70.00	2022-06-06
TRC	B750993-100mg	3-Bromo-4-phenylpyridine	88345-89-5		100mg	$ 115.00	2022-06-06
Alichem	A023023232-250mg	3-Bromo-4-phenylpyridine	88345-89-5	97%	250mg	$693.60	2023-08-31
Alichem	A023023232-500mg	3-Bromo-4-phenylpyridine	88345-89-5	97%	500mg	$1019.20	2023-08-31
Alichem	A023023232-1g	3-Bromo-4-phenylpyridine	88345-89-5	97%	1g	$1696.80	2023-08-31
Chemenu	CM120980-1g	3-Bromo-4-phenylpyridine	88345-89-5	97%	1g	$338	2021-08-06

3-Bromo-4-phenylpyridine Production Method

Production Method 1

88345-89-5

Reaction Conditions

1.1 Reagents: Potassium carbonate Catalysts: 2,2′-Bipyridine , Palladium diacetate Solvents: 1,2-Dichloroethane ; 5 h, 80 °C

Reference

A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

Chiba, Shunsuke; et al, Journal of the American Chemical Society, 2009, 131(36), 12886-12887

Production Method 2

98-80-6

13534-90-2

88345-89-5

Reaction Conditions

1.1 Reagents: Potassium carbonate Catalysts: Triphenylphosphine , Palladium diacetate Solvents: Methanol , Acetonitrile ; 24 h, 50 °C

Reference

Syntheses of Benzofuranoquinolines and Analogues via Photoinduced Acceptorless Dehydrogenative Annulation of o-Phenylfuranylpyridines

Fan, Jinming ; et al, Organic Letters, 2019, 21(22), 9183-9187

Production Method 3

88345-89-5

Reaction Conditions

1.1 Reagents: Cerium trichloride , Sodium borohydride Solvents: Methanol ; 2 min, rt; 30 min, rt
1.2 Reagents: Water ; rt
1.3 Reagents: Sodium azide Solvents: Dimethylformamide ; rt; 2 h, rt → 70 °C
1.4 Reagents: Water ; 70 °C
2.1 Reagents: Potassium carbonate Catalysts: 2,2′-Bipyridine , Palladium diacetate Solvents: 1,2-Dichloroethane ; 5 h, 80 °C

Reference

A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

Chiba, Shunsuke; et al, Journal of the American Chemical Society, 2009, 131(36), 12886-12887

Production Method 4

357940-96-6

88345-89-5

Reaction Conditions

1.1 Reagents: N-Bromosuccinimide Catalysts: Trimethylsilyl triflate Solvents: Acetonitrile ; 12 h, rt
2.1 Reagents: Cerium trichloride , Sodium borohydride Solvents: Methanol ; 2 min, rt; 30 min, rt
2.2 Reagents: Water ; rt
2.3 Reagents: Sodium azide Solvents: Dimethylformamide ; rt; 2 h, rt → 70 °C
2.4 Reagents: Water ; 70 °C
3.1 Reagents: Potassium carbonate Catalysts: 2,2′-Bipyridine , Palladium diacetate Solvents: 1,2-Dichloroethane ; 5 h, 80 °C

Reference

A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

Chiba, Shunsuke; et al, Journal of the American Chemical Society, 2009, 131(36), 12886-12887

Production Method 5

357941-18-5

88345-89-5

Reaction Conditions

1.1 Reagents: Pyridinium chlorochromate Solvents: Dichloromethane ; 24 h, rt
2.1 Reagents: N-Bromosuccinimide Catalysts: Trimethylsilyl triflate Solvents: Acetonitrile ; 12 h, rt
3.1 Reagents: Cerium trichloride , Sodium borohydride Solvents: Methanol ; 2 min, rt; 30 min, rt
3.2 Reagents: Water ; rt
3.3 Reagents: Sodium azide Solvents: Dimethylformamide ; rt; 2 h, rt → 70 °C
3.4 Reagents: Water ; 70 °C
4.1 Reagents: Potassium carbonate Catalysts: 2,2′-Bipyridine , Palladium diacetate Solvents: 1,2-Dichloroethane ; 5 h, 80 °C

Reference

A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

Chiba, Shunsuke; et al, Journal of the American Chemical Society, 2009, 131(36), 12886-12887

Production Method 6

10481-34-2

88345-89-5

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran , Hexane ; -78 °C; 2 h, -78 °C
1.2 Solvents: Tetrahydrofuran ; -78 °C; 4 h, -78 °C
1.3 Reagents: Water ; -78 °C
2.1 Reagents: Pyridinium chlorochromate Solvents: Dichloromethane ; 24 h, rt
3.1 Reagents: N-Bromosuccinimide Catalysts: Trimethylsilyl triflate Solvents: Acetonitrile ; 12 h, rt
4.1 Reagents: Cerium trichloride , Sodium borohydride Solvents: Methanol ; 2 min, rt; 30 min, rt
4.2 Reagents: Water ; rt
4.3 Reagents: Sodium azide Solvents: Dimethylformamide ; rt; 2 h, rt → 70 °C
4.4 Reagents: Water ; 70 °C
5.1 Reagents: Potassium carbonate Catalysts: 2,2′-Bipyridine , Palladium diacetate Solvents: 1,2-Dichloroethane ; 5 h, 80 °C

Reference

A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

Chiba, Shunsuke; et al, Journal of the American Chemical Society, 2009, 131(36), 12886-12887

Production Method 7

98-80-6

626-55-1

88345-89-5

27012-25-5

91182-50-2

Reaction Conditions

1.1 Reagents: Trifluoroacetic acid , Selectfluor Solvents: 1,2-Dichloroethane , Water ; 1 min, rt
1.2 Catalysts: Silver nitrate Solvents: Water ; 24 h, rt → 50 °C

Reference

: Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant

Galloway, Jordan D.; et al, Organic Letters, 2017, 19(21), 5772-5775

Production Method 8

98-80-6

626-55-1

88345-89-5

27012-25-5

91182-50-2

Reaction Conditions

1.1 Reagents: Trifluoroacetic acid , Potassium persulfate Catalysts: Iron sulfide (FeS) Solvents: Dichloromethane , Water ; 40 h, rt

Reference

: Iron-mediated direct arylation with arylboronic acids through an aryl radical transfer pathway

Wang, Jian; et al, Chemical Communications (Cambridge, 2012, 48(96), 11769-11771

3-Bromo-4-phenylpyridine Raw materials

3-Bromo-4-phenylpyridine Preparation Products

3-Bromo-4-phenylpyridine Related Literature

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Related Categories

Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Pyridines and derivatives Phenylpyridines

88345-89-5 (3-Bromo-4-phenylpyridine) Related Products

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Cas no 88345-89-5 (3-Bromo-4-phenylpyridine)

3-Bromo-4-phenylpyridine Chemical and Physical Properties

Names and Identifiers

Computed Properties

Experimental Properties

3-Bromo-4-phenylpyridine Security Information

3-Bromo-4-phenylpyridine Customs Data

China Customs Code:

Overview:

Declaration elements:

Summary:

3-Bromo-4-phenylpyridine Pricemore >>

3-Bromo-4-phenylpyridine Production Method

Production Method 1

Production Method 2

Production Method 3

Production Method 4

Production Method 5

Production Method 6

Production Method 7

Production Method 8

3-Bromo-4-phenylpyridine Raw materials

3-Bromo-4-phenylpyridine Preparation Products

3-Bromo-4-phenylpyridine Related Literature

Related Categories

88345-89-5 (3-Bromo-4-phenylpyridine) Related Products